AQA GCSE Chemistry Chemistry Paper 1 (Foundation), November 2021: Question 1

10 marks · Low Demand difficulty · Multiple Choice

Identify substances, elements, and Group 0 properties, determine an empirical formula from a lattice, and calculate the surface area and surface area to volume ratio of cubic nanoparticles.

Practise this question

Question

Question 1 contains parts 01.1 to 01.8. Parts 01.1 to 01.5 are multiple-choice tick-box questions about classifying elements/compounds/mixtures and the properties of Group 0 noble gases. Part 01.6 shows Figure 1, a unit cell diagram of a metal oxide showing grey spheres for metal (X) and black spheres for oxygen (O), asking for the empirical formula XO_. Part 01.7 shows Figure 2, a cube with a side length of 2.8 nm, and asks to calculate its surface area to 2 significant figures using the given formula. Part 01.8 is a multiple-choice question comparing the surface area to volume ratio of fine and coarse particle cubes.
Question text

01 This question is about elements, compounds and mixtures.

01.1 Substance A contains only one type of atom.

Substance A does not conduct electricity.

Which type of substance is A?

[1 mark]

Tick ( ) one box.

Compound

Metallic element

Mixture

Non-metallic element

01.2 Substance B contains two types of atoms.

The atoms are chemically combined together in fixed proportions.

Which type of substance is B?

[1 mark]

Tick ( ) one box.

Compound

Metallic element

Mixture

Non-metallic element 4

01.3 What is the name of the elements in Group 0 of the periodic table?

[1 mark]

Tick ( ) one box.

Alkali metals

*03* Halogens

Noble gases

Transition metals

01.4 Which statement about the elements in Group 0 is correct?

[1 mark]

Tick ( ) one box.

All elements in the group are very reactive.

All elements in the group form negative ions.

The boiling points increase down the group.

The relative atomic masses (Ar) decrease down the group.5

01.5 Neon is in Group 0.

What type of particles are in a sample of neon?

[1 mark]

Tick ( ) one box.

Atoms

Ions

Molecules

01.6 Figure 1 represents part of the structure of an oxide of a metal.

Figure 1

Determine the empirical formula of this oxide.

[1 mark]

Empirical formula =6 XO___

A nanoparticle of a metallic element is a cube.

Figure 2 shows a diagram of the nanoparticle.

Figure 2

01.7 The surface area of a cube is given by the equation:

surface area = (length of side)2 × 6

Calculate the surface area of the cube in Figure 2.

Give your answer to 2 significant figures.

[3 marks]

Surface area (2 significant figures) =7 nm2

01.8 Fine and coarse particles of the metallic element are also cubes.

The length of a fine particle cube is 10 times smaller than the length of a

coarse particle cube.

How does the surface area to volume ratio of the fine particle cube compare with that

of the coarse particle cube?

[1 mark]

Tick ( ) one box.

*06* Both surface area to volume ratios are the same.

The surface area to volume ratio of the fine particle is 10 times greater.

The surface area to volume ratio of the fine particle is 10 times smaller.

Mark scheme

Show the mark scheme Mark scheme for Question 1: 01.1 is 'non-metallic element' (1 mark). 01.2 is 'compound' (1 mark). 01.3 is 'noble gases' (1 mark). 01.4 is 'the boiling points increase down the group' (1 mark). 01.5 is 'atoms' (1 mark). 01.6 is 'XO2' (1 mark). 01.7 awards 1 mark for (2.8)^2 x 6, 1 mark for 47.04, and 1 mark for 47 (nm^2) to 2 significant figures. 01.8 is 'the surface area to volume ratio of the fine particle is 10 times greater' (1 mark). Total: 10 marks.

Question 1

AO /

Question Answers Extra information Mark

Spec. Ref.

01.1 non-metallic element 1 AO3

4.1.1.1

4.1.2.3

AO /

Spec. Ref.

01.2 compound 1 AO1

4.1.1.1

AO /

Spec. Ref.

01.3 noble gases 1 AO1

4.1.2.4

AO /

Spec. Ref.

01.4 the boiling points increase down 1 AO1

the group 4.1.2.4

AO /

Spec. Ref.

01.5 atoms 1 AO1

4.1.2.4

AO /

Spec. Ref.

01.6 XO2 1 AO2

4.2.1.3

Question 1 continued

AO / 7

Spec. Ref.

01.7 (2.8)2 × 6 1 AO2

4.2.4.1

= 47.04 1

= 47 (nm2) allow an answer correct to 2 1

significant figures resulting from

an incorrect attempt at the

calculation

AO /

Spec. Ref.

01.8 the surface area to volume ratio 1 AO1

of the fine particle is 10 times 4.2.4.1

greater

Total 10

How to answer it

Substances, Noble Gases, and Nanoparticle Calculations

📋 Topic Summary

What this question tests

This question covers foundational concepts from AQA GCSE Chemistry specifications 4.1.1, 4.1.2, and 4.2.4:

  • Classifying matter: Distinguishing between elements (metallic vs non-metallic), compounds, and mixtures.
  • Group 0 trends & properties: Naming noble gases, physical trends down the group, and monatomic particle structure.
  • Representing structures: Deducing the empirical formula of an ionic/giant structure from a unit cell model.
  • Nanoparticle mathematics: Calculating surface area of a cube and applying rounding to significant figures; understanding how size affects surface area to volume (SA:V) ratio.
Questions 01.1 & 01.2

Classifying Substances A and B

Identifying elements and compounds from fundamental definitions

✅ Correct Choices

  • 01.1: Non-metallic element [1 mark]
  • 01.2: Compound [1 mark]

💡 Key Knowledge

  • Element: A substance consisting of only one type of atom.
  • Metallic vs Non-metallic: Metals conduct electricity because they have delocalised electrons. Non-metals generally do not conduct electricity.
  • Compound: Two or more different types of atoms chemically combined in fixed proportions.

🧠 Exam Technique

Highlight keywords in the prompt:

  • "Only one type of atom" immediately rules out Compound and Mixture.
  • "Does NOT conduct electricity" rules out Metallic element.

❌ Common Errors

Confusing compounds with mixtures. Remember: mixtures contain substances that are not chemically bonded and can be present in any proportion, whereas compounds have fixed chemical bonds.

Questions 01.3, 01.4 & 01.5

Group 0 Elements (Noble Gases)

Periodic table groups, trends, and atomic state

✅ Correct Choices

  • 01.3: Noble gases [1 mark]
  • 01.4: The boiling points increase down the group. [1 mark]
  • 01.5: Atoms [1 mark]

💡 Key Knowledge

  • Group 0 Name: Noble gases (He, Ne, Ar, Kr, Xe, Rn).
  • Group 0 Trend: As you go down the group, atoms get larger, meaning the intermolecular forces become stronger and require more thermal energy to break. Thus, boiling points increase.
  • State: Noble gases have a full outer shell of electrons (stable octet/duplet), so they exist as single, unbonded atoms (monatomic).

🧠 Exam Technique

Process of elimination for 01.4:

  • Noble gases are unreactive (inert), ruling out "very reactive".
  • They don't gain electrons easily, ruling out "form negative ions".
  • Relative atomic mass (Aᵣ) increases down the periodic table, not decreases.

❌ Common Errors

  • Ticking Molecules for 01.5. Diatomic molecules (like O₂ or Cl₂) apply to Groups 5, 6, and 7, but never Group 0.
  • Confusing Group 0 (Noble gases) with Group 7 (Halogens).
Question 01.6

Deducing Empirical Formula from a Lattice

Determining the simplest whole-number ratio from Figure 1

✅ Correct Answer

Empirical formula = XO₂

Completing the blank with: 2 [1 mark]

💡 Key Knowledge

The empirical formula gives the simplest whole-number ratio of atoms or ions of each element in a compound.

Count the visible spheres shown in the unit cell:

  • Grey circles (Metal X) = 3
  • Black circles (Oxygen O) = 6
  • Ratio: X : O = 3 : 6 = 1 : 2

❌ Common Errors

  • Writing X₃O₆ instead of simplifying to the empirical formula.
  • Writing the subscript on the metal, e.g. X₂O (inverting the ratio).
Questions 01.7 & 01.8

Nanoparticles: Surface Area & Ratio Calculations

Applying geometric formulas and significant figures

📐 Step-by-Step Calculation (01.7)

Given: length of side = 2.8 nm
Formula: Surface area = (length of side)² × 6

  1. Calculate area of one face:
    (2.8)² = 7.84 [1 mark]
  2. Multiply by 6 faces:
    7.84 × 6 = 47.04 [1 mark]
  3. Round to 2 significant figures:
    47.04 rounded to 2 s.f. = 47 [1 mark]
Surface area = 47 nm² (3 marks total)

✅ Question 01.8 Answer

The surface area to volume ratio of the fine particle is 10 times greater [1 mark]

Inverse Rule of Size: As side length decreases by a factor of n, the surface area to volume ratio increases by that same factor n.

❌ Calculation Traps & Common Errors

  • Forgetting to round: Writing 47.04 loses the final accuracy mark. Always underline "2 significant figures" in the exam paper!
  • Wrong arithmetic: Doing 2.8 × 2 instead of (2.8)² is a frequent squaring error.
  • Ratio misconception: Thinking smaller particles have smaller surface area to volume ratios. Smaller particles actually have a much larger proportion of their atoms on the surface.

🧠 Exam Technique

Notice the mark scheme allows an error carried forward (ECF):

"Allow an answer correct to 2 significant figures resulting from an incorrect attempt at the calculation."

Even if you make a calculation slip, showing clear working and rounding your answer properly guarantees you can still pick up the final significant figures mark!

Topics

Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Foundation), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.