AQA GCSE Chemistry Chemistry Paper 1 (Higher), November 2021: Question 1
11 marks · Standard Demand difficulty · Extended Answer
Answer questions on the structure, bonding, and properties of fullerenes, propanone, and graphite.
Practise this questionQuestion
Question text
01 This question is about carbon and its compounds.
Fullerenes are molecules of carbon atoms.
The first fullerene to be discovered was Buckminsterfullerene (C60).
01.1 What shape is a Buckminsterfullerene molecule?
[1 mark]
01.2 Give one use of a fullerene.
[1 mark]
Propanone is a compound of carbon, hydrogen and oxygen.
Figure 1 shows the dot and cross diagram for a propanone molecule.
Figure 1
01.3 Complete Figure 2 to show a propanone molecule.
Use a line to represent each single bond.
Use Figure 1.
[1 mark]
Figure 2
01.4 Determine the molecular formula of propanone.
Use Figure 1.
[1 mark]
Molecular formula =
01.5 Propanone is a liquid with a low boiling point.
Why does propanone have a low boiling point?
[1 mark]
Tick ( ) one box.
The covalent bonds are strong.
The covalent bonds are weak.
The intermolecular forces are strong.
The intermolecular forces are weak.4
01.6 Figure 3 represents the structure of graphite.
Figure 3
Explain why graphite is:
• a good electrical conductor
• soft and slippery.
You should answer in terms of structure and bonding.
[6 marks]
Mark scheme
Show the mark scheme
Question 1
AO /
Question Answers Extra information Mark
Spec. Ref.
01.1 spherical allow ball-shaped 1 AO1
ignore round / circular 4.2.3.3
AO /
Spec. Ref.
01.2 any one from: 1 AO1
• drug delivery (round the body) 4.2.3.3
• hydrogen storage
• anti-oxidants
• reduction of bacterial growth
• catalysts
• (cylindrical fullerenes for)
strengthening materials
• (spherical fullerenes for)
lubricants
AO /
Spec. Ref.
01.3 1 AO2
4.2.1.4
AO /
Spec. Ref.
01.4 C3H6O allow CH3COCH3 1 AO2
allow elements in any order–HEMISTRY – – 4.2.1.4
Question 1 continued
AO /
Spec. Ref.
01.5 the intermolecular forces are 1 AO1
weak 4.2.2.1
4.2.2.4 7
AO/
Question Answers Mark
Spec. Ref
Level 3: Relevant points (reasons/causes) are identified, given in 5–6 AO1
01.6
detail and logically linked to form a clear account. 4.2.2.6
4.2.3.2
Level 2: Relevant points (reasons/causes) are identified, and there
3–4
are attempts at logical linking. The resulting account is not fully
clear.
Level 1: Points are identified and stated simply, but their relevance
1–2
is not clear and there is no attempt at logical linking.
No relevant content 0
Indicative content
• bonds are covalent
• giant / macromolecular structure
• three (covalent) bonds per carbon atom
or
only three electrons per carbon atom used in (covalent) bonds
• so one electron per carbon atom (is delocalised)
• these delocalised electrons
• can move through the structure
• carrying (electrical) charge
• so graphite conducts electricity
• layered structure
• of (interlocking) hexagonal rings
• with weak (intermolecular) forces between layers
or
no (covalent) bonds between layers
• so the layers can slide over each other
• so graphite is soft and slippery
Total 11
How to answer it
Carbon Chemistry: Fullerenes, Covalent Molecules & Graphite
What This Question Tests
- Recall of allotropes of carbon: The shape and real-world uses of fullerenes (Buckminsterfullerene, C₆₀).
- Covalent representations: Interpreting dot-and-cross diagrams and drawing displayed formula structures.
- Molecular formulas: Counting constituent atoms from a molecular structure.
- Physical properties of small molecules: Explaining low boiling points in terms of weak intermolecular forces.
- Extended scientific explanation (6 marks): Linking the giant covalent structure and bonding of graphite directly to electrical conductivity and slipperiness.
Shape of a Buckminsterfullerene Molecule
What shape is a Buckminsterfullerene molecule?
✅ Correct Answer
Spherical (or ball-shaped).
🧠 Exam Technique
Buckminsterfullerene (C₆₀) is a hollow sphere resembling a football made from pentagons and hexagons of carbon atoms.
❌ Common Errors
Do not write "round" or "circular". These describe two-dimensional circles, whereas fullerenes are three-dimensional spheres.
💡 Key Knowledge
Fullerenes are molecules of carbon atoms with hollow shapes based on hexagonal rings, but they can also contain rings of 5 or 7 carbon atoms.
Uses of Fullerenes
Give one use of a fullerene.
✅ Acceptable Answers (Give ANY one)
- Drug delivery (into specific cells in the body)
- Lubricant (spherical molecules roll over each other)
- Catalysts (large surface area to volume ratio)
- Hydrogen storage
- Anti-oxidants
- Strengthening materials (carbon nanotubes)
❌ Common Errors
Vague answers like "for medicine" or "used in cars" do not gain credit. Be precise: specify "drug delivery" or "lubricant".
Completing the Displayed Structure of Propanone
Complete Figure 2 to show a propanone molecule using a line for each single bond.
✅ Correct Answer
Add two carbon atoms bonded to the central C, each with 3 attached H atoms via single lines:
🧠 How to Check Your Drawing
Count the bonds on every atom:
- Each Carbon (C) must have exactly 4 lines (4 bonds).
- Each Hydrogen (H) must have exactly 1 line (1 bond).
- The Oxygen (O) already has a double bond (=) attached to the central C.
❌ Common Errors
Forgetting one of the end hydrogen atoms or drawing bonds directly between hydrogens and oxygen.
Molecular Formula of Propanone
Determine the molecular formula of propanone from Figure 1.
✅ Correct Answer
C₃H₆O (or CH₃COCH₃)
🧠 Systematic Counting
Look at the dot-and-cross diagram and count the chemical symbols:
- Carbon atoms (C): 1 left + 1 centre + 1 right = 3
- Hydrogen atoms (H): 3 left + 3 right = 6
- Oxygen atoms (O): 1 bottom = 1
❌ Common Errors
Writing charges or improper subscript formatting (e.g. C3H6O without subscripts, though examiners allow it if clearly intended, standard subscript format is expected). Mixing up hydrogen count by missing peripheral H circles.
Why Propanone Has a Low Boiling Point
Tick (✓) one box to explain why propanone is a liquid with a low boiling point.
✅ Correct Box
☑ The intermolecular forces are weak.
❌ Number One GCSE Misconception
Never tick "covalent bonds are weak"! Covalent bonds are extremely strong, but they do not break when propanone boils. Only the weak forces between molecules (intermolecular forces) are overcome.
Structure and Properties of Graphite
Explain why graphite is a good electrical conductor AND soft and slippery. Answer in terms of structure and bonding.
| Level | Marks | Description |
|---|---|---|
| Level 3 | 5–6 | Relevant points for both properties are identified, given in detail, and logically linked to structure and bonding. |
| Level 2 | 3–4 | Points for both properties are identified with some logical linking, OR one property is explained in full detail. |
| Level 1 | 1–2 | Isolated points stated simply without clear logical links to bonding/structure. |
💡 Part 1: Why Graphite Conducts Electricity
- Graphite has a giant covalent structure.
- Each carbon atom forms only three covalent bonds.
- This leaves one delocalised electron per carbon atom.
- These delocalised electrons are free to move through the layers.
- They carry electrical charge through the structure.
💡 Part 2: Why Graphite is Soft and Slippery
- Carbon atoms form layers of hexagonal rings.
- There are weak intermolecular forces between the layers (no covalent bonds between layers).
- Because these forces are weak, the layers can slide over each other easily.
🧠 Top-Level Structure (Full 6/6 Template)
Structure your answer into two distinct paragraphs using connective phrases:
"Graphite is an electrical conductor because each carbon atom forms 3 covalent bonds, leaving one electron per atom delocalised. These delocalised electrons can move throughout the structure carrying electric charge."
"Graphite is soft and slippery because it is arranged in layers of hexagonal rings with only weak forces between layers. This means the layers can easily slide over one another."
❌ Costly Mistakes to Avoid
- Saying "ions move": Graphite contains neutral carbon atoms and delocalised electrons, not ions!
- Saying "covalent bonds break": The covalent bonds within layers are very strong and do not break when graphite is rubbed.
- Covering only one property: If you only explain conduction, you are capped at Level 2 (max 4 marks). Always address both bullet points!
Structure & Bonding: Giant/macromolecular covalent structure; layers of hexagonal rings.
Conduction: 3 covalent bonds per C atom → 1 delocalised electron per atom → free to move through structure → carries electrical charge.
Slippery: Weak forces / no covalent bonds between layers → layers can slide over each other.
Topics
Chemistry · C2: Bonding, Structure and the Properties of Matter
Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Higher), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.