AQA GCSE Chemistry Chemistry Paper 2 (Foundation), June 2025: Question 6
8 marks · Low Demand difficulty · Short Answer
Analyze changes in the Earth's early atmosphere using graphical and tabular data to identify gas proportions, causes of atmospheric evolution, and the process producing oxygen.
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Question text
06 The Earth’s atmosphere has changed over time.
Figure 5 shows the percentage of carbon dioxide in the Earth’s atmosphere between
4.5 billion and 2.75 billion years ago.
Figure 5
06.1 Complete Figure 5.
You should extend the line of best fit to the plotted point at 2.75 billions of years ago.
[1 mark]
06.2 What was the percentage (%) of carbon dioxide in the Earth’s atmosphere
3.75 billions of years ago?
Use Figure 5.
[1 mark]
%
06.3 The percentage of carbon dioxide changed between 4.5 and 3.0 billion years ago.
Which was a cause of this change?
Use Figure 5.
[1 mark]
Tick ( ) one box.
Carbon dioxide was dissolved in oceans.
Carbon dioxide was produced during combustion of fossil fuels.
Carbon dioxide was released during volcanic activity.22
Table 2 shows information about the percentage of nitrogen present in the
Earth’s atmosphere.
Table 2
Time in billions of Percentage (%) of
years ago nitrogen
4.5 4
4.0 34
3.5 62
3.0 75
2.5 78
06.4 The percentage of nitrogen changed between 4.5 and 2.5 billion years ago.
*21Which was a cause of this change?*
Use Table 2.
[1 mark]
Tick ( ) one box.
Nitrogen was dissolved in oceans.
Nitrogen was produced during combustion of fossil fuels.
Nitrogen was released during volcanic activity.23
06.5 When did the percentage of nitrogen in the Earth’s atmosphere become similar to the
percentage of nitrogen in the Earth’s atmosphere today?
Use Table 2.
[1 mark]
Tick ( ) one box.
2.5 billion years ago
3.0 billion years ago
3.5 billion years ago
4.0 billion years ago
4.5 billion years ago
06.6 Which two gases may also have been present in the Earth’s early atmosphere?
[2 marks]
Tick ( ) two boxes.
Ammonia
Chlorine
Helium
Hydrogen
Methane
06.7 Name the process that started to produce oxygen in the Earth’s atmosphere
2.7 billion years ago.
[1 mark]
Mark scheme
Show the mark scheme
Question 6
AO /
Question Answers Extra information Mark
Spec. Ref.
06.1 line of best fit 1 AO2
4.9.1.2
AO /
Spec. Ref.
06.2 40 (%) 1 AO2
4.9.1.2
AO /
Spec. Ref.
06.3 carbon dioxide was dissolved in 1 AO3
oceans 4.9.1.2
AO /
Spec. Ref.
06.4 nitrogen was released during 1 AO3
volcanic activity 4.9.1.2
AO /
Spec. Ref.
06.5 2.5 billion years ago 1 AO3
4.9.1.1
AO /
Spec. Ref.
06.6 ammonia 1 AO1
4.9.1.2
methane 1
AO /
Spec. Ref.
06.7 photosynthesis 1 AO1
4.9.1.3
Total Question 6 8
How to answer it
Earth's Early Atmosphere & How It Changed
What this question tests
This question assesses fundamental recall and graphical skills regarding how the composition of the Earth's atmosphere has evolved over 4.6 billion years:
- Graph skills: Continuing a smooth line of best fit and taking readings from a scale.
- Atmospheric changes: Why carbon dioxide decreased (dissolving into newly formed oceans).
- Volcanic activity: How volcanoes released nitrogen, water vapour, carbon dioxide, methane, and ammonia.
- Present-day atmosphere: Recalling that nitrogen makes up ~78–80% of our atmosphere today.
- Photosynthesis: The biological process by algae and plants that removed CO₂ and produced O₂.
Completing the Line of Best Fit
AO2 • Spec Ref: 4.9.1.2
✅ Correct Action
Draw a smooth curved line continuing from the point at 3.50 billion years ago, passing smoothly through or very close to the points at 3.25, 3.00, and ending at 2.75 billion years ago.
🧠 Exam Technique
- Turn the paper so your wrist acts as a natural pivot to draw a single smooth curve.
- Look ahead at the target points rather than looking right under your pencil tip.
- Do not use a ruler for curved trends.
❌ Common Errors
- Dot-to-dot lines: Joining points with straight ruler lines loses the mark.
- Feathered/hairy lines: Multiple overlapping sketchy pencil strokes.
- Stopping before 2.75 billion years ago.
Reading Values from Figure 5
AO2 • Spec Ref: 4.9.1.2
✅ Correct Answer
40 %
🧠 Step-by-Step Method
- Locate 3.75 on the horizontal axis (halfway between 3.50 and 4.00).
- Follow the grid line vertically up to meet the plotted point on the curve.
- Track horizontally left to the vertical axis to read the value: exactly 40.
❌ Common Errors
Misreading the horizontal axis scale (each large grid square = 0.50 billion years, so each small square = 0.05 billion years).
Cause of Carbon Dioxide Decrease
AO3 • Spec Ref: 4.9.1.2
✅ Correct Box to Tick
☑ Carbon dioxide was dissolved in oceans.
💡 Key Knowledge
As the Earth cooled, water vapour produced by volcanoes condensed to form the oceans. Huge amounts of CO₂ dissolved in this water, forming soluble carbonate compounds and precipitates (sediments).
❌ Why Other Options Are Wrong
- Combustion of fossil fuels: Fossil fuels had not formed yet, and combustion releases CO₂, it does not remove it.
- Released during volcanic activity: Volcanoes increased CO₂, rather than decreasing it.
Cause of Nitrogen Increase
AO3 • Spec Ref: 4.9.1.2
✅ Correct Box to Tick
☑ Nitrogen was released during volcanic activity.
💡 Key Knowledge
Intense volcanic activity in the first billion years produced large volumes of nitrogen gas (N₂). Because nitrogen is an unreactive gas, it gradually built up in the atmosphere over geological time.
🧠 Exam Tip
Remember the volcanic emissions: mostly carbon dioxide and water vapour, with small but increasing amounts of nitrogen, plus traces of methane (CH₄) and ammonia (NH₃).
When Nitrogen Levels Approached Modern Day
AO3 • Spec Ref: 4.9.1.1
✅ Correct Box to Tick
☑ 2.5 billion years ago
💡 Key Knowledge
Today's atmosphere is composed of approximately 78% to 80% nitrogen. Looking at Table 2:
- 3.0 billion years ago = 75%
- 2.5 billion years ago = 78% (matches modern levels!)
❌ Common Trap
Selecting 4.5 billion years ago by confusing the age of the Earth with when the atmosphere reached modern composition.
Gases in the Early Atmosphere
AO1 • Spec Ref: 4.9.1.2
✅ Correct Boxes to Tick (Select Two)
- ☑ Ammonia (NH₃)
- ☑ Methane (CH₄)
💡 Key Knowledge
The early atmosphere resembled the atmospheres of Mars and Venus today. Along with CO₂, H₂O, and N₂, volcanoes released trace amounts of:
- Methane (CH₄)
- Ammonia (NH₃)
❌ Distractors to Avoid
- Chlorine (Cl₂): Far too reactive to exist free in early atmospheric air.
- Helium / Hydrogen: Extremely light gases that easily escaped Earth's gravitational pull into space.
Process Producing Oxygen
AO1 • Spec Ref: 4.9.1.3
✅ Correct Answer
Photosynthesis
💡 Key Knowledge
Around 2.7 billion years ago, algae first evolved and began producing oxygen gas via photosynthesis:
carbon dioxide + water → glucose + oxygen
6CO₂ + 6H₂O → C₆H₁₂O₆ + 6O₂
Over the next billion years, green plants also evolved, boosting O₂ levels to allow animals to evolve.
❌ Common Errors
Writing "respiration" instead of photosynthesis. Aerobic respiration consumes oxygen, whereas photosynthesis produces it!
Topics
Chemistry · C9: Chemistry of the Atmosphere
Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), June 2025. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.