AQA GCSE Chemistry Chemistry Paper 1 (Foundation), November 2021: Question 3

12 marks · Low Demand difficulty · Short Answer

Identify properties, trends, and reactions of Group 1 alkali metals with water, and complete dot-and-cross diagrams for the formation of sodium fluoride.

Practise this question

Question

Question 3 focuses on Group 1 elements. Part 03.1 provides Table 2 showing sodium with 11 electrons and electronic structure 2,8,1, asking to complete the electronic structure for potassium with 19 electrons. Part 03.2 is a multiple-choice question on why Group 1 elements have similar chemical properties. Part 03.3 asks to identify the type of bonding in sodium (covalent, ionic, or metallic). Parts 03.4 to 03.6 refer to Table 3 containing observations of reactions of lithium, potassium, and rubidium with water, asking for observations for sodium, the reactivity trend down Group 1, and two pieces of evidence from the table for this trend. Part 03.7 asks which gas is produced when alkali metals react with water. Part 03.8 shows electron diagrams for a sodium atom and a fluorine atom, asking students to complete the ions' electron shells and charges in square brackets for sodium fluoride.
Question text

03 This question is about Group 1 elements.

03.1 Complete Table 2 to show the electronic structure of a potassium atom.

[1 mark]

Table 2

Atom Number of electrons Electronic structure

Sodium 11 2,8,1

Potassium 19

03.2 Why do Group 1 elements have similar chemical properties?

[1 mark]

Tick ( ) one box.

They have the same number of electron shells.

They have the same number of outer shell electrons.

They have two electrons in the first shell.

03.3 What is the type of bonding in sodium?

[1 mark]

Tick ( ) one box.

Covalent

Ionic

Metallic 12

Table 3 shows observations made when lithium, potassium and rubidium react

with water.

Table 3

Element Observations

Bubbles slowly

*11*Lithium Floats

Moves slowly

Sodium

Bubbles very quickly

Melts into a ball

Potassium Floats

Moves very quickly

Flame

Sinks

Rubidium Melts into a ball

Explodes with a flame

03.4 Give two observations you could make when sodium reacts with water.

Write your answers in Table 3.

[2 marks]

03.5 How does the reactivity of the elements change going down Group 1?

[1 mark]

03.6 Give two ways in which the observations in Table 3 show the change in reactivity

going down Group 1.

[2 marks]

03.7 Which gas is produced when Group 1 elements react with water?

[1 mark]

Tick ( ) one box.

Carbon dioxide

Hydrogen

Nitrogen

Oxygen 14

03.8 Sodium fluoride is an ionic compound.

Figure 5 shows dot and cross diagrams for a sodium atom and a fluorine atom.

Complete Figure 5 to show what happens when a sodium atom and a fluorine atom

react to produce sodium fluoride.

You should:

• complete the electronic structures of the sodium ion and the fluoride ion

• give the charges on the sodium ion and the fluoride ion.

*13* [3 marks]

Figure 5

Mark scheme

Show the mark scheme The mark scheme lists answers for Question 3 totaling 12 marks: 03.1 is 2,8,8,1 (1 mark); 03.2 is 'they have the same number of outer shell electrons' (1 mark); 03.3 is 'metallic' (1 mark); 03.4 awards 2 marks for any two observations from: bubbles (very) quickly, melts into a ball, floats, moves (very) quickly; 03.5 is 'increases' (1 mark); 03.6 awards 2 marks for two trends seen in Table 3 (e.g. increasing speed of movement, rate of bubble production, melting, or flame/explosion); 03.7 is 'hydrogen' (1 mark); 03.8 awards 3 marks for sodium ion structure (2,8), fluoride ion structure (2,8), and respective charges + and -.

Question 3

AO /

Question Answers Extra information Mark

Spec. Ref.

03.1 2,8,8,1 1 AO2

4.1.1.7

AO /

Spec. Ref.

03.2 they have the same number of 1 AO1

outer shell electrons 4.1.2.1

4.1.2.5

AO /

Spec. Ref.

03.3 metallic 1 AO1

4.2.1.5

1-3

AO /

Spec. Ref.

03.4 any two from: 2 AO1

• bubbles (very) quickly 4.1.2.5

• melts (into a ball) 4.4.1.2

• floats

• moves (very) quickly

allow flame

AO /

Spec. Ref.

03.5 (reactivity) increases (down the 1 AO1

group) 4.1.2.5

Question 3 continued

AO /

Spec. Ref.

03.6 any two from: 2 AO3

• increasing speed of 4.1.2.5

movement 4.4.1.2

• increasing rate of bubble

production

• doesn’t melt → melts

• no flame → flame

or

flame → explosion

AO /

Spec. Ref.

03.7 hydrogen 1 AO1

4.1.2.5

4.4.1.2

Question 3 continued

AO /

Spec. Ref.

sodium ion structure 2,8 allow any combination of circles, 1 AO2

03.8 dots, crosses or e(–) 4.2.1.2

fluoride ion structure 2,8 1

+ charge on sodium ion and 1

– charge on fluoride ion

an answer of

12 scores 3 marks

Total 12

How to answer it

Group 1 Alkali Metals: Trends, Reactions & Bonding

📌 What This Question Tests

This question covers fundamental AQA GCSE Specification 4.1 (Atomic Structure and the Periodic Table) and 4.2 (Bonding and Structure):

  • Writing electronic configurations up to element 20 (potassium).
  • Explaining chemical properties based on outer shell electrons.
  • Identifying metallic bonding in pure elemental metals.
  • Recalling and comparing observations when alkali metals react with cold water.
  • Recognising the trend in reactivity down Group 1 using experimental evidence.
  • Drawing dot-and-cross diagrams to illustrate electron transfer and ion charges in ionic bonding.
Question 03.1 • 1 Mark

Electronic Structure of Potassium

Complete Table 2 to show the electronic structure of a potassium atom (19 electrons).

✅ Correct Answer

2,8,8,1

awarded for the exact sequence 2,8,8,1 .

💡 Key Knowledge

  • Shell 1 holds up to 2 electrons.
  • Shell 2 holds up to 8 electrons.
  • Shell 3 holds up to 8 electrons (for GCSE elements up to Calcium).
  • 2 + 8 + 8 = 18 electrons, leaving 1 electron in the 4th shell: total = 19.
Question 03.2 • 1 Mark

Group 1 Similar Chemical Properties

Why do Group 1 elements have similar chemical properties? (Tick one box)

✅ Correct Answer

☑ They have the same number of outer shell electrons.

🧠 Exam Technique

The group number on the periodic table tells you the number of electrons in an atom's outermost shell. Chemical reactions depend on losing, gaining, or sharing these valence electrons. Since all Group 1 atoms have 1 outer shell electron, they react in similar ways.

❌ Common Errors

Confusing shells with outer electrons. They do not have the same number of total shells—each step down the group adds a new shell!

Question 03.3 • 1 Mark

Bonding in Elemental Sodium

What is the type of bonding in sodium? (Tick one box)

✅ Correct Answer

☑ Metallic

❌ Examiner Pitfall

Many students see "sodium" and instantly tick ionic because sodium forms ions in compounds. However, the question asks about sodium on its own (an element). A pure metal atom lattice held together by delocalised electrons has metallic bonding.

Question 03.4 • 2 Marks

Observations: Sodium Reacting with Water

Give two observations you could make when sodium reacts with water.

✅ Correct Answers (Any two)

  • Melts into a ball
  • Floats on the water
  • Moves (very) quickly / darts on the surface
  • Bubbles / effervescence / fizzing (very quickly)
  • Also allowed: burns with a yellow/orange flame
1 mark for each valid observation (max 2 marks).

🧠 Observation vs Theory

An observation is something you can see, hear, or feel. Never write names of invisible products such as "hydrogen gas is made" or "sodium hydroxide forms". Write what you physically witness: fizzing/bubbles, floating, or melting into a shiny sphere.

Question 03.5 & 03.6 • 3 Marks Total

Reactivity Trends in Group 1

03.5 How does reactivity change going down Group 1? [1 mark]

03.6 Give two ways in which the observations in Table 3 show the change in reactivity going down Group 1. [2 marks]

✅ Correct Answers

03.5: Reactivity increases down the group. [1 mark]

03.6 (Any two comparative points):

  • Speed of movement increases (e.g. moves slowly with Li → moves very quickly with K).
  • Rate of bubbling increases (e.g. bubbles slowly with Li → bubbles very quickly with K).
  • Lithium does not melt → sodium/potassium melts into a ball.
  • No flame produced for Li → flame appears for K → explosion for Rb.

🧠 Exam Technique: Making Comparisons

For question 03.6, you must link the trend to the table data by showing a progression or change. Do not just restate what one metal does in isolation. Mention the contrast or use comparative words like "faster", "more vigorous", or "Li doesn't melt whereas Na and K do".

Question 03.7 • 1 Mark

Gas Produced in Alkali Metal + Water Reactions

Which gas is produced when Group 1 elements react with water? (Tick one box)

✅ Correct Answer

☑ Hydrogen

💡 Standard Word Equation

Alkali Metal + Water → Metal Hydroxide + Hydrogen

Example: 2Na + 2H₂O → 2NaOH + H₂

The hydrogen gas catches fire with potassium due to the high heat released!

Question 03.8 • 3 Marks

Dot-and-Cross Diagram: Sodium Fluoride Formation

Complete Figure 5 to show what happens when a sodium atom and a fluorine atom react.

Visual Description of the Correct Diagram:
  • Sodium ion: Inner shell contains 2 dots; second shell contains 8 dots; outermost 3rd shell is left empty (or omitted). Surrounded by square brackets with a + (or 1+) charge at the top right.
  • Fluoride ion: Inner shell contains 2 crosses; outer shell contains 7 crosses and 1 dot (showing the transferred electron from sodium). Surrounded by square brackets with a − (or 1−) charge at the top right.

✅ Mark Scheme Breakdown

  • Mark 1: Sodium ion has an electronic structure of 2,8 .
  • Mark 2: Fluoride ion has an electronic structure of 2,8 (showing 1 transferred electron).
  • Mark 3: Correct charges: + on the sodium ion AND − on the fluoride ion.

❌ Common Errors

  • Omitting charges: Forgetting to write the + and − outside the brackets. Both charges are required to secure the 3rd mark!
  • Wrong symbol type: Drawing the transferred electron as another cross instead of a dot (or circle), making it impossible to see electron transfer.
  • Leaving the 3rd shell: Leaving an electron on sodium's 3rd shell instead of transferring it completely.

Topics

Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter · C4: Chemical Changes

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Foundation), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.