AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2018: Question 4
9 marks · Standard Demand difficulty · Short Answer
Answer short questions about halogens involving state symbols, dot-and-cross bonding in fluorine, electron number in F2, balancing the reaction of aluminium with bromine, and explaining why chlorine is more reactive than bromine.
Practise this questionQuestion
Question text
04 This question is about the halogens.
04.1 Write the state symbol for chlorine at room temperature.
[1 mark]
Cl2 ( )
04.2 Figure 4 represents one molecule of fluorine.
Complete the dot and cross diagram on Figure 4
You should show only the electrons in the outer shells.
[2 marks]
Figure 4
04.3 19
A fluorine atom can be represented as F
What is the total number of electrons in a fluorine molecule (F2)?
[1 mark]
Tick one box.
9 14 18 38
04.4 Aluminium reacts with bromine to produce aluminium bromide.
Complete the balanced chemical equation for this reaction.
[2 marks]
Al + Br 2 9
04.5 When chlorine reacts with potassium bromide, chlorine displaces bromine.
Cl2 + 2 KBr Br2 + 2 KCl
Explain why chlorine is more reactive than bromine.
[3 marks]
Mark scheme
Show the mark scheme
AO /
Question Answers Extra information Mark
Spec. Ref.
04.1 g do not accept upper case (G) 1 AO1
do not accept gas 5.1.2.6
04.2 one shared pair anywhere in 1 AO1
overlap between two circles or 5.1.2.6
5.2.1.4
on intersection
6 other electrons on each atom 1 AO2
5.1.2.6
allow dots or crosses or mixture 5.2.1.4
for all marks
ignore any inner shell electrons
04.3 18 1 AO2
5.1.1.5
5.1.2.6
04.4 ignore state symbols AO2
ignore charges 5.1.1.1
ignore brackets as eg Al(Br)3 5.1.2.6
AlBr3 1
2 Al + 3 Br2 ( 2 AlBr3 ) 1
allow 1 mark for balancing their
equation with an incorrect
product
04.5 max 2 if outer shell / level not
mentioned
'it' refers to chlorine
allow converse reasons for
bromine being less reactive
chlorine is a smaller atom ignore chlorine has fewer 1 AO1
5.1.2.6
or has fewer energy levels electrons
or outer shell closer to nucleus
chlorine has less shielding 1 AO1
or 5.1.2.6 11
has the greater attraction
between the nucleus and the
outer shell or incoming electron
therefore chlorine can gain an 1 AO2
electron (into the outer shell) 5.1.2.6
more easily
if no other marks awarded allow
1 mark for correct trend in
reactivity in Group 7
do not accept reference to
incorrect particles eg chloride
atom
Total 9
How to answer it
Halogens: states, bonding, equations and reactivity
You need to know simple Group 7 facts: state symbols, dot-and-cross diagrams for covalent molecules, counting electrons from atomic number, writing formulae for halides, balancing equations, and explaining why reactivity changes down the group.
Short title: Halogens and their reactions
Total marks: 9 — most marks come from secure recall and clear explanations using the right science words.
Part 04.1 — State symbol for chlorine at room temperature
1 mark
✅ Correct answer
Cl₂ (g)
So the state symbol is g.
💡 Key knowledge
- Chlorine is a gas at room temperature.
- State symbols: (s) solid, (l) liquid, (g) gas, (aq) aqueous.
🧠 Exam technique
- Write the symbol exactly as g.
- The mark scheme does not accept upper case G.
- Do not write the word “gas” if a state symbol is asked for.
❌ Common errors
- Using G instead of g.
- Leaving the blank empty.
- Writing (l) or (s) by mistake.
Part 04.2 — Dot and cross diagram for fluorine molecule
2 marks
✅ Correct answer
- Draw one shared pair of electrons in the overlap between the two fluorine atoms.
- Show 6 other outer-shell electrons on each fluorine atom.
What should be drawn: two overlapping circles labelled F and F, with one electron from each atom in the overlap to make the covalent bond, and three lone pairs on each atom outside the overlap.
💡 Key knowledge
- Fluorine is in Group 7, so each atom has 7 outer-shell electrons.
- In F₂, each atom shares 1 electron to make a single covalent bond.
- This leaves 6 outer electrons on each fluorine atom as lone pairs.
🧠 Exam technique
- The exact choice of dots and crosses is flexible.
- You can use dots only, crosses only, or a mixture — the key is to show the shared pair clearly.
- The mark scheme says to ignore inner-shell electrons, so only draw outer-shell electrons.
❌ Common errors
- Showing two shared pairs instead of one.
- Putting all 7 electrons in the overlap.
- Forgetting the 6 other electrons on each atom.
- Drawing inner-shell electrons when they are not needed.
📐 How to build the diagram
- Write F and F.
- Remember each fluorine has 7 outer electrons.
- Place 1 electron from each atom in the overlap.
- Place the remaining 6 electrons around each atom as three lone pairs.
- Check that the overlap contains exactly one shared pair.
Part 04.3 — Total number of electrons in a fluorine molecule
1 mark
✅ Correct answer
18
💡 Key knowledge
- The atomic number of fluorine is 9.
- A neutral fluorine atom has 9 electrons.
- F₂ has two fluorine atoms, so 9 + 9 = 18 electrons.
🧠 Exam technique
- Use the atomic number, not the mass number.
- In this question, the number of electrons is the same as the number of protons because fluorine atoms are neutral.
❌ Common errors
- Answering 9 because you forgot it is a molecule.
- Using the mass number 19 by mistake.
- Giving 14 or 38 from unrelated counting errors.
📐 Step-by-step calculation
- Fluorine has atomic number 9.
- One fluorine atom has 9 electrons.
- F₂ means 2 fluorine atoms.
- Calculate: 9 × 2 = 18.
Part 04.4 — Balanced chemical equation for aluminium bromide
2 marks
✅ Correct answer
2 Al + 3 Br₂ → 2 AlBr₃
The product formula is AlBr₃.
💡 Key knowledge
- Aluminium forms Al³⁺ ions.
- Bromine forms Br⁻ ions.
- So the compound must contain 1 aluminium and 3 bromine atoms: AlBr₃.
🧠 Exam technique
- First write the correct formula for the product, then balance the equation.
- The mark scheme allows a range of equivalent formatting, including brackets as Al(Br)₃ , but the standard answer is AlBr₃.
- State symbols and charges are ignored here.
❌ Common errors
- Writing the wrong formula, e.g. AlBr or AlBr₂.
- Forgetting bromine is Br₂ in its elemental form.
- Not balancing atoms on both sides.
📐 Balancing steps
- Write the unbalanced equation: Al + Br₂ → AlBr₃.
- Balance bromine first: each AlBr₃ has 3 Br atoms, so use 3 Br₂ to make 6 Br atoms.
- Now there are 2 AlBr₃ molecules on the right, so balance aluminium with 2 Al.
- Final equation: 2 Al + 3 Br₂ → 2 AlBr₃.
Part 04.5 — Why chlorine is more reactive than bromine
3 marks
✅ Correct answer
- Chlorine is a smaller atom than bromine, or it has fewer energy levels.
- It has less shielding.
- So there is a greater attraction between the nucleus and an incoming electron, meaning chlorine can gain an electron more easily.
💡 Key knowledge
- Group 7 reactivity decreases down the group.
- Top halogens are more reactive because they attract an extra electron more strongly.
- In the reaction shown, chlorine displaces bromine from potassium bromide because chlorine is more reactive.
🧠 Exam technique
- To get full marks, build the explanation in a chain:
- smaller atom / fewer shells → less shielding → stronger attraction → gains electron more easily.
- Use chlorine and bromine correctly. The “it” in the question refers to chlorine.
- If you do not mention outer shell or energy levels, the mark scheme limits the marks you can gain.
❌ Common errors
- Saying chlorine is more reactive because it has more electrons — this is not the mark point.
- Referring to the wrong ion, such as chloride atom.
- Giving a vague answer like “chlorine is stronger” without explaining why.
📐 Best 3-mark answer structure
- Chlorine is a smaller atom / has fewer energy levels.
- It has less shielding.
- There is a stronger attraction to an incoming electron, so chlorine gains an electron more easily.
Examiner insight: what scored well
💡 Top responses did these things
- Used the exact state symbol (g).
- In the dot-and-cross diagram, showed one shared pair and the correct number of outer electrons.
- Used the atomic number to count electrons correctly in F₂.
- Wrote the correct formula AlBr₃ before balancing.
- Explained reactivity using size, shielding and attraction rather than just saying “it is more reactive”.
❌ Where students lost marks
- Not knowing chlorine is a gas.
- Drawing the fluorine molecule with the wrong number of shared electrons.
- Using 19 instead of 9 to count electrons.
- Forgetting bromine exists as Br₂.
- Giving a trend statement with no explanation of outer shell distance or shielding.
Quick revision checklist
- Know the state of halogens at room temperature.
- Be able to draw a simple covalent dot-and-cross diagram.
- Use atomic number to count electrons in neutral atoms.
- Write and balance simple equations involving halogens and metals.
- Explain Group 7 reactivity in terms of atomic size, shielding, and attraction for electrons.
Topics
Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter
Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2018. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.