AQA GCSE Chemistry Chemistry Paper 2 (Foundation), June 2025: Question 6

8 marks · Low Demand difficulty · Short Answer

Analyze changes in the Earth's early atmosphere using graphical and tabular data to identify gas proportions, causes of atmospheric evolution, and the process producing oxygen.

Practise this question

Question

Question 6 comprises seven parts based on the Earth's early atmosphere. Figure 5 shows a graph of Percentage of carbon dioxide in the Earth's atmosphere against Time in billions of years ago from 4.50 to 2.50, with a curve drawn through points from 4.50 to 3.50 and unconnected plotted points at 3.25, 3.00, and 2.75. Parts 06.1 to 06.3 ask to complete the line of best fit, read the percentage at 3.75 billion years ago, and choose the cause of the decrease in carbon dioxide. Table 2 provides data for percentage of nitrogen at various times from 4.5 to 2.5 billion years ago. Parts 06.4 and 06.5 ask for the cause of the increase in nitrogen and the time it reached modern levels. Parts 06.6 and 06.7 ask to identify two other gases present in the early atmosphere and name the process that began producing oxygen 2.7 billion years ago.
Question text

06 The Earth’s atmosphere has changed over time.

Figure 5 shows the percentage of carbon dioxide in the Earth’s atmosphere between

4.5 billion and 2.75 billion years ago.

Figure 5

06.1 Complete Figure 5.

You should extend the line of best fit to the plotted point at 2.75 billions of years ago.

[1 mark]

06.2 What was the percentage (%) of carbon dioxide in the Earth’s atmosphere

3.75 billions of years ago?

Use Figure 5.

[1 mark]

%

06.3 The percentage of carbon dioxide changed between 4.5 and 3.0 billion years ago.

Which was a cause of this change?

Use Figure 5.

[1 mark]

Tick ( ) one box.

Carbon dioxide was dissolved in oceans.

Carbon dioxide was produced during combustion of fossil fuels.

Carbon dioxide was released during volcanic activity.22

Table 2 shows information about the percentage of nitrogen present in the

Earth’s atmosphere.

Table 2

Time in billions of Percentage (%) of

years ago nitrogen

4.5 4

4.0 34

3.5 62

3.0 75

2.5 78

06.4 The percentage of nitrogen changed between 4.5 and 2.5 billion years ago.

*21Which was a cause of this change?*

Use Table 2.

[1 mark]

Tick ( ) one box.

Nitrogen was dissolved in oceans.

Nitrogen was produced during combustion of fossil fuels.

Nitrogen was released during volcanic activity.23

06.5 When did the percentage of nitrogen in the Earth’s atmosphere become similar to the

percentage of nitrogen in the Earth’s atmosphere today?

Use Table 2.

[1 mark]

Tick ( ) one box.

2.5 billion years ago

3.0 billion years ago

3.5 billion years ago

4.0 billion years ago

4.5 billion years ago

06.6 Which two gases may also have been present in the Earth’s early atmosphere?

[2 marks]

Tick ( ) two boxes.

Ammonia

Chlorine

Helium

Hydrogen

Methane

06.7 Name the process that started to produce oxygen in the Earth’s atmosphere

2.7 billion years ago.

[1 mark]

Mark scheme

Show the mark scheme Mark scheme for Question 6 listing answers: 06.1 requires completing the line of best fit to 2.75 billion years ago (1 mark, AO2). 06.2: 40 (%) (1 mark, AO2). 06.3: carbon dioxide was dissolved in oceans (1 mark, AO3). 06.4: nitrogen was released during volcanic activity (1 mark, AO3). 06.5: 2.5 billion years ago (1 mark, AO3). 06.6: ammonia and methane (2 marks, 1 mark each, AO1). 06.7: photosynthesis (1 mark, AO1). Total marks: 8.

Question 6

AO /

Question Answers Extra information Mark

Spec. Ref.

06.1 line of best fit 1 AO2

4.9.1.2

AO /

Spec. Ref.

06.2 40 (%) 1 AO2

4.9.1.2

AO /

Spec. Ref.

06.3 carbon dioxide was dissolved in 1 AO3

oceans 4.9.1.2

AO /

Spec. Ref.

06.4 nitrogen was released during 1 AO3

volcanic activity 4.9.1.2

AO /

Spec. Ref.

06.5 2.5 billion years ago 1 AO3

4.9.1.1

AO /

Spec. Ref.

06.6 ammonia 1 AO1

4.9.1.2

methane 1

AO /

Spec. Ref.

06.7 photosynthesis 1 AO1

4.9.1.3

Total Question 6 8

How to answer it

Earth's Early Atmosphere & How It Changed

Topic 9: Chemistry of the Atmosphere

What this question tests

This question assesses fundamental recall and graphical skills regarding how the composition of the Earth's atmosphere has evolved over 4.6 billion years:

  • Graph skills: Continuing a smooth line of best fit and taking readings from a scale.
  • Atmospheric changes: Why carbon dioxide decreased (dissolving into newly formed oceans).
  • Volcanic activity: How volcanoes released nitrogen, water vapour, carbon dioxide, methane, and ammonia.
  • Present-day atmosphere: Recalling that nitrogen makes up ~78–80% of our atmosphere today.
  • Photosynthesis: The biological process by algae and plants that removed CO₂ and produced O₂.
Question 06.1 (1 Mark)

Completing the Line of Best Fit

AO2 • Spec Ref: 4.9.1.2

✅ Correct Action

Draw a smooth curved line continuing from the point at 3.50 billion years ago, passing smoothly through or very close to the points at 3.25, 3.00, and ending at 2.75 billion years ago.

🧠 Exam Technique

  • Turn the paper so your wrist acts as a natural pivot to draw a single smooth curve.
  • Look ahead at the target points rather than looking right under your pencil tip.
  • Do not use a ruler for curved trends.

❌ Common Errors

  • Dot-to-dot lines: Joining points with straight ruler lines loses the mark.
  • Feathered/hairy lines: Multiple overlapping sketchy pencil strokes.
  • Stopping before 2.75 billion years ago.
Mark Scheme: 1 mark for an acceptable, smooth line of best fit extending to 2.75 billion years ago.
Question 06.2 (1 Mark)

Reading Values from Figure 5

AO2 • Spec Ref: 4.9.1.2

✅ Correct Answer

40 %

🧠 Step-by-Step Method

  1. Locate 3.75 on the horizontal axis (halfway between 3.50 and 4.00).
  2. Follow the grid line vertically up to meet the plotted point on the curve.
  3. Track horizontally left to the vertical axis to read the value: exactly 40.

❌ Common Errors

Misreading the horizontal axis scale (each large grid square = 0.50 billion years, so each small square = 0.05 billion years).

Mark Scheme: 40 (%) [1 mark].
Question 06.3 (1 Mark)

Cause of Carbon Dioxide Decrease

AO3 • Spec Ref: 4.9.1.2

✅ Correct Box to Tick

☑ Carbon dioxide was dissolved in oceans.

💡 Key Knowledge

As the Earth cooled, water vapour produced by volcanoes condensed to form the oceans. Huge amounts of CO₂ dissolved in this water, forming soluble carbonate compounds and precipitates (sediments).

❌ Why Other Options Are Wrong

  • Combustion of fossil fuels: Fossil fuels had not formed yet, and combustion releases CO₂, it does not remove it.
  • Released during volcanic activity: Volcanoes increased CO₂, rather than decreasing it.
Mark Scheme: carbon dioxide was dissolved in oceans [1 mark].
Question 06.4 (1 Mark)

Cause of Nitrogen Increase

AO3 • Spec Ref: 4.9.1.2

✅ Correct Box to Tick

☑ Nitrogen was released during volcanic activity.

💡 Key Knowledge

Intense volcanic activity in the first billion years produced large volumes of nitrogen gas (N₂). Because nitrogen is an unreactive gas, it gradually built up in the atmosphere over geological time.

🧠 Exam Tip

Remember the volcanic emissions: mostly carbon dioxide and water vapour, with small but increasing amounts of nitrogen, plus traces of methane (CH₄) and ammonia (NH₃).

Mark Scheme: nitrogen was released during volcanic activity [1 mark].
Question 06.5 (1 Mark)

When Nitrogen Levels Approached Modern Day

AO3 • Spec Ref: 4.9.1.1

✅ Correct Box to Tick

☑ 2.5 billion years ago

💡 Key Knowledge

Today's atmosphere is composed of approximately 78% to 80% nitrogen. Looking at Table 2:

  • 3.0 billion years ago = 75%
  • 2.5 billion years ago = 78% (matches modern levels!)

❌ Common Trap

Selecting 4.5 billion years ago by confusing the age of the Earth with when the atmosphere reached modern composition.

Mark Scheme: 2.5 billion years ago [1 mark].
Question 06.6 (2 Marks)

Gases in the Early Atmosphere

AO1 • Spec Ref: 4.9.1.2

✅ Correct Boxes to Tick (Select Two)

  • ☑ Ammonia (NH₃)
  • ☑ Methane (CH₄)

💡 Key Knowledge

The early atmosphere resembled the atmospheres of Mars and Venus today. Along with CO₂, H₂O, and N₂, volcanoes released trace amounts of:

  • Methane (CH₄)
  • Ammonia (NH₃)

❌ Distractors to Avoid

  • Chlorine (Cl₂): Far too reactive to exist free in early atmospheric air.
  • Helium / Hydrogen: Extremely light gases that easily escaped Earth's gravitational pull into space.
Mark Scheme: Ammonia (1 mark), Methane (1 mark). If more than two boxes are ticked, marks are deducted!
Question 06.7 (1 Mark)

Process Producing Oxygen

AO1 • Spec Ref: 4.9.1.3

✅ Correct Answer

Photosynthesis

💡 Key Knowledge

Around 2.7 billion years ago, algae first evolved and began producing oxygen gas via photosynthesis:

carbon dioxide + water → glucose + oxygen
6CO₂ + 6H₂O → C₆H₁₂O₆ + 6O₂

Over the next billion years, green plants also evolved, boosting O₂ levels to allow animals to evolve.

❌ Common Errors

Writing "respiration" instead of photosynthesis. Aerobic respiration consumes oxygen, whereas photosynthesis produces it!

Mark Scheme: photosynthesis [1 mark]. Spelling must be recognisable.

Topics

Chemistry · C9: Chemistry of the Atmosphere

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), June 2025. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.