AQA GCSE Chemistry Chemistry Paper 1 (Higher), November 2021: Question 1

11 marks · Standard Demand difficulty · Extended Answer

Answer questions on the structure, bonding, and properties of fullerenes, propanone, and graphite.

Practise this question

Question

Question 01 contains parts 01.1 to 01.6. Question 01.1 asks for the shape of a Buckminsterfullerene molecule. Question 01.2 asks for one use of a fullerene. Figure 1 shows a dot and cross diagram of propanone showing three carbon atoms, one oxygen atom, and six hydrogen atoms. Question 01.3 provides Figure 2, an incomplete displayed formula showing a central carbon atom double-bonded to an oxygen atom, and asks to complete the molecule using single bonds. Question 01.4 asks to determine the molecular formula of propanone. Question 01.5 asks to select why propanone has a low boiling point from four options involving covalent bonds or intermolecular forces being strong or weak. Figure 3 shows three planar layers of hexagonal carbon rings representing graphite, and Question 01.6 asks for an explanation in terms of structure and bonding of why graphite is a good electrical conductor and soft and slippery (6 marks).
Question text

01 This question is about carbon and its compounds.

Fullerenes are molecules of carbon atoms.

The first fullerene to be discovered was Buckminsterfullerene (C60).

01.1 What shape is a Buckminsterfullerene molecule?

[1 mark]

01.2 Give one use of a fullerene.

[1 mark]

Propanone is a compound of carbon, hydrogen and oxygen.

Figure 1 shows the dot and cross diagram for a propanone molecule.

Figure 1

01.3 Complete Figure 2 to show a propanone molecule.

Use a line to represent each single bond.

Use Figure 1.

[1 mark]

Figure 2

01.4 Determine the molecular formula of propanone.

Use Figure 1.

[1 mark]

Molecular formula =

01.5 Propanone is a liquid with a low boiling point.

Why does propanone have a low boiling point?

[1 mark]

Tick ( ) one box.

The covalent bonds are strong.

The covalent bonds are weak.

The intermolecular forces are strong.

The intermolecular forces are weak.4

01.6 Figure 3 represents the structure of graphite.

Figure 3

Explain why graphite is:

• a good electrical conductor

• soft and slippery.

You should answer in terms of structure and bonding.

[6 marks]

Mark scheme

Show the mark scheme Mark scheme for Question 01: 01.1 accepts 'spherical' (allow ball-shaped, 1 mark). 01.2 accepts drug delivery, hydrogen storage, anti-oxidants, reduction of bacterial growth, catalysts, lubricants, or strengthening materials (1 mark). 01.3 shows the completed displayed formula of propanone with two methyl groups attached to the carbonyl group (1 mark). 01.4 accepts C3H6O or CH3COCH3 (1 mark). 01.5 awards 1 mark for 'the intermolecular forces are weak'. 01.6 provides a 3-level mark scheme (up to 6 marks) with indicative content detailing giant covalent structure, three bonds per carbon, delocalised electrons that carry electrical charge, and hexagonal layers with weak intermolecular forces that allow layers to slide.

Question 1

AO /

Question Answers Extra information Mark

Spec. Ref.

01.1 spherical allow ball-shaped 1 AO1

ignore round / circular 4.2.3.3

AO /

Spec. Ref.

01.2 any one from: 1 AO1

• drug delivery (round the body) 4.2.3.3

• hydrogen storage

• anti-oxidants

• reduction of bacterial growth

• catalysts

• (cylindrical fullerenes for)

strengthening materials

• (spherical fullerenes for)

lubricants

AO /

Spec. Ref.

01.3 1 AO2

4.2.1.4

AO /

Spec. Ref.

01.4 C3H6O allow CH3COCH3 1 AO2

allow elements in any order–HEMISTRY – – 4.2.1.4

Question 1 continued

AO /

Spec. Ref.

01.5 the intermolecular forces are 1 AO1

weak 4.2.2.1

4.2.2.4 7

AO/

Question Answers Mark

Spec. Ref

Level 3: Relevant points (reasons/causes) are identified, given in 5–6 AO1

01.6

detail and logically linked to form a clear account. 4.2.2.6

4.2.3.2

Level 2: Relevant points (reasons/causes) are identified, and there

3–4

are attempts at logical linking. The resulting account is not fully

clear.

Level 1: Points are identified and stated simply, but their relevance

1–2

is not clear and there is no attempt at logical linking.

No relevant content 0

Indicative content

• bonds are covalent

• giant / macromolecular structure

• three (covalent) bonds per carbon atom

or

only three electrons per carbon atom used in (covalent) bonds

• so one electron per carbon atom (is delocalised)

• these delocalised electrons

• can move through the structure

• carrying (electrical) charge

• so graphite conducts electricity

• layered structure

• of (interlocking) hexagonal rings

• with weak (intermolecular) forces between layers

or

no (covalent) bonds between layers

• so the layers can slide over each other

• so graphite is soft and slippery

Total 11

How to answer it

Carbon Chemistry: Fullerenes, Covalent Molecules & Graphite

AQA GCSE Chemistry • Structure, Bonding and the Properties of Matter

What This Question Tests

  • Recall of allotropes of carbon: The shape and real-world uses of fullerenes (Buckminsterfullerene, C₆₀).
  • Covalent representations: Interpreting dot-and-cross diagrams and drawing displayed formula structures.
  • Molecular formulas: Counting constituent atoms from a molecular structure.
  • Physical properties of small molecules: Explaining low boiling points in terms of weak intermolecular forces.
  • Extended scientific explanation (6 marks): Linking the giant covalent structure and bonding of graphite directly to electrical conductivity and slipperiness.
Question 01.1 • 1 Mark

Shape of a Buckminsterfullerene Molecule

What shape is a Buckminsterfullerene molecule?

✅ Correct Answer

Spherical (or ball-shaped).

🧠 Exam Technique

Buckminsterfullerene (C₆₀) is a hollow sphere resembling a football made from pentagons and hexagons of carbon atoms.

❌ Common Errors

Do not write "round" or "circular". These describe two-dimensional circles, whereas fullerenes are three-dimensional spheres.

💡 Key Knowledge

Fullerenes are molecules of carbon atoms with hollow shapes based on hexagonal rings, but they can also contain rings of 5 or 7 carbon atoms.

Mark Scheme: spherical [1]. Allow: ball-shaped. Ignore: round / circular.
Question 01.2 • 1 Mark

Uses of Fullerenes

Give one use of a fullerene.

✅ Acceptable Answers (Give ANY one)

  • Drug delivery (into specific cells in the body)
  • Lubricant (spherical molecules roll over each other)
  • Catalysts (large surface area to volume ratio)
  • Hydrogen storage
  • Anti-oxidants
  • Strengthening materials (carbon nanotubes)

❌ Common Errors

Vague answers like "for medicine" or "used in cars" do not gain credit. Be precise: specify "drug delivery" or "lubricant".

Mark Scheme: Any one from: drug delivery (round the body) / hydrogen storage / anti-oxidants / reduction of bacterial growth / catalysts / strengthening materials / lubricants [1].
Question 01.3 • 1 Mark

Completing the Displayed Structure of Propanone

Complete Figure 2 to show a propanone molecule using a line for each single bond.

✅ Correct Answer

Add two carbon atoms bonded to the central C, each with 3 attached H atoms via single lines:

H H | | H - C - C - C - H | || | H O H

🧠 How to Check Your Drawing

Count the bonds on every atom:

  • Each Carbon (C) must have exactly 4 lines (4 bonds).
  • Each Hydrogen (H) must have exactly 1 line (1 bond).
  • The Oxygen (O) already has a double bond (=) attached to the central C.

❌ Common Errors

Forgetting one of the end hydrogen atoms or drawing bonds directly between hydrogens and oxygen.

Mark Scheme: Fully correct displayed formula with both -CH₃ groups single-bonded to the central C=O carbon [1].
Question 01.4 • 1 Mark

Molecular Formula of Propanone

Determine the molecular formula of propanone from Figure 1.

✅ Correct Answer

C₃H₆O (or CH₃COCH₃)

🧠 Systematic Counting

Look at the dot-and-cross diagram and count the chemical symbols:

  • Carbon atoms (C): 1 left + 1 centre + 1 right = 3
  • Hydrogen atoms (H): 3 left + 3 right = 6
  • Oxygen atoms (O): 1 bottom = 1

❌ Common Errors

Writing charges or improper subscript formatting (e.g. C3H6O without subscripts, though examiners allow it if clearly intended, standard subscript format is expected). Mixing up hydrogen count by missing peripheral H circles.

Mark Scheme: C₃H₆O [1]. Allow: CH₃COCH₃. Allow: elements in any order (e.g., H₆C₃O).
Question 01.5 • 1 Mark

Why Propanone Has a Low Boiling Point

Tick (✓) one box to explain why propanone is a liquid with a low boiling point.

✅ Correct Box

☑ The intermolecular forces are weak.

❌ Number One GCSE Misconception

Never tick "covalent bonds are weak"! Covalent bonds are extremely strong, but they do not break when propanone boils. Only the weak forces between molecules (intermolecular forces) are overcome.

Mark Scheme: the intermolecular forces are weak [1].
Question 01.6 • 6 Marks

Structure and Properties of Graphite

Explain why graphite is a good electrical conductor AND soft and slippery. Answer in terms of structure and bonding.

Level Marks Description
Level 3 5–6 Relevant points for both properties are identified, given in detail, and logically linked to structure and bonding.
Level 2 3–4 Points for both properties are identified with some logical linking, OR one property is explained in full detail.
Level 1 1–2 Isolated points stated simply without clear logical links to bonding/structure.

💡 Part 1: Why Graphite Conducts Electricity

  1. Graphite has a giant covalent structure.
  2. Each carbon atom forms only three covalent bonds.
  3. This leaves one delocalised electron per carbon atom.
  4. These delocalised electrons are free to move through the layers.
  5. They carry electrical charge through the structure.

💡 Part 2: Why Graphite is Soft and Slippery

  1. Carbon atoms form layers of hexagonal rings.
  2. There are weak intermolecular forces between the layers (no covalent bonds between layers).
  3. Because these forces are weak, the layers can slide over each other easily.

🧠 Top-Level Structure (Full 6/6 Template)

Structure your answer into two distinct paragraphs using connective phrases:

"Graphite is an electrical conductor because each carbon atom forms 3 covalent bonds, leaving one electron per atom delocalised. These delocalised electrons can move throughout the structure carrying electric charge."

"Graphite is soft and slippery because it is arranged in layers of hexagonal rings with only weak forces between layers. This means the layers can easily slide over one another."

❌ Costly Mistakes to Avoid

  • Saying "ions move": Graphite contains neutral carbon atoms and delocalised electrons, not ions!
  • Saying "covalent bonds break": The covalent bonds within layers are very strong and do not break when graphite is rubbed.
  • Covering only one property: If you only explain conduction, you are capped at Level 2 (max 4 marks). Always address both bullet points!
Indicative Content:
Structure & Bonding: Giant/macromolecular covalent structure; layers of hexagonal rings.
Conduction: 3 covalent bonds per C atom → 1 delocalised electron per atom → free to move through structure → carries electrical charge.
Slippery: Weak forces / no covalent bonds between layers → layers can slide over each other.

Topics

Chemistry · C2: Bonding, Structure and the Properties of Matter

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Higher), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.