AQA GCSE Chemistry Chemistry Paper 2 (Foundation), June 2024: Question 1

12 marks · Low Demand difficulty · Short Answer

Identify properties, formulas, pollutants, cracking products, and composition by mass of the alkane hexane (C6H14).

Practise this question

Question

Question 1 contains nine parts regarding hydrocarbons with formula C6H14: naming the two constituent elements, calculating the total number of atoms in one molecule, selecting the general formula and homologous series name (alkanes), completing a displayed structural formula diagram showing six carbon atoms and 14 hydrogen atoms, defining petrol as a fuel, identifying solid (soot) and gaseous (carbon monoxide) incomplete combustion pollutants, completing a cracking equation C12H26 to C6H14 + C6H12, and completing a bar chart showing percentage by mass of carbon (84%) and hydrogen (16%).
Question text

01 This question is about hydrocarbons.

A hydrocarbon has the formula C6H14

01.1 Name the two elements in a hydrocarbon.

[2 marks]

01.2 How many atoms are there in one molecule of C6H14?

[1 mark]

Tick ( ) one box.

C6H14 is a member of a homologous series.

01.3 What is the general formula for the homologous series that contains C6H14?

[1 mark]

Tick ( ) one box.

CnH2n–2

CnH2n

CnH2n+2 3

01.4 Which homologous series has C6H14 as a member?

[1 mark]

Tick ( ) one box.

Alcohols

Alkanes

Alkenes

Carboxylic acids

01.5 Complete Figure 1 to show the displayed structural formula of C6H14

[1 mark]

Figure 1

01.6 Petrol contains C6H14

Petrol is burned in car engines.

What general name is used to describe petrol when petrol is burned to release

energy?

[1 mark]

01.7 Atmospheric pollutants are formed when C6H14 undergoes incomplete combustion.

Complete the sentences.

Choose answers from the box.

[2 marks]

ammonia carbon monoxide coal

*03* soot sulfur sulfur dioxide

The solid atmospheric pollutant formed during incomplete combustion of C6H14 is

.

The gaseous atmospheric pollutant formed during incomplete combustion of C6H14 is

.

01.8 A different organic compound (C12H26) can be broken down to produce C6H14 and one

other compound.

Complete the equation for the reaction.

[1 mark]

C12H26 → C6H145 + C H

01.9 The percentage by mass of each element in C6H14 is:

• 84% C

• 16% H

Complete Figure 2.

You should:

• label each element on the x-axis

• plot the percentage by mass of C in C6H14

[2 marks]

Figure 2

Mark scheme

Show the mark scheme Mark scheme for Question 1 providing acceptable answers: 01.1: carbon and hydrogen (1 mark each); 01.2: 20 (1 mark); 01.3: CnH2n+2 (1 mark); 01.4: alkanes (1 mark); 01.5: completed displayed structure with all single C-C and C-H bonds (1 mark); 01.6: fuel / fossil fuel (1 mark); 01.7: soot and carbon monoxide (1 mark each); 01.8: C6H12 (1 mark); 01.9: bar drawn to 84% (allow ± half a small square) and bars correctly labelled C and H (1 mark each). Total marks: 12.

Question 1

AO /

Question Answers Extra information Mark

Spec. Ref.

01.1 carbon ignore C 1 AO1

4.1.1.1

hydrogen ignore H 1 4.7.1.1

AO /

Spec. Ref.

01.2 20 1 AO2

4.1.1.1

4.7.1.1

AO /

Spec. Ref.

01.3 CnH2n+2 1 AO2

4.7.1.1

AO /

Spec. Ref.

01.4 alkanes 1 AO2

4.7.1.1

AO /

Spec. Ref.

01.5 1 AO2

4.7.1.1

– – –

AO /

Spec. Ref.

01.6 fuel allow fossil fuel 1 AO1

4.7.1.3

AO / 7

Spec. Ref.

01.7 soot 1 AO1

4.9.3.1

carbon monoxide 1

AO /

Spec. Ref.

01.8 C6H12 1 AO2

4.7.1.4

AO /

Spec. Ref.

01.9 bar drawn to 84% allow a tolerance of ± ½ a small 1 AO2

square 4.7.1.1

bars labelled C / carbon 1

and

H / hydrogen

Total Question 1 12

How to answer it

AQA GCSE Chemistry: Hydrocarbons, Combustion & Cracking

📋 What this question tests

This question assesses fundamental knowledge from Organic Chemistry (Topic 7) and Chemistry of the Atmosphere (Topic 9):

  • Definition & Structure: Identifying the elements in hydrocarbons, total atom counts, and drawing complete displayed structural formulas.
  • Alkanes: Recognizing homologous series and applying the general formula CₙH₂ₙ₊₂.
  • Combustion & Pollution: Defining a fuel and recalling pollutants from incomplete combustion (soot and carbon monoxide).
  • Cracking: Balancing thermal decomposition equations to produce alkenes.
  • Mathematical & Graph Skills: Accurately plotting bar chart data and labelling axes correctly.
Questions 01.1 & 01.2

Hydrocarbon Basics & Molecular Formulas

Understanding C₆H₁₄

✅ Correct Answers

01.1:

  • carbon [1 mark]
  • hydrogen [1 mark]

01.2: Tick the box for 20 [1 mark]

💡 Key Knowledge

A hydrocarbon is a compound consisting of hydrogen and carbon only.

In a molecular formula like C₆H₁₄ :

  • 6 carbon atoms
  • 14 hydrogen atoms
  • Total atoms = 6 + 14 = 20 atoms

🧠 Exam Technique: "Name" vs "Symbol"

Always read command words carefully. The question states "Name the two elements", so you must write their full English names.

Mark Scheme note: "ignore C, ignore H". Writing just the periodic symbols scores 0 marks here!

❌ Common Errors

  • Writing "oxygen" or "water" as an element in a hydrocarbon.
  • Selecting 14 or 6 in 01.2 by confusing total atoms with the count of an individual element.
  • Selecting 2 by mistaking the number of different elements for the total number of atoms.
Questions 01.3, 01.4 & 01.5

Alkanes & Displayed Structural Formulas

General formulas and structural representations

✅ Correct Answers

01.3: CₙH₂ₙ₊₂ [1 mark]

01.4: Alkanes [1 mark]

01.5: Complete all missing single bonds in Figure 1 [1 mark]:

  • Draw horizontal single lines ( — ) between all 6 carbon atoms (5 C—C bonds).
  • Draw the single bond between the end H and the first C, and the last C and the right-hand H (2 C—H end bonds).

💡 Alkanes: Saturated Hydrocarbons

Alkanes are saturated hydrocarbons containing only single covalent bonds:

  • General formula: CₙH₂ₙ₊₂
  • If n = 6: C₆H₍₂ ₓ ₆₎ ₊ ₂ = C₆H₁₄ (hexane)
  • Every carbon atom must form exactly 4 covalent bonds.
  • Every hydrogen atom forms exactly 1 covalent bond.

🧠 Exam Technique: Spotting Missing Bonds

In Figure 1, vertical bonds between C and H were provided, but the backbone was broken:

Make sure you connect every carbon atom together with a single horizontal line, and do not forget the two outer hydrogens at the ends.

❌ Common Errors

  • Confusing alkanes (CₙH₂ₙ₊₂) with alkenes (CₙH₂ₙ).
  • Drawing double lines between carbons (which would give carbons 5 bonds).
  • Forgetting to draw the two bonds to the terminal hydrogen atoms on the far left and far right.
Questions 01.6 & 01.7

Combustion, Fuels & Atmospheric Pollutants

Complete vs incomplete combustion

✅ Correct Answers

01.6: fuel (allow fossil fuel) [1 mark]

01.7:

  • Solid pollutant: soot [1 mark]
  • Gaseous pollutant: carbon monoxide [1 mark]

💡 Incomplete Combustion

When hydrocarbons burn with an insufficient supply of oxygen:

  • Soot (carbon particulates): Tiny solid carbon particles that cause global dimming and respiratory issues.
  • Carbon monoxide (CO): A toxic, colourless, and odourless gas that binds irreversibly to haemoglobin.

🧠 Look at the State of Matter

The question provides strong clues:

  • "solid atmospheric pollutant" → Soot (pure carbon solid).
  • "gaseous pollutant formed during incomplete combustion" → Carbon monoxide.
Sulfur dioxide is formed from sulfur impurities, not directly from burning pure C₆H₁₄!

❌ Common Errors

  • Selecting coal as the solid pollutant (coal is an unburned rock fuel, not a combustion product).
  • Selecting sulfur dioxide for incomplete combustion (sulfur is not present in pure C₆H₁₄).
  • Confusing carbon monoxide with carbon dioxide (carbon dioxide forms during complete combustion).
Question 01.8

Cracking Alkanes

Balancing thermal decomposition reactions

✅ Correct Answer

C₆H₁₂ [1 mark]

C₁₂H₂₆ → C₆H₁₄ + C₆H₁₂

📐 Calculation: Conservation of Mass

Atoms cannot be created or destroyed:

  1. Carbon atoms: 12 on LHS → 6 in C₆H₁₄, so missing = 12 − 6 = 6
  2. Hydrogen atoms: 26 on LHS → 14 in C₆H₁₄, so missing = 26 − 14 = 12
  3. Formula: C₆H₁₂

💡 Cracking Rule

When a long-chain alkane is cracked, it breaks down into:

Long alkane → Shorter alkane + Alkene

Here, dodecane (C₁₂H₂₆) forms hexane (alkane, C₆H₁₄) and hexene (alkene, C₆H₁₂).

❌ Common Errors

  • Arithmetic slip: writing C₆H₁₄ again or C₆H₁₀.
  • Writing numbers as normal text instead of subscripts on the question line.
Question 01.9

Data Presentation: Graph Plotting

Completing the bar chart for percentage by mass

✅ Correct Answer & Marks

  • Bar height: Draw a neat bar for Carbon up to exactly 84% [1 mark]
  • X-axis labels: Both bars correctly labelled on the x-axis: Carbon / C under the 84% bar, and Hydrogen / H under the existing 16% bar [1 mark]

🧠 Exam Technique: Reading the Scale

  • Look at the y-axis: between 80 and 90 there are 5 small grid squares.
  • Each small square = (90 − 80) ÷ 5 = 2%.
  • 84% is exactly 2 small squares above the 80 line.
  • The mark scheme allows a tolerance of ± ½ small square.
  • Always use a ruler and pencil to draw bar charts!

❌ Common Errors

  • Plotting 84% at 4 small squares above 80 (assuming 1 square = 1%).
  • Forgetting to label the existing bar (the bar drawn at 16% must be labelled H / Hydrogen).
  • Drawing bars with unequal widths.

Topics

Chemistry · C7: Organic Chemistry · C9: Chemistry of the Atmosphere

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), June 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.