AQA GCSE Chemistry Chemistry Paper 2 (Foundation), June 2022: Question 3

10 marks · Low Demand difficulty · Short Answer

Answer questions about the evolution and composition of the Earth's atmosphere, including calculating the percentage of nitrogen, processes changing atmospheric gases, and reading data from a graph.

Practise this question

Question

The question presents Table 5 showing estimated percentages of gases in the early atmosphere versus today: Nitrogen (1.8% early, X today), Oxygen (0.2% early, 20.95% today), Carbon dioxide (96.0% early, 0.04% today), Other gases (2.0% early, 0.92% today). Part 03.1 asks to calculate X. Parts 03.2 to 03.4 ask multiple-choice questions about early atmospheric gases, photosynthesis, and processes that decreased carbon dioxide. Figure 3 displays a line graph showing the percentage of carbon dioxide, nitrogen, and oxygen over time from 4500 million years ago to present day. Parts 03.5 and 03.6 ask to read values from Figure 3. Part 03.7 asks for the biomass source of crude oil, and 03.8 asks why scientists use estimated values for the data.
Question text

03 This question is about the Earth’s atmosphere.

Table 5 shows:

• the estimated percentages of gases in the Earth’s early atmosphere

• the percentages of gases in the Earth’s atmosphere today.

Table 5

Estimated percentage (%) in Percentage (%) in the

Gas

the Earth’s early atmosphere Earth’s atmosphere today

Nitrogen 1.8 X

Oxygen 0.2 20.95

Carbon dioxide 96.0 0.04

Other gases 2.0 0.92

03.1 Calculate value X in Table 5.

[1 mark]

X = %

03.2 Which two other gases may have been in the Earth’s early atmosphere?

[2 marks]

Tick ( ) two boxes.

Ammonia

Coal

Limestone

Methane

Poly(ethene) 13

Algae and plants increased the percentage of oxygen in the Earth’s atmosphere.

The same process in algae and plants decreased the percentage of carbon dioxide in

the Earth’s atmosphere.

03.3 Which process in algae and plants increased the percentage of oxygen in the

Earth’s atmosphere?

[1 mark]

Tick ( ) one box.

Fermentation

Photosynthesis

Rusting

Sedimentation

03.4 Which two other processes decreased the percentage of carbon dioxide in the

Earth’s atmosphere?

[2 marks]

Tick ( ) two boxes.

Burning fossil fuels

Dissolving carbon dioxide in oceans

Eruption of volcanoes

Evolution of animals

Formation of sedimentary rocks 14

Figure 3 shows how the percentages of gases in the Earth’s atmosphere may have

changed since the atmosphere was formed.

Figure 3

03.5 When was the percentage of oxygen in the Earth’s atmosphere 8%?

Use Figure 3.

[1 mark]

millions of years ago

03.6 When did the percentage of nitrogen in the Earth’s atmosphere become constant?

Use Figure 3.

[1 mark]

15 millions of years ago

03.7 Crude oil was formed from an ancient biomass as the Earth’s atmosphere evolved.

What did this ancient biomass mainly consist of?

*14* [1 mark]

Tick ( ) one box.

Limestone

Plankton

Sand

03.8 Most of the percentages of the gases in Figure 3 are estimated values.

Why have scientists used estimated values for the percentages of the gases in

Figure 3?

[1 mark]

Mark scheme

Show the mark scheme Mark scheme for Question 3: 03.1 gives 78.09 (%) for 1 mark; 03.2 gives ammonia and methane for 1 mark each; 03.3 gives photosynthesis for 1 mark; 03.4 gives dissolving carbon dioxide in oceans and formation of sedimentary rocks for 1 mark each; 03.5 gives 1500 (millions of years ago) for 1 mark; 03.6 gives 2500 (allow 2500 to 2700) for 1 mark; 03.7 gives plankton for 1 mark; 03.8 gives '(there is) limited evidence' or 'timescale was millions / billions of years' for 1 mark. Total 10 marks.

Question 3

AO /

Question Answers Extra information Mark

Spec. Ref.

03.1 78.09 (%) 1 AO2

4.9.1.1

AO /

Spec. Ref.

03.2 ammonia 1 AO1

4.9.1.2

methane 1

AO /

Spec. Ref.

03.3 photosynthesis 1 AO1

4.9.1.3

AO /

Spec. Ref.

03.4 dissolving carbon dioxide in 1 AO1

oceans 4.9.1.2

4.9.1.4

formation of sedimentary rocks 1

AO /

Spec. Ref.

03.5 1500 (millions of years ago) 1 AO2

4.9.1.3

AO / 11

Spec. Ref.

03.6 2500 (millions of years ago) allow a value in the range 2500 1 AO3

to 2700 (millions of years ago) 4.9.1.3

AO /

Spec. Ref.

03.7 plankton 1 AO1

4.7.1.1

4.9.1.4

AO /

Spec. Ref.

03.8 (there is) limited evidence allow the timescale was 1 AO2

millions / billions of years 4.9.1.2

Total Question 3 10

How to answer it

The Earth's Atmosphere: Past and Present

What this question tests

This question assesses fundamental recall and graph-interpretation skills from Topic 9: Chemistry of the Atmosphere:

  • The composition of the Earth's atmosphere today vs. the early atmosphere.
  • How carbon dioxide decreased and oxygen increased over geological time.
  • The origin of fossil fuels (crude oil).
  • Extracting data from dual-axis line graphs.
  • Scientific reasoning regarding theories with limited historical evidence.

Part 03.1: Percentage of Nitrogen Today 1 Mark

Calculate value X in Table 5

📐 Step-by-Step Calculation

1
All percentages in the table must add up to exactly 100%.
2
Sum known gases:
20.95 + 0.04 + 0.92 = 21.91%
3
Subtract from 100%:
X = 100 - 21.91 = 78.09%

✅ Correct Answer

X = 78.09%

1 Mark: Exactly 78.09 (or rounded to 78.1 if error carried, but exact arithmetic gives 78.09).

🧠 Exam Technique

Always double-check that you used the correct column! Table 5 has two columns: "early atmosphere" and "atmosphere today". Make sure you do not add the 1.8% from the early atmosphere column.

❌ Common Errors

Writing 78% or 80% from standard recall memory rather than calculating the precise value from the given data table.

Part 03.2: Other Gases in the Early Atmosphere 2 Marks

Which two other gases may have been in the Earth's early atmosphere?

✅ Correct Answers

  • ✔ Ammonia (NH₃)
  • ✔ Methane (CH₄)
2 Marks: 1 mark for each correctly selected box.

💡 Key Knowledge

Intense volcanic activity released mainly carbon dioxide and water vapour, with small amounts of methane, ammonia, and nitrogen.

❌ Common Errors

Selecting Coal or Limestone. These are solids/rocks, not gases! Poly(ethene) is a modern synthetic plastic polymer.

🧠 Exam Technique

Look at state of matter hints in the question text: "Which two other gases...". Filtering out solids instantly leaves only Ammonia and Methane.

Part 03.3: Biological Increase of Oxygen 1 Mark

Which process in algae and plants increased the percentage of oxygen?

✅ Correct Answer

✔ Photosynthesis

1 Mark: Photosynthesis ticked.

💡 Key Knowledge

Algae first produced oxygen around 2.7 billion years ago. Photosynthesis word equation:

carbon dioxide + water → glucose + oxygen

6CO₂ + 6H₂O → C₆H₁₂O₆ + 6O₂

Part 03.4: Removal of Carbon Dioxide 2 Marks

Which two other processes decreased the percentage of carbon dioxide?

✅ Correct Answers

  • ✔ Dissolving carbon dioxide in oceans
  • ✔ Formation of sedimentary rocks
2 Marks: 1 mark for each correct box ticked.

💡 Key Knowledge

  • Oceans formed: Water vapour condensed; CO₂ dissolved to form soluble carbonate compounds and marine shells.
  • Sedimentary rocks: Locked up carbon in rocks like limestone (calcium carbonate, CaCO₃).

❌ Common Errors

Selecting "Burning fossil fuels" or "Eruption of volcanoes". Both of these processes increase atmospheric CO₂, rather than decrease it.

Parts 03.5 & 03.6: Reading Evolution Graphs 2 Marks Total

✅ 03.5: Oxygen at 8%

1500 millions of years ago

1 Mark: Exactly 1500.

✅ 03.6: Nitrogen Constant

2500 millions of years ago

1 Mark: Allow any value in range 2500 to 2700.

🧠 Exam Technique: Reading Figure 3

  • For 03.5: Find 8% on the vertical axis (each small square = 2%). Follow across to the solid line (Oxygen), then trace directly down to the horizontal axis to find 1500 .
  • For 03.6: Find the point where the dashed line (Nitrogen) stops rising and levels out completely flat at 80%. This occurs around 2500 million years ago.
  • Note the scale on the x-axis: it counts backwards from 4500 to 0 (millions of years ago).

❌ Common Errors

Mixing up the line styles from the key (dotted line = CO₂, dashed = N₂, solid = O₂). Always trace the line with a ruler to avoid reading the wrong trace.

Part 03.7: Formation of Crude Oil 1 Mark

What did this ancient biomass mainly consist of?

✅ Correct Answer

✔ Plankton

1 Mark: Plankton ticked.

💡 Key Knowledge: Fossil Fuel Origins

  • Crude oil & natural gas: Formed from deposits of plankton buried under high heat and pressure in seabed mud over millions of years.
  • Coal: A sedimentary rock formed from thick plant deposits (trees and ferns in ancient swamps).

Part 03.8: Why Values are Estimated 1 Mark

Why have scientists used estimated values for the percentages of gases in Figure 3?

✅ Correct Answer (Any one of the following)

  • There is limited evidence / lack of proof.
  • It occurred a very long time ago (billions / millions of years ago).
  • No humans were alive to take measurements or keep records.
1 Mark: Mentions limited evidence OR the enormous timescale (millions/billions of years).

🧠 Examiner Insight

Examiners look for the word "evidence". A common weak response is "because they are guessing"—this does not get the mark. State that evidence is limited because it happened 4.6 billion years ago.

Topics

Chemistry · C7: Organic Chemistry · C9: Chemistry of the Atmosphere

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), June 2022. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.