AQA GCSE Chemistry Chemistry Paper 2 (Foundation), June 2022: Question 3
10 marks · Low Demand difficulty · Short Answer
Answer questions about the evolution and composition of the Earth's atmosphere, including calculating the percentage of nitrogen, processes changing atmospheric gases, and reading data from a graph.
Practise this questionQuestion
Question text
03 This question is about the Earth’s atmosphere.
Table 5 shows:
• the estimated percentages of gases in the Earth’s early atmosphere
• the percentages of gases in the Earth’s atmosphere today.
Table 5
Estimated percentage (%) in Percentage (%) in the
Gas
the Earth’s early atmosphere Earth’s atmosphere today
Nitrogen 1.8 X
Oxygen 0.2 20.95
Carbon dioxide 96.0 0.04
Other gases 2.0 0.92
03.1 Calculate value X in Table 5.
[1 mark]
X = %
03.2 Which two other gases may have been in the Earth’s early atmosphere?
[2 marks]
Tick ( ) two boxes.
Ammonia
Coal
Limestone
Methane
Poly(ethene) 13
Algae and plants increased the percentage of oxygen in the Earth’s atmosphere.
The same process in algae and plants decreased the percentage of carbon dioxide in
the Earth’s atmosphere.
03.3 Which process in algae and plants increased the percentage of oxygen in the
Earth’s atmosphere?
[1 mark]
Tick ( ) one box.
Fermentation
Photosynthesis
Rusting
Sedimentation
03.4 Which two other processes decreased the percentage of carbon dioxide in the
Earth’s atmosphere?
[2 marks]
Tick ( ) two boxes.
Burning fossil fuels
Dissolving carbon dioxide in oceans
Eruption of volcanoes
Evolution of animals
Formation of sedimentary rocks 14
Figure 3 shows how the percentages of gases in the Earth’s atmosphere may have
changed since the atmosphere was formed.
Figure 3
03.5 When was the percentage of oxygen in the Earth’s atmosphere 8%?
Use Figure 3.
[1 mark]
millions of years ago
03.6 When did the percentage of nitrogen in the Earth’s atmosphere become constant?
Use Figure 3.
[1 mark]
15 millions of years ago
03.7 Crude oil was formed from an ancient biomass as the Earth’s atmosphere evolved.
What did this ancient biomass mainly consist of?
*14* [1 mark]
Tick ( ) one box.
Limestone
Plankton
Sand
03.8 Most of the percentages of the gases in Figure 3 are estimated values.
Why have scientists used estimated values for the percentages of the gases in
Figure 3?
[1 mark]
Mark scheme
Show the mark scheme
Question 3
AO /
Question Answers Extra information Mark
Spec. Ref.
03.1 78.09 (%) 1 AO2
4.9.1.1
AO /
Spec. Ref.
03.2 ammonia 1 AO1
4.9.1.2
methane 1
AO /
Spec. Ref.
03.3 photosynthesis 1 AO1
4.9.1.3
AO /
Spec. Ref.
03.4 dissolving carbon dioxide in 1 AO1
oceans 4.9.1.2
4.9.1.4
formation of sedimentary rocks 1
AO /
Spec. Ref.
03.5 1500 (millions of years ago) 1 AO2
4.9.1.3
AO / 11
Spec. Ref.
03.6 2500 (millions of years ago) allow a value in the range 2500 1 AO3
to 2700 (millions of years ago) 4.9.1.3
AO /
Spec. Ref.
03.7 plankton 1 AO1
4.7.1.1
4.9.1.4
AO /
Spec. Ref.
03.8 (there is) limited evidence allow the timescale was 1 AO2
millions / billions of years 4.9.1.2
Total Question 3 10
How to answer it
The Earth's Atmosphere: Past and Present
What this question tests
This question assesses fundamental recall and graph-interpretation skills from Topic 9: Chemistry of the Atmosphere:
- The composition of the Earth's atmosphere today vs. the early atmosphere.
- How carbon dioxide decreased and oxygen increased over geological time.
- The origin of fossil fuels (crude oil).
- Extracting data from dual-axis line graphs.
- Scientific reasoning regarding theories with limited historical evidence.
Part 03.1: Percentage of Nitrogen Today 1 Mark
Calculate value X in Table 5
📐 Step-by-Step Calculation
20.95 + 0.04 + 0.92 = 21.91%
X = 100 - 21.91 = 78.09%
✅ Correct Answer
X = 78.09%
🧠 Exam Technique
Always double-check that you used the correct column! Table 5 has two columns: "early atmosphere" and "atmosphere today". Make sure you do not add the 1.8% from the early atmosphere column.
❌ Common Errors
Writing 78% or 80% from standard recall memory rather than calculating the precise value from the given data table.
Part 03.2: Other Gases in the Early Atmosphere 2 Marks
Which two other gases may have been in the Earth's early atmosphere?
✅ Correct Answers
- ✔ Ammonia (NH₃)
- ✔ Methane (CH₄)
💡 Key Knowledge
Intense volcanic activity released mainly carbon dioxide and water vapour, with small amounts of methane, ammonia, and nitrogen.
❌ Common Errors
Selecting Coal or Limestone. These are solids/rocks, not gases! Poly(ethene) is a modern synthetic plastic polymer.
🧠 Exam Technique
Look at state of matter hints in the question text: "Which two other gases...". Filtering out solids instantly leaves only Ammonia and Methane.
Part 03.3: Biological Increase of Oxygen 1 Mark
Which process in algae and plants increased the percentage of oxygen?
✅ Correct Answer
✔ Photosynthesis
💡 Key Knowledge
Algae first produced oxygen around 2.7 billion years ago. Photosynthesis word equation:
carbon dioxide + water → glucose + oxygen
6CO₂ + 6H₂O → C₆H₁₂O₆ + 6O₂
Part 03.4: Removal of Carbon Dioxide 2 Marks
Which two other processes decreased the percentage of carbon dioxide?
✅ Correct Answers
- ✔ Dissolving carbon dioxide in oceans
- ✔ Formation of sedimentary rocks
💡 Key Knowledge
- Oceans formed: Water vapour condensed; CO₂ dissolved to form soluble carbonate compounds and marine shells.
- Sedimentary rocks: Locked up carbon in rocks like limestone (calcium carbonate, CaCO₃).
❌ Common Errors
Selecting "Burning fossil fuels" or "Eruption of volcanoes". Both of these processes increase atmospheric CO₂, rather than decrease it.
Parts 03.5 & 03.6: Reading Evolution Graphs 2 Marks Total
✅ 03.5: Oxygen at 8%
1500 millions of years ago
✅ 03.6: Nitrogen Constant
2500 millions of years ago
🧠 Exam Technique: Reading Figure 3
- For 03.5: Find 8% on the vertical axis (each small square = 2%). Follow across to the solid line (Oxygen), then trace directly down to the horizontal axis to find 1500 .
- For 03.6: Find the point where the dashed line (Nitrogen) stops rising and levels out completely flat at 80%. This occurs around 2500 million years ago.
- Note the scale on the x-axis: it counts backwards from 4500 to 0 (millions of years ago).
❌ Common Errors
Mixing up the line styles from the key (dotted line = CO₂, dashed = N₂, solid = O₂). Always trace the line with a ruler to avoid reading the wrong trace.
Part 03.7: Formation of Crude Oil 1 Mark
What did this ancient biomass mainly consist of?
✅ Correct Answer
✔ Plankton
💡 Key Knowledge: Fossil Fuel Origins
- Crude oil & natural gas: Formed from deposits of plankton buried under high heat and pressure in seabed mud over millions of years.
- Coal: A sedimentary rock formed from thick plant deposits (trees and ferns in ancient swamps).
Part 03.8: Why Values are Estimated 1 Mark
Why have scientists used estimated values for the percentages of gases in Figure 3?
✅ Correct Answer (Any one of the following)
- There is limited evidence / lack of proof.
- It occurred a very long time ago (billions / millions of years ago).
- No humans were alive to take measurements or keep records.
🧠 Examiner Insight
Examiners look for the word "evidence". A common weak response is "because they are guessing"—this does not get the mark. State that evidence is limited because it happened 4.6 billion years ago.
Topics
Chemistry · C7: Organic Chemistry · C9: Chemistry of the Atmosphere
Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), June 2022. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.