AQA GCSE Chemistry Chemistry Paper 2 (Higher), November 2020: Question 10
10 marks · Standard Demand difficulty · Short Answer
Explain the effects of changing concentration, temperature, and pressure on a reversible reaction between iron(III) and thiocyanate ions, and identify a transition metal ion that forms coloured complexes.
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Question text
10 This question is about a reversible reaction.
The reaction between solutions of iron(III) ions (Fe3+) and thiocyanate ions (SCN–)
is reversible.
The ionic equation for the reaction is:
Fe3+(aq) + SCN–(aq) ⇌ FeSCN2+(aq)
Colour of solution: yellow colourless red
The colour of the equilibrium mixture is orange at room temperature.
10.1 Give the name of the solvent used to dissolve the ions in this reaction.
[1 mark]
10.2 A few drops of a colourless solution containing a high concentration of
thiocyanate ions (SCN–) are added to the orange equilibrium mixture.
Explain the colour change observed.
[3 marks]
10.3 A water bath is set up at a temperature above room temperature.
When a test tube containing the orange equilibrium mixture is placed in the water
bath, the mixture becomes more yellow.
Explain what this shows about the energy change for the forward reaction.
[3 marks]
10.4 Explain why a change in pressure does not affect the colour of the equilibrium
mixture.
[2 marks]
10.5 Other metal ions form coloured equilibrium mixtures with thiocyanate ions.
Which metal ion could form a coloured equilibrium mixture with thiocyanate ions?
[1 mark]
Tick ( ) one box.
Al3+
Co2+
Mg2+
Na+
Mark scheme
Show the mark scheme
Question 10
AO /
Question Answers Extra information Mark
Spec. Ref.
AO1
10.1 water allow H2O 1 4.2.2.2
10.2 becomes (more) red 1 AO2
4.6.2.4
4.6.2.5
(because the position of) allow (because) the 1
equilibrium moves to the right concentration of FeSCN2+ (ions)
increases
allow (because) the forward
reaction is favoured
(so that) the (increase in the) allow (so that) the increase in 1
concentration of thiocyanate the concentration of thiocyanate
(ions) is reduced (ions) is counteracted
10.3 (the position of) equilibrium allow the concentration of Fe3+ 1 AO2
moves to the left (ions) increases 4.6.2.4
4.6.2.6
allow the reverse reaction is
favoured
(so that) the (increase in the) allow (so that) the increase in 1
temperature is reduced the temperature is counteracted
(therefore) the forward reaction allow (therefore) the forward 1
is exothermic reaction releases energy (to the
surroundings)
Question 10 (continued)
AO /
Spec. Ref.
22 10.4 no change in equilibrium 1 AO2
position 4.6.2.7
(because) no gases are present allow (because) only aqueous 1
solutions are present
AO2
10.5 Co2+ 1 4.1.3.2
4.6.2.5
Total 10
How to answer it
Reversible Reactions & Le Chatelier's Principle
This question assesses understanding of dynamic equilibria, applying Le Chatelier's principle to predict and explain shifts caused by changes in concentration, temperature, and pressure, as well as recalling characteristic properties of transition metals.
Question 10.1
Identifying the Solvent from State Symbols
✅ Correct Answer
Water (or H₂O )
💡 Key Knowledge
The state symbol (aq) stands for aqueous, meaning a substance is dissolved in water. Water is therefore the solvent.
Question 10.2
Effect of Increasing Concentration on Equilibrium
✅ Correct Answer
- The mixture becomes (more) red [1]
- (because the position of) equilibrium moves to the right / forward reaction is favoured [1]
- to reduce / counteract the increase in thiocyanate ion concentration [1]
🧠 Exam Technique (3-Step Formula)
- Observation: Name the new colour clearly (it shifts towards the product side, which is red).
- Direction of Shift: State whether equilibrium shifts to the left or right.
- Reasoning: State that the system acts to oppose/counteract the change (Le Chatelier's Principle).
❌ Common Errors
- Stating only that "it turns red" without explaining the shift in equilibrium.
- Writing that the colour is "colourless" because SCN⁻ is colourless, ignoring the reversible equilibrium shift.
- Vague explanations like "because more reactants are added" without referring to counteracting the change.
Question 10.3
Effect of Temperature & Deducing Enthalpy Change
✅ Correct Answer
- (The position of) equilibrium moves to the left / reverse reaction is favoured [1]
- to reduce / counteract the increase in temperature [1]
- (therefore) the forward reaction is exothermic [1]
💡 Equilibrium Temperature Rules
- An increase in temperature favours the endothermic direction (to take in heat).
- Heating caused the mixture to become yellow (Fe³⁺ side = left), so the reverse reaction must be endothermic.
- Because the reverse reaction is endothermic, the forward reaction must be exothermic.
❌ Common Errors
- Concluding the forward reaction is endothermic because the temperature was increased. Remember: look at which way it actually shifted!
- Forgetting to mention the direction of shift (moving left / towards the yellow side) and jumping straight to an unjustified conclusion.
Question 10.4
Effect of Pressure on Aqueous Systems
✅ Correct Answer
- There is no change in the equilibrium position [1]
- because no gases are present / only aqueous solutions/liquids are present [1]
💡 Key Knowledge
Pressure only alters the position of equilibrium in reactions involving gases. In aqueous solutions or liquid systems, particles are already closely packed, so changing pressure has negligible effect on concentrations.
❌ Common Errors
- Stating "there are equal moles on both sides" — this rule only applies when comparing moles of gas.
- Forgetting to state the first marking point: explicitly confirming that there is no change.
Question 10.5
Identifying Metal Ions that Form Coloured Compounds
✅ Correct Answer
☑ Co²⁺
💡 Transition Metals vs Group Metals
- Cobalt (Co): A transition element. A characteristic property of transition elements is that they form coloured compounds.
- Al³⁺, Mg²⁺, Na⁺: Main-group metals (Groups 3, 2, and 1). Their ions typically form white solids and colourless solutions.
Topics
Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter · C6: The Rate and Extent of Chemical Change
Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Higher), November 2020. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.