AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2019: Question 1

9 marks · Standard Demand difficulty · Short Answer

Determine the reactivity order of calcium, magnesium, zinc and copper with hydrochloric acid, identify control and independent variables, predict beryllium's reactivity from the periodic table, and calculate concentration in g per dm³.

Practise this question

Question

The question page is titled as being about reactions of metals and shows four test tubes labelled calcium, copper, magnesium and zinc added to hydrochloric acid. The calcium tube has vigorous bubbling, magnesium has moderate bubbling, zinc has fewer bubbles, and copper shows no visible reaction; one label points to the bubbles as hydrogen. Below, part 01.1 is a 1-mark multiple-choice question asking for the order of decreasing reactivity with options Zn Ca Cu Mg, Ca Cu Mg Zn, Cu Zn Ca Mg, and Ca Mg Zn Cu; part 01.2 asks for two variables to keep constant for a fair comparison; part 01.3 asks for the independent variable; part 01.4 asks to predict the reactivity of beryllium compared with magnesium using the periodic table and give a reason; part 01.5 is a 3-mark calculation stating that a hydrochloric acid solution contains 3.2 g of hydrogen chloride in 50 cm cubed and asking for the concentration in g per dm cubed.
Question text

01 This question is about reactions of metals.

Figure 1 shows what happens when calcium, copper, magnesium and zinc are added

to hydrochloric acid.

Figure 1

01.1 What is the order of decreasing reactivity of these four metals?

[1 mark]

Tick ( ) one box.

Zn Ca Cu Mg

Ca Cu Mg Zn

Cu Zn Ca Mg

Ca Mg Zn Cu 3

A student wants to make a fair comparison of the reactivity of the metals with

hydrochloric acid.

01.2 Name two variables that must be kept constant.

[2 marks]

*02* 2

01.3 What is the independent variable in this reaction?

[1 mark]

01.4 Predict the reactivity of beryllium compared with magnesium.

Give a reason for your answer.

Use the periodic table.

[2 marks]

Reason

A solution of hydrochloric acid contains 3.2 g of hydrogen chloride in 50 cm3

01.5

Calculate the concentration of hydrogen chloride in g per dm3

[3 marks]

Concentration = g per dm3

Mark scheme

Show the mark scheme The mark scheme image provided does not match the question shown. It is a table for a different water-solubility question, with rows labelled 01.1 to 01.5 containing answers such as potable, boil water at 100 degrees Celsius, an evaporation method, a calculation giving 0.031 g, and a percentage calculation of 8.8 percent, with AO/specification references and a total of 13 marks. Because it refers to different content from the metal reactivity and hydrochloric acid question, it is not the corresponding mark scheme for this question.

AO /

Question Answers Extra information Mark

Spec. Ref.

01.1 Ca Mg Zn Cu 1 AO3

5.4.1.2

01.2 any two from: 2 AO3

5.4.1.2

• mass (of metal / element) allow weight

• surface area (of metal / ignore size

element) ignore length

• concentration (of acid) ignore pH

ignore strength

• volume (of acid)

• temperature (of acid) ignore room temperature

01.3 (type of) metal / element 1 AO2

5.4.1.2

01.4 allow converse answers for AO3

magnesium 5.1.2.3

5.1.2.5

MP2 only if MP1 is correct 5.4.1.2

(beryllium is) less reactive 1

any one from: 1

• greater attraction between

nucleus and outer electrons

• more energy is needed to

remove electrons

• loss of electrons is more

difficult

• outer electrons closer to

nucleus

• less shielding

allow higher in group

allow reactivity increases down

the group

ignore reactivity series 7

01.5 an answer of 64 (g per dm3) AO2

scores 3 marks 5.3.2.5

an incorrect answer for one

step does not prevent

allocation of marks for

subsequent steps

50 3

(dm ) 1

1000

= 0.05 (dm3) 1

3.2 3

( ) = 64 (g per dm ) 1

0.05

alternative approach:

3.2

(1)

= 0.064 (1)

(× 1000) = 64 (g per dm3) (1)

alternative approach:

1000

(1)

= 20 (1)

(× 3.2) = 64 (g per dm3) (1)

an answer of 0.16 / 0.064 / 0.64

/ 6.4 / 6.4 × 10–5 (g per dm3)

gains 2 marks

Total 9

How to answer it

Reactivity of Metals with Hydrochloric Acid

What this question tests
Recognising the reactivity series from reaction observations, identifying control variables and the independent variable, using the periodic table to compare Group 2 metals, and converting units to calculate concentration in g per dm³.

Overall question focus

This is a standard demand GCSE question. The marks come from a mix of recall, explanation, planning a fair test, and one multi-step calculation. The biggest scoring points are: knowing the reactivity order, keeping a test fair, and converting units correctly.

Part 01.1 – Ordering the metals by reactivity

Tick the correct order of decreasing reactivity

✅ Correct answer

Ca Mg Zn Cu

So the correct tick is Ca Mg Zn Cu.

💡 Key knowledge

  • More reactive metals react more vigorously with acids.
  • Calcium is more reactive than magnesium, zinc, and copper.
  • Copper is the least reactive here and does not react with dilute hydrochloric acid.

🧠 Exam technique

Use the pattern of bubbles. More bubbles = more hydrogen gas made = faster reaction = more reactive metal.

To score the mark, you only need the correct order in the box.

❌ Common errors

  • Putting copper above zinc because it is “heavier” or “looks more shiny”.
  • Mixing up magnesium and zinc.
  • Writing the right metals but in the wrong order.

Part 01.2 – Fair test: control variables

Name two variables that must be kept constant

✅ Correct answers

  • Same volume of hydrochloric acid
  • Same concentration of hydrochloric acid
  • Same mass of metal
  • Same size/surface area of metal pieces
  • Same temperature

Any two sensible control variables score the 2 marks.

💡 Key knowledge

A fair test means only the type of metal should change. Everything else must stay the same so the results can be compared properly.

🧠 Exam technique

Good answers are specific. For example:

same volume of acid is better than just same acid .

❌ Common errors

  • Saying “same metal” — that changes the variable being tested.
  • Writing “keep it constant” without saying what it is.
  • Using vague answers like “same conditions” with no detail.

Part 01.3 – Independent variable

What is the independent variable in this reaction?

✅ Correct answer

The type of metal used.

💡 Key knowledge

The independent variable is the thing you deliberately change. Here, the student changes the metal to see how it reacts with hydrochloric acid.

🧠 Exam technique

If a question asks about variables, link your answer to the experiment:

metal is the thing being compared; the acid is kept the same.

❌ Common errors

  • Saying “hydrochloric acid” — that is not the thing being changed.
  • Saying “the reaction” — too vague.

Part 01.4 – Predicting beryllium’s reactivity

Predict the reactivity of beryllium compared with magnesium. Give a reason using the periodic table.

✅ Correct answer

Beryllium is less reactive than magnesium.

Reason: They are both in Group 2, and reactivity increases down the group. Beryllium is above magnesium in the periodic table, so it is less reactive.

💡 Key knowledge

  • Group 2 metals all have 2 outer electrons.
  • Down Group 2, atoms get larger and the outer electrons are further from the nucleus.
  • Because of this, the outer electrons are lost more easily, so reactivity increases down the group.

🧠 Exam technique

To get both marks, include:

  • a comparison word: more or less reactive
  • a periodic table reason: beryllium is above magnesium in Group 2

❌ Common errors

  • Saying beryllium is more reactive because it is “higher up” without the Group 2 trend.
  • Giving no comparison with magnesium.
  • Confusing Group 2 with Group 1 trends.

Part 01.5 – Concentration calculation

Calculate the concentration of hydrogen chloride in g per dm³

📐 Calculations step-by-step

  1. Write down the mass and volume given: 3.2 g in 50 cm³.
  2. Convert the volume to dm³: 50 cm³ = 0.050 dm³.
  3. Use concentration = mass ÷ volume.
  4. Calculate: 3.2 ÷ 0.050 = 64.

Answer = 64 g per dm³

💡 Key knowledge

For concentration in g per dm³:

concentration = mass ÷ volume

Make sure the volume is in dm³, not cm³.

🧠 Exam technique

Show the conversion clearly to earn method marks:

50 cm³ ÷ 1000 = 0.050 dm³

Always include units in the final answer.

❌ Common errors

  • Using 50 cm³ directly in the calculation.
  • Dividing the wrong way round.
  • Writing 64 g/cm³ instead of 64 g/dm³.
  • Missing the unit completely.

Important note about the mark scheme image

The mark scheme shown in the image appears to include a different worked example for this part, but for this question’s given values the correct calculation is:

3.2 g ÷ 0.050 dm³ = 64 g per dm³

Quick examiner insight

💡 What top answers did well

  • Used the reactivity pattern correctly from the metal observations.
  • Gave specific control variables for a fair test.
  • Explained beryllium using Group 2 and the periodic table.
  • Showed the calculation method with correct unit conversion.

❌ Where students lose marks

  • Confusing independent and control variables.
  • Being too vague in explanation questions.
  • Forgetting to convert cm³ to dm³.
  • Not giving the final unit.

Final answer checklist

  • 01.1: Ca Mg Zn Cu
  • 01.2: Any two control variables, e.g. same volume and concentration of acid
  • 01.3: Type of metal used
  • 01.4: Beryllium is less reactive than magnesium because reactivity increases down Group 2
  • 01.5: 64 g per dm³

Topics

Chemistry · C4: Chemical Changes · C1: Atomic Structure and the Periodic Table · C3: Quantitative Chemistry

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2019. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.