AQA GCSE Chemistry Chemistry Paper 2 (Higher), November 2020: Question 10

10 marks · Standard Demand difficulty · Short Answer

Explain the effects of changing concentration, temperature, and pressure on a reversible reaction between iron(III) and thiocyanate ions, and identify a transition metal ion that forms coloured complexes.

Practise this question

Question

Question 10 describes an equilibrium reaction between iron(III) ions (yellow) and thiocyanate ions (colourless) to produce FeSCN2+ ions (red), with an orange mixture at room temperature. Part 1 asks for the solvent used to dissolve the ions. Part 2 asks to explain the colour change when extra thiocyanate ions are added. Part 3 asks to explain what an increase in yellow colour upon heating shows about the energy change of the forward reaction. Part 4 asks why pressure changes do not affect the colour. Part 5 provides four checkboxes to identify which metal ion (Al3+, Co2+, Mg2+, Na+) forms coloured equilibrium mixtures.
Question text

10 This question is about a reversible reaction.

The reaction between solutions of iron(III) ions (Fe3+) and thiocyanate ions (SCN–)

is reversible.

The ionic equation for the reaction is:

Fe3+(aq) + SCN–(aq) ⇌ FeSCN2+(aq)

Colour of solution: yellow colourless red

The colour of the equilibrium mixture is orange at room temperature.

10.1 Give the name of the solvent used to dissolve the ions in this reaction.

[1 mark]

10.2 A few drops of a colourless solution containing a high concentration of

thiocyanate ions (SCN–) are added to the orange equilibrium mixture.

Explain the colour change observed.

[3 marks]

10.3 A water bath is set up at a temperature above room temperature.

When a test tube containing the orange equilibrium mixture is placed in the water

bath, the mixture becomes more yellow.

Explain what this shows about the energy change for the forward reaction.

[3 marks]

10.4 Explain why a change in pressure does not affect the colour of the equilibrium

mixture.

[2 marks]

10.5 Other metal ions form coloured equilibrium mixtures with thiocyanate ions.

Which metal ion could form a coloured equilibrium mixture with thiocyanate ions?

[1 mark]

Tick ( ) one box.

Al3+

Co2+

Mg2+

Na+

Mark scheme

Show the mark scheme Mark scheme for Question 10. 10.1: water or H2O (1 mark). 10.2: becomes more red (1 mark), equilibrium shifts right (1 mark), to counteract/reduce the increase in thiocyanate ions (1 mark). 10.3: equilibrium shifts left (1 mark), to counteract/reduce the increase in temperature (1 mark), therefore forward reaction is exothermic (1 mark). 10.4: no change in equilibrium position (1 mark) because no gases are present / only aqueous solutions are present (1 mark). 10.5: Co2+ (1 mark). Total: 10 marks.

Question 10

AO /

Question Answers Extra information Mark

Spec. Ref.

AO1

10.1 water allow H2O 1 4.2.2.2

10.2 becomes (more) red 1 AO2

4.6.2.4

4.6.2.5

(because the position of) allow (because) the 1

equilibrium moves to the right concentration of FeSCN2+ (ions)

increases

allow (because) the forward

reaction is favoured

(so that) the (increase in the) allow (so that) the increase in 1

concentration of thiocyanate the concentration of thiocyanate

(ions) is reduced (ions) is counteracted

10.3 (the position of) equilibrium allow the concentration of Fe3+ 1 AO2

moves to the left (ions) increases 4.6.2.4

4.6.2.6

allow the reverse reaction is

favoured

(so that) the (increase in the) allow (so that) the increase in 1

temperature is reduced the temperature is counteracted

(therefore) the forward reaction allow (therefore) the forward 1

is exothermic reaction releases energy (to the

surroundings)

Question 10 (continued)

AO /

Spec. Ref.

22 10.4 no change in equilibrium 1 AO2

position 4.6.2.7

(because) no gases are present allow (because) only aqueous 1

solutions are present

AO2

10.5 Co2+ 1 4.1.3.2

4.6.2.5

Total 10

How to answer it

Reversible Reactions & Le Chatelier's Principle

📋 What this question tests

This question assesses understanding of dynamic equilibria, applying Le Chatelier's principle to predict and explain shifts caused by changes in concentration, temperature, and pressure, as well as recalling characteristic properties of transition metals.

Fe³⁺(aq) [yellow] + SCN⁻(aq) [colourless] ⇌ FeSCN²⁺(aq) [red]

Question 10.1

Identifying the Solvent from State Symbols

✅ Correct Answer

Water (or H₂O )

1 Mark: AO1 (Spec ref: 4.2.2.2)

💡 Key Knowledge

The state symbol (aq) stands for aqueous, meaning a substance is dissolved in water. Water is therefore the solvent.

Question 10.2

Effect of Increasing Concentration on Equilibrium

✅ Correct Answer

  • The mixture becomes (more) red [1]
  • (because the position of) equilibrium moves to the right / forward reaction is favoured [1]
  • to reduce / counteract the increase in thiocyanate ion concentration [1]
3 Marks: AO2 (Spec ref: 4.6.2.4 & 4.6.2.5)

🧠 Exam Technique (3-Step Formula)

  1. Observation: Name the new colour clearly (it shifts towards the product side, which is red).
  2. Direction of Shift: State whether equilibrium shifts to the left or right.
  3. Reasoning: State that the system acts to oppose/counteract the change (Le Chatelier's Principle).

❌ Common Errors

  • Stating only that "it turns red" without explaining the shift in equilibrium.
  • Writing that the colour is "colourless" because SCN⁻ is colourless, ignoring the reversible equilibrium shift.
  • Vague explanations like "because more reactants are added" without referring to counteracting the change.

Question 10.3

Effect of Temperature & Deducing Enthalpy Change

✅ Correct Answer

  • (The position of) equilibrium moves to the left / reverse reaction is favoured [1]
  • to reduce / counteract the increase in temperature [1]
  • (therefore) the forward reaction is exothermic [1]
3 Marks: AO2 (Spec ref: 4.6.2.4 & 4.6.2.6)

💡 Equilibrium Temperature Rules

  • An increase in temperature favours the endothermic direction (to take in heat).
  • Heating caused the mixture to become yellow (Fe³⁺ side = left), so the reverse reaction must be endothermic.
  • Because the reverse reaction is endothermic, the forward reaction must be exothermic.

❌ Common Errors

  • Concluding the forward reaction is endothermic because the temperature was increased. Remember: look at which way it actually shifted!
  • Forgetting to mention the direction of shift (moving left / towards the yellow side) and jumping straight to an unjustified conclusion.

Question 10.4

Effect of Pressure on Aqueous Systems

✅ Correct Answer

  • There is no change in the equilibrium position [1]
  • because no gases are present / only aqueous solutions/liquids are present [1]
2 Marks: AO2 (Spec ref: 4.6.2.7)

💡 Key Knowledge

Pressure only alters the position of equilibrium in reactions involving gases. In aqueous solutions or liquid systems, particles are already closely packed, so changing pressure has negligible effect on concentrations.

❌ Common Errors

  • Stating "there are equal moles on both sides" — this rule only applies when comparing moles of gas.
  • Forgetting to state the first marking point: explicitly confirming that there is no change.

Question 10.5

Identifying Metal Ions that Form Coloured Compounds

✅ Correct Answer

☑ Co²⁺

1 Mark: AO2 (Spec ref: 4.1.3.2 & 4.6.2.5)

💡 Transition Metals vs Group Metals

  • Cobalt (Co): A transition element. A characteristic property of transition elements is that they form coloured compounds.
  • Al³⁺, Mg²⁺, Na⁺: Main-group metals (Groups 3, 2, and 1). Their ions typically form white solids and colourless solutions.

Topics

Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter · C6: The Rate and Extent of Chemical Change

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Higher), November 2020. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.