AQA GCSE Chemistry Chemistry Paper 1 (Foundation), June 2022: Question 5

9 marks · Low Demand difficulty · Short Answer

Identify products and variables, analyse anomalous data, and plot a graph for the reaction between magnesium and hydrochloric acid.

Practise this question

Question

The question shows an investigation of the reaction between magnesium ribbon and 25 cm³ of hydrochloric acid in a conical flask connected to a gas syringe via a delivery tube. Part 05.1 asks to tick the gas produced from four options (Carbon dioxide, Chlorine, Hydrogen, Oxygen). Parts 05.2 and 05.3 ask for the independent variable and one control variable. Part 05.4 and 05.5 present Table 5 containing gas volumes for four trials (19, 36, 37, 32 cm³) and ask to identify and explain an anomalous result. Part 05.6 presents Table 6 with magnesium lengths from 10 to 60 mm and mean gas volumes from 7 to 42 cm³, asking students to plot the data on Figure 8 and draw a line of best fit. Part 05.7 asks to complete a sentence describing the relationship.
Question text

05 A student investigated the reaction of magnesium with hydrochloric acid.

Figure 7 shows the apparatus used.

Figure 7

This is the method used.

1. Set up the apparatus as shown in Figure 7.

2. Cut 10 mm of magnesium ribbon.

3. Remove the stopper.

4. Add the magnesium ribbon to the conical flask.

5. Replace the stopper as quickly as possible.

6. Record the final reading on the gas syringe when the reaction has stopped.

7. Repeat steps 1 to 6 three more times.

8. Repeat steps 1 to 7 with different lengths of magnesium ribbon.

05.1 Which gas is produced when magnesium reacts with hydrochloric acid?

[1 mark]

Tick ( ) one box.

Carbon dioxide

Chlorine

Hydrogen

Oxygen

05.2 What was the independent variable in the investigation?

[1 mark]

05.3 Give one control variable in the investigation.

[1 mark]

Table 5 shows the results for one length of magnesium ribbon.

Table 5

Trial 1 Trial 2 Trial 3 Trial 4

Volume of gas

3 19 36 37 32

produced in cm

One of the results was anomalous.

05.4 Which trial in Table 5 gave an anomalous result?

[1 mark]

Trial

*0195.*5 Suggest one reason for the anomalous result in Table 5.

[1 mark]

05.6 Table 6 shows the mean volume of gas produced for each length of

magnesium ribbon.

Table 6

Length of magnesium ribbon in mm 10 20 30 40 50 60

Mean volume of gas produced in cm3 7 14 21 28 35 42

Plot the data from Table 6 on Figure 8.

Draw a line of best fit.

[3 marks]

Figure 8

05.7 Complete the sentence.

[1 mark]

As the length of the magnesium ribbon increases, the mean volume of gas produced

.

Mark scheme

Show the mark scheme The mark scheme lists the answers for Question 5: 05.1 is hydrogen (1 mark); 05.2 is length of magnesium ribbon (1 mark); 05.3 is volume or concentration of acid, or width/thickness of ribbon, or temperature (1 mark); 05.4 is trial 1 or 19 cm³ (1 mark); 05.5 allows gas escaping, leak, reaction unfinished, less acid, or shorter ribbon (1 mark); 05.6 awards 2 marks for all six points correctly plotted (1 mark for 4 or 5 points) and 1 mark for a straight line of best fit through the origin; 05.7 is increases (1 mark). Total 9 marks, all referencing spec 4.4.2.1.

Question 5

AO /

Question Answers Extra information Mark

Spec. Ref.

05.1 hydrogen 1 AO1

4.4.2.1

AO /

Spec. Ref.

05.2 length of magnesium ribbon 1 AO2

4.4.2.1

AO /

Spec. Ref.

05.3 any one from: 1 AO3

• volume of (hydrochloric) acid 4.4.2.1

• concentration of (hydrochloric)

acid

• width / thickness of

magnesium ribbon

allow temperature of

(hydrochloric) acid

allow temperature of solution

AO /

Spec. Ref.

(trial) 1 allow 19 (cm3) 1 AO3

05.4

4.4.2.1

AO /

Spec. Ref.

05.5 any one from: 1 AO3

16 • some gas escaped before the allow the stopper was not 4.4.2.1

stopper was put in replaced quickly enough

• apparatus leaked

• reaction not finished (when

reading taken)

• less than 25cm3 of

(hydrochloric) acid used

• magnesium (ribbon) not long

enough

AO /

Spec. Ref.

05.6 all six points correctly plotted allow a tolerance of ± ½ a small 2 AO2

square 4.4.2.1

View with

Figure 8

allow 1 mark for four or five

points correctly plotted

line of best fit 1

AO /

Spec. Ref.

05.7 increases 1 AO2

4.4.2.1

Total Question 5 9

How to answer it

Reaction of Magnesium with Hydrochloric Acid (Rate & Gas Production)

📋 What This Question Tests

This question assesses fundamental practical skills and chemical knowledge from AQA Specification Section 4.4.2 (Reactions of Acids):

  • Chemical Recall: Identifying the gas formed when a reactive metal reacts with an acid (metal + acid → salt + hydrogen).
  • Working Scientifically (Variables): Correctly identifying independent, dependent, and control variables in a laboratory investigation.
  • Data Analysis: Spotting anomalous results from repeated experimental trials and explaining likely sources of practical error.
  • Graph Skills: Accurately plotting points on a linear scale, drawing a straight line of best fit through the origin, and describing trends.
Part 05.1

Product of Acid-Metal Reaction

Identifying the gas released

✅ Correct Answer

Tick the box next to: Hydrogen [1 mark]

💡 Key Knowledge

General equation for acid + metal:

metal + acid → salt + hydrogen

Here: Mg + 2HCl → MgCl₂ + H₂

Carbon dioxide is only released if a carbonate is used.

❌ Common Errors

  • Ticking Chlorine just because hydrochloric acid was used. Acid-metal reactions release hydrogen gas, never chlorine!
  • Ticking Oxygen or Carbon dioxide.
Mark breakdown: 1 mark for selecting 'Hydrogen' only.
Part 05.2

Experimental Variables: Independent Variable

Identifying what is changed by the investigator

✅ Correct Answer

Length of magnesium ribbon [1 mark]

🧠 Exam Technique

Look at the method: step 8 states "Repeat steps 1 to 7 with different lengths of magnesium ribbon."

The variable the experimenter deliberately changes across comparisons is the independent variable.

❌ Common Errors

  • Writing just "magnesium" (too vague – must specify length or mass).
  • Confusing independent with dependent variable (writing "volume of gas").
Mark breakdown: 1 mark for stating "length of magnesium ribbon".
Part 05.3

Experimental Variables: Control Variable

Identifying what must be kept constant for a fair test

✅ Correct Answer (Any one from)

  • Volume of (hydrochloric) acid
  • Concentration of (hydrochloric) acid
  • Width / thickness of magnesium ribbon
  • Temperature of acid / solution

[1 mark]

🧠 Exam Technique

Always specify the property of the substance, not just its name:

  • Say "concentration of acid", not just "the acid".
  • Say "width/thickness of ribbon", not just "magnesium".

❌ Common Errors

  • Writing "amount of acid" – this is too vague. State volume or concentration.
  • Stating "length of magnesium ribbon" – that is the variable being changed!
Mark breakdown: 1 mark for any valid control variable clearly stated.
Part 05.4

Data Analysis: Spotting the Anomaly

Reviewing repeated trials in Table 5

✅ Correct Answer

Trial 1 (or 19 cm³) [1 mark]

💡 Key Knowledge

Look at the four trials:

Trial 1: 19 | Trial 2: 36 | Trial 3: 37 | Trial 4: 32

Trials 2, 3, and 4 cluster closely in the thirties (32–37 cm³). Trial 1 (19 cm³) is substantially lower and does not fit the pattern.

🧠 Exam Technique

An anomalous result is a value that differs significantly from the other repeats under the same conditions. Identifying it simply requires comparing the numbers side by side.

Mark breakdown: 1 mark for identifying Trial 1 (or writing 19).
Part 05.5

Explaining Experimental Errors

Suggesting reasons for an unusually low gas volume

✅ Correct Answer (Any one from)

  • Gas escaped before the stopper was put in / stopper was not replaced quickly enough
  • Apparatus leaked (e.g. around the delivery tube or stopper)
  • Reaction had not finished when reading was taken
  • Less than 25 cm³ of acid was used
  • Magnesium ribbon was cut too short (less than 10 mm / not long enough)

[1 mark]

🧠 Exam Technique

Notice that Trial 1 gave a smaller volume than expected (19 cm³ vs ~35 cm³). Therefore, your reason must explain why less gas was collected.

The most common and highest-scoring explanation in gas collection experiments is gas escaping before replacing the bung.

❌ Common Errors

  • Giving a reason that would cause a higher volume (e.g. "used too much magnesium" or "temperature was too high").
  • Saying "human error" or "measured incorrectly" without stating what actually went wrong. Examiner tip: generic "human error" never gets credit!
Mark breakdown: 1 mark for a specific, realistic cause resulting in a reduced gas reading.
Part 05.6

Graph Skills: Plotting and Line of Best Fit

Plotting data from Table 6 on Figure 8

✅ Required Plotting & Best Fit

  • All 6 points plotted correctly: [2 marks]
    (10, 7), (20, 14), (30, 21), (40, 28), (50, 35), (60, 42)
    (Allow 1 mark for 4 or 5 points correctly plotted; tolerance is ± ½ a small square)
  • Line of best fit: [1 mark]
    A sharp, single straight line drawn with a ruler passing directly through (0,0) and matching the trend of all points.

📐 Grid Scale Breakdown

X-axis: 10 small squares = 10 mm → 1 small square = 1 mm

Y-axis: 10 small squares = 10 cm³ → 1 small square = 1 cm³

This 1:1 ratio makes counting easy! For example, for 30 mm, count up 21 small squares (one square above 20).

❌ Common Errors

  • Plotting large "blobs" instead of neat crosses (×) or small dots with circles (⊙). If the blob covers more than 1 small square, you may lose marks.
  • Drawing a sketchy, "furry", or freehand line instead of using a clear, clean ruler.
  • Connecting points dot-to-dot instead of drawing a single straight line of best fit.
Mark breakdown: 2 marks for plotting all 6 points correctly (1 mark for 4–5 points) + 1 mark for a clean ruler-drawn line of best fit. Total = 3 marks.
Part 05.7

Describing Trends

Completing the conclusion sentence

✅ Correct Answer

"As the length of the magnesium ribbon increases, the mean volume of gas produced..."

increases [1 mark]

💡 Key Knowledge

More magnesium ribbon provides more reactant particles (more moles of Mg), which produce a greater volume of hydrogen gas when reacted with excess acid.

Since the line is straight through the origin, it is actually directly proportional, but "increases" is all that is required to complete the sentence.

🧠 Exam Technique

Always check whether the question asks you to "complete the sentence" or "describe the relationship in detail". Here, a single comparative word like increases fulfills the sentence grammatically and scientifically.

Mark breakdown: 1 mark for "increases".

Topics

Chemistry · C4: Chemical Changes

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Foundation), June 2022. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.