AQA GCSE Chemistry Chemistry Paper 2 (Foundation), June 2024: Question 1
12 marks · Low Demand difficulty · Short Answer
Identify properties, formulas, pollutants, cracking products, and composition by mass of the alkane hexane (C6H14).
Practise this questionQuestion
Question text
01 This question is about hydrocarbons.
A hydrocarbon has the formula C6H14
01.1 Name the two elements in a hydrocarbon.
[2 marks]
01.2 How many atoms are there in one molecule of C6H14?
[1 mark]
Tick ( ) one box.
C6H14 is a member of a homologous series.
01.3 What is the general formula for the homologous series that contains C6H14?
[1 mark]
Tick ( ) one box.
CnH2n–2
CnH2n
CnH2n+2 3
01.4 Which homologous series has C6H14 as a member?
[1 mark]
Tick ( ) one box.
Alcohols
Alkanes
Alkenes
Carboxylic acids
01.5 Complete Figure 1 to show the displayed structural formula of C6H14
[1 mark]
Figure 1
01.6 Petrol contains C6H14
Petrol is burned in car engines.
What general name is used to describe petrol when petrol is burned to release
energy?
[1 mark]
01.7 Atmospheric pollutants are formed when C6H14 undergoes incomplete combustion.
Complete the sentences.
Choose answers from the box.
[2 marks]
ammonia carbon monoxide coal
*03* soot sulfur sulfur dioxide
The solid atmospheric pollutant formed during incomplete combustion of C6H14 is
.
The gaseous atmospheric pollutant formed during incomplete combustion of C6H14 is
.
01.8 A different organic compound (C12H26) can be broken down to produce C6H14 and one
other compound.
Complete the equation for the reaction.
[1 mark]
C12H26 → C6H145 + C H
01.9 The percentage by mass of each element in C6H14 is:
• 84% C
• 16% H
Complete Figure 2.
You should:
• label each element on the x-axis
• plot the percentage by mass of C in C6H14
[2 marks]
Figure 2
Mark scheme
Show the mark scheme
Question 1
AO /
Question Answers Extra information Mark
Spec. Ref.
01.1 carbon ignore C 1 AO1
4.1.1.1
hydrogen ignore H 1 4.7.1.1
AO /
Spec. Ref.
01.2 20 1 AO2
4.1.1.1
4.7.1.1
AO /
Spec. Ref.
01.3 CnH2n+2 1 AO2
4.7.1.1
AO /
Spec. Ref.
01.4 alkanes 1 AO2
4.7.1.1
AO /
Spec. Ref.
01.5 1 AO2
4.7.1.1
– – –
AO /
Spec. Ref.
01.6 fuel allow fossil fuel 1 AO1
4.7.1.3
AO / 7
Spec. Ref.
01.7 soot 1 AO1
4.9.3.1
carbon monoxide 1
AO /
Spec. Ref.
01.8 C6H12 1 AO2
4.7.1.4
AO /
Spec. Ref.
01.9 bar drawn to 84% allow a tolerance of ± ½ a small 1 AO2
square 4.7.1.1
bars labelled C / carbon 1
and
H / hydrogen
Total Question 1 12
How to answer it
AQA GCSE Chemistry: Hydrocarbons, Combustion & Cracking
This question assesses fundamental knowledge from Organic Chemistry (Topic 7) and Chemistry of the Atmosphere (Topic 9):
- Definition & Structure: Identifying the elements in hydrocarbons, total atom counts, and drawing complete displayed structural formulas.
- Alkanes: Recognizing homologous series and applying the general formula CₙH₂ₙ₊₂.
- Combustion & Pollution: Defining a fuel and recalling pollutants from incomplete combustion (soot and carbon monoxide).
- Cracking: Balancing thermal decomposition equations to produce alkenes.
- Mathematical & Graph Skills: Accurately plotting bar chart data and labelling axes correctly.
Hydrocarbon Basics & Molecular Formulas
Understanding C₆H₁₄
✅ Correct Answers
01.1:
- carbon [1 mark]
- hydrogen [1 mark]
01.2: Tick the box for 20 [1 mark]
💡 Key Knowledge
A hydrocarbon is a compound consisting of hydrogen and carbon only.
In a molecular formula like C₆H₁₄ :
- 6 carbon atoms
- 14 hydrogen atoms
- Total atoms = 6 + 14 = 20 atoms
🧠 Exam Technique: "Name" vs "Symbol"
Always read command words carefully. The question states "Name the two elements", so you must write their full English names.
❌ Common Errors
- Writing "oxygen" or "water" as an element in a hydrocarbon.
- Selecting 14 or 6 in 01.2 by confusing total atoms with the count of an individual element.
- Selecting 2 by mistaking the number of different elements for the total number of atoms.
Alkanes & Displayed Structural Formulas
General formulas and structural representations
✅ Correct Answers
01.3: CₙH₂ₙ₊₂ [1 mark]
01.4: Alkanes [1 mark]
01.5: Complete all missing single bonds in Figure 1 [1 mark]:
- Draw horizontal single lines ( — ) between all 6 carbon atoms (5 C—C bonds).
- Draw the single bond between the end H and the first C, and the last C and the right-hand H (2 C—H end bonds).
💡 Alkanes: Saturated Hydrocarbons
Alkanes are saturated hydrocarbons containing only single covalent bonds:
- General formula: CₙH₂ₙ₊₂
- If n = 6: C₆H₍₂ ₓ ₆₎ ₊ ₂ = C₆H₁₄ (hexane)
- Every carbon atom must form exactly 4 covalent bonds.
- Every hydrogen atom forms exactly 1 covalent bond.
🧠 Exam Technique: Spotting Missing Bonds
In Figure 1, vertical bonds between C and H were provided, but the backbone was broken:
Make sure you connect every carbon atom together with a single horizontal line, and do not forget the two outer hydrogens at the ends.
❌ Common Errors
- Confusing alkanes (CₙH₂ₙ₊₂) with alkenes (CₙH₂ₙ).
- Drawing double lines between carbons (which would give carbons 5 bonds).
- Forgetting to draw the two bonds to the terminal hydrogen atoms on the far left and far right.
Combustion, Fuels & Atmospheric Pollutants
Complete vs incomplete combustion
✅ Correct Answers
01.6: fuel (allow fossil fuel) [1 mark]
01.7:
- Solid pollutant: soot [1 mark]
- Gaseous pollutant: carbon monoxide [1 mark]
💡 Incomplete Combustion
When hydrocarbons burn with an insufficient supply of oxygen:
- Soot (carbon particulates): Tiny solid carbon particles that cause global dimming and respiratory issues.
- Carbon monoxide (CO): A toxic, colourless, and odourless gas that binds irreversibly to haemoglobin.
🧠 Look at the State of Matter
The question provides strong clues:
- "solid atmospheric pollutant" → Soot (pure carbon solid).
- "gaseous pollutant formed during incomplete combustion" → Carbon monoxide.
❌ Common Errors
- Selecting coal as the solid pollutant (coal is an unburned rock fuel, not a combustion product).
- Selecting sulfur dioxide for incomplete combustion (sulfur is not present in pure C₆H₁₄).
- Confusing carbon monoxide with carbon dioxide (carbon dioxide forms during complete combustion).
Cracking Alkanes
Balancing thermal decomposition reactions
✅ Correct Answer
C₆H₁₂ [1 mark]
C₁₂H₂₆ → C₆H₁₄ + C₆H₁₂
📐 Calculation: Conservation of Mass
Atoms cannot be created or destroyed:
- Carbon atoms: 12 on LHS → 6 in C₆H₁₄, so missing = 12 − 6 = 6
- Hydrogen atoms: 26 on LHS → 14 in C₆H₁₄, so missing = 26 − 14 = 12
- Formula: C₆H₁₂
💡 Cracking Rule
When a long-chain alkane is cracked, it breaks down into:
Long alkane → Shorter alkane + Alkene
Here, dodecane (C₁₂H₂₆) forms hexane (alkane, C₆H₁₄) and hexene (alkene, C₆H₁₂).
❌ Common Errors
- Arithmetic slip: writing C₆H₁₄ again or C₆H₁₀.
- Writing numbers as normal text instead of subscripts on the question line.
Data Presentation: Graph Plotting
Completing the bar chart for percentage by mass
✅ Correct Answer & Marks
- Bar height: Draw a neat bar for Carbon up to exactly 84% [1 mark]
- X-axis labels: Both bars correctly labelled on the x-axis: Carbon / C under the 84% bar, and Hydrogen / H under the existing 16% bar [1 mark]
🧠 Exam Technique: Reading the Scale
- Look at the y-axis: between 80 and 90 there are 5 small grid squares.
- Each small square = (90 − 80) ÷ 5 = 2%.
- 84% is exactly 2 small squares above the 80 line.
- The mark scheme allows a tolerance of ± ½ small square.
- Always use a ruler and pencil to draw bar charts!
❌ Common Errors
- Plotting 84% at 4 small squares above 80 (assuming 1 square = 1%).
- Forgetting to label the existing bar (the bar drawn at 16% must be labelled H / Hydrogen).
- Drawing bars with unequal widths.
Topics
Chemistry · C7: Organic Chemistry · C9: Chemistry of the Atmosphere
Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), June 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.