AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2018: Question 4

9 marks · Standard Demand difficulty · Short Answer

Answer short questions about halogens involving state symbols, dot-and-cross bonding in fluorine, electron number in F2, balancing the reaction of aluminium with bromine, and explaining why chlorine is more reactive than bromine.

Practise this question

Question

The question page is headed 'This question is about the halogens' and contains five short sub-questions numbered 04.1 to 04.5, worth a total of 9 marks. The tasks ask for the state symbol of chlorine at room temperature, completion of a dot-and-cross diagram for one molecule of fluorine shown as two overlapping circles each labelled F with one electron already marked on each atom, selection of the total number of electrons in F2 from tick-box options 9, 14, 18 and 38, completion of a balanced equation shown as '__ Al + __ Br2 -> 2 ______', and an explanation of why chlorine displaces bromine from potassium bromide in the equation 'Cl2 + 2 KBr -> Br2 + 2 KCl'. The page includes blank answer lines and tick boxes, with no graphs or tables.
Question text

04 This question is about the halogens.

04.1 Write the state symbol for chlorine at room temperature.

[1 mark]

Cl2 ( )

04.2 Figure 4 represents one molecule of fluorine.

Complete the dot and cross diagram on Figure 4

You should show only the electrons in the outer shells.

[2 marks]

Figure 4

04.3 19

A fluorine atom can be represented as F

What is the total number of electrons in a fluorine molecule (F2)?

[1 mark]

Tick one box.

9 14 18 38

04.4 Aluminium reacts with bromine to produce aluminium bromide.

Complete the balanced chemical equation for this reaction.

[2 marks]

Al + Br 2 9

04.5 When chlorine reacts with potassium bromide, chlorine displaces bromine.

Cl2 + 2 KBr Br2 + 2 KCl

Explain why chlorine is more reactive than bromine.

[3 marks]

Mark scheme

Show the mark scheme The mark scheme is a table with columns for Question, Answers, Extra information, Mark, and AO/Spec. Ref., covering parts 04.1 to 04.5 and showing a total of 9 marks. It gives 'g' for chlorine's state symbol, a completed fluorine dot-and-cross diagram with one shared pair in the overlap and six other outer-shell electrons on each fluorine atom, '18' for the total electrons in F2, and the balanced equation '2 Al + 3 Br2 -> 2 AlBr3'. For the final explanation it awards marks for stating chlorine is smaller or has fewer energy levels with outer shell closer to the nucleus, has less shielding or greater attraction between nucleus and incoming electron, and therefore gains an electron more easily; extra notes specify accepted and rejected wording.

AO /

Question Answers Extra information Mark

Spec. Ref.

04.1 g do not accept upper case (G) 1 AO1

do not accept gas 5.1.2.6

04.2 one shared pair anywhere in 1 AO1

overlap between two circles or 5.1.2.6

5.2.1.4

on intersection

6 other electrons on each atom 1 AO2

5.1.2.6

allow dots or crosses or mixture 5.2.1.4

for all marks

ignore any inner shell electrons

04.3 18 1 AO2

5.1.1.5

5.1.2.6

04.4 ignore state symbols AO2

ignore charges 5.1.1.1

ignore brackets as eg Al(Br)3 5.1.2.6

AlBr3 1

2 Al + 3 Br2 ( 2 AlBr3 ) 1

allow 1 mark for balancing their

equation with an incorrect

product

04.5 max 2 if outer shell / level not

mentioned

'it' refers to chlorine

allow converse reasons for

bromine being less reactive

chlorine is a smaller atom ignore chlorine has fewer 1 AO1

5.1.2.6

or has fewer energy levels electrons

or outer shell closer to nucleus

chlorine has less shielding 1 AO1

or 5.1.2.6 11

has the greater attraction

between the nucleus and the

outer shell or incoming electron

therefore chlorine can gain an 1 AO2

electron (into the outer shell) 5.1.2.6

more easily

if no other marks awarded allow

1 mark for correct trend in

reactivity in Group 7

do not accept reference to

incorrect particles eg chloride

atom

Total 9

How to answer it

Halogens: states, bonding, equations and reactivity

What this question tests

You need to know simple Group 7 facts: state symbols, dot-and-cross diagrams for covalent molecules, counting electrons from atomic number, writing formulae for halides, balancing equations, and explaining why reactivity changes down the group.

Question focus: Group 7 / Halogens

Short title: Halogens and their reactions

Total marks: 9 — most marks come from secure recall and clear explanations using the right science words.

Part 04.1 — State symbol for chlorine at room temperature

1 mark

✅ Correct answer

Cl₂ (g)

So the state symbol is g.

💡 Key knowledge

  • Chlorine is a gas at room temperature.
  • State symbols: (s) solid, (l) liquid, (g) gas, (aq) aqueous.

🧠 Exam technique

  • Write the symbol exactly as g.
  • The mark scheme does not accept upper case G.
  • Do not write the word “gas” if a state symbol is asked for.

❌ Common errors

  • Using G instead of g.
  • Leaving the blank empty.
  • Writing (l) or (s) by mistake.

Part 04.2 — Dot and cross diagram for fluorine molecule

2 marks

✅ Correct answer

  • Draw one shared pair of electrons in the overlap between the two fluorine atoms.
  • Show 6 other outer-shell electrons on each fluorine atom.

What should be drawn: two overlapping circles labelled F and F, with one electron from each atom in the overlap to make the covalent bond, and three lone pairs on each atom outside the overlap.

💡 Key knowledge

  • Fluorine is in Group 7, so each atom has 7 outer-shell electrons.
  • In F₂, each atom shares 1 electron to make a single covalent bond.
  • This leaves 6 outer electrons on each fluorine atom as lone pairs.

🧠 Exam technique

  • The exact choice of dots and crosses is flexible.
  • You can use dots only, crosses only, or a mixture — the key is to show the shared pair clearly.
  • The mark scheme says to ignore inner-shell electrons, so only draw outer-shell electrons.

❌ Common errors

  • Showing two shared pairs instead of one.
  • Putting all 7 electrons in the overlap.
  • Forgetting the 6 other electrons on each atom.
  • Drawing inner-shell electrons when they are not needed.

📐 How to build the diagram

  1. Write F and F.
  2. Remember each fluorine has 7 outer electrons.
  3. Place 1 electron from each atom in the overlap.
  4. Place the remaining 6 electrons around each atom as three lone pairs.
  5. Check that the overlap contains exactly one shared pair.

Part 04.3 — Total number of electrons in a fluorine molecule

1 mark

✅ Correct answer

18

💡 Key knowledge

  • The atomic number of fluorine is 9.
  • A neutral fluorine atom has 9 electrons.
  • F₂ has two fluorine atoms, so 9 + 9 = 18 electrons.

🧠 Exam technique

  • Use the atomic number, not the mass number.
  • In this question, the number of electrons is the same as the number of protons because fluorine atoms are neutral.

❌ Common errors

  • Answering 9 because you forgot it is a molecule.
  • Using the mass number 19 by mistake.
  • Giving 14 or 38 from unrelated counting errors.

📐 Step-by-step calculation

  1. Fluorine has atomic number 9.
  2. One fluorine atom has 9 electrons.
  3. F₂ means 2 fluorine atoms.
  4. Calculate: 9 × 2 = 18.

Part 04.4 — Balanced chemical equation for aluminium bromide

2 marks

✅ Correct answer

2 Al + 3 Br₂ → 2 AlBr₃

The product formula is AlBr₃.

💡 Key knowledge

  • Aluminium forms Al³⁺ ions.
  • Bromine forms Br⁻ ions.
  • So the compound must contain 1 aluminium and 3 bromine atoms: AlBr₃.

🧠 Exam technique

  • First write the correct formula for the product, then balance the equation.
  • The mark scheme allows a range of equivalent formatting, including brackets as Al(Br)₃ , but the standard answer is AlBr₃.
  • State symbols and charges are ignored here.

❌ Common errors

  • Writing the wrong formula, e.g. AlBr or AlBr₂.
  • Forgetting bromine is Br₂ in its elemental form.
  • Not balancing atoms on both sides.

📐 Balancing steps

  1. Write the unbalanced equation: Al + Br₂ → AlBr₃.
  2. Balance bromine first: each AlBr₃ has 3 Br atoms, so use 3 Br₂ to make 6 Br atoms.
  3. Now there are 2 AlBr₃ molecules on the right, so balance aluminium with 2 Al.
  4. Final equation: 2 Al + 3 Br₂ → 2 AlBr₃.

Part 04.5 — Why chlorine is more reactive than bromine

3 marks

✅ Correct answer

  • Chlorine is a smaller atom than bromine, or it has fewer energy levels.
  • It has less shielding.
  • So there is a greater attraction between the nucleus and an incoming electron, meaning chlorine can gain an electron more easily.

💡 Key knowledge

  • Group 7 reactivity decreases down the group.
  • Top halogens are more reactive because they attract an extra electron more strongly.
  • In the reaction shown, chlorine displaces bromine from potassium bromide because chlorine is more reactive.

🧠 Exam technique

  • To get full marks, build the explanation in a chain:
  • smaller atom / fewer shells → less shielding → stronger attraction → gains electron more easily.
  • Use chlorine and bromine correctly. The “it” in the question refers to chlorine.
  • If you do not mention outer shell or energy levels, the mark scheme limits the marks you can gain.

❌ Common errors

  • Saying chlorine is more reactive because it has more electrons — this is not the mark point.
  • Referring to the wrong ion, such as chloride atom.
  • Giving a vague answer like “chlorine is stronger” without explaining why.

📐 Best 3-mark answer structure

  1. Chlorine is a smaller atom / has fewer energy levels.
  2. It has less shielding.
  3. There is a stronger attraction to an incoming electron, so chlorine gains an electron more easily.

Examiner insight: what scored well

💡 Top responses did these things

  • Used the exact state symbol (g).
  • In the dot-and-cross diagram, showed one shared pair and the correct number of outer electrons.
  • Used the atomic number to count electrons correctly in F₂.
  • Wrote the correct formula AlBr₃ before balancing.
  • Explained reactivity using size, shielding and attraction rather than just saying “it is more reactive”.

❌ Where students lost marks

  • Not knowing chlorine is a gas.
  • Drawing the fluorine molecule with the wrong number of shared electrons.
  • Using 19 instead of 9 to count electrons.
  • Forgetting bromine exists as Br₂.
  • Giving a trend statement with no explanation of outer shell distance or shielding.

Quick revision checklist

  • Know the state of halogens at room temperature.
  • Be able to draw a simple covalent dot-and-cross diagram.
  • Use atomic number to count electrons in neutral atoms.
  • Write and balance simple equations involving halogens and metals.
  • Explain Group 7 reactivity in terms of atomic size, shielding, and attraction for electrons.

Topics

Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2018. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.