AQA GCSE Combined Science: Trilogy Chemistry Paper 2 (Higher), 2019: Question 3

8 marks · Standard Demand difficulty · Short Answer

Define a formulation and explain how paper chromatography separates and identifies multiple dyes in a food colouring sample.

Practise this question

Question

A chemistry exam page headed question 03 states that the question is about chromatography of food colouring. It has four parts with lined answer spaces: 03.1 asks 'Food colouring is a formulation. What is a formulation?' for 1 mark; 03.2 asks to explain how paper chromatography separates the dyes in a food colouring, without giving experimental details, for 2 marks; 03.3 asks how a student could tell from the chromatogram that the food colouring contained more than one dye for 2 marks; and 03.4 asks how chromatography could be used to identify unknown dyes in the food colouring for 3 marks. There are no diagrams, only text, question numbers, and mark values on the right.
Question text

03 This question is about chromatography of food colouring.

03.1 Food colouring is a formulation.

What is a formulation?

[1 mark]

03.2 Explain how paper chromatography separates the dyes in a food colouring.

Do not give details of how to do the experiment.

[2 marks]

03.3 Explain how the student could tell from the chromatogram that the food colouring

contained more than one dye.

[2 marks]

03.4 Explain how the student could use chromatography to identify unknown dyes in the

food colouring.

[3 marks]

Mark scheme

Show the mark scheme The mark scheme is a table with columns for question, answers, extra information, mark, and AO/specification reference. For 03.1 it gives 'a mixture designed as a useful product'; for 03.2 it credits that dyes are distributed differently between the stationary and mobile phases, for example due to different solubilities or attractions to the paper or solvent, so they move different distances or at different rates up the paper; for 03.3 it credits different dots or colours in a vertical column above the original spot. For 03.4 it credits running known dyes alongside the food colouring, comparing distances moved or Rf values, and identifying dyes that match the known dyes; the total is 8 marks.

AO /

Question Answers Extra information Mark

Spec. Ref.

03.1 a mixture designed as a useful 1 AO1

product 5.8.1.2

03.2 dyes distributed differently allow dyes have different 1 AO1

between the stationary and solubilities

mobile phase allow dyes have different forces 5.8.1.3

of attraction for stationary phase

allow dyes have different forces

of attraction for mobile phase

allow dyes have different forces

of attraction to the paper

allow dyes have different forces

of attraction to the solvent

ignore density

(so dyes) move up the paper at 1

different speeds / rates allow (so dyes) move different

distances up the paper

ignore references to time

03.3 (because chromatogram has) 1 AO2

different dots / colours 5.8.1.3

in a (vertical) column allow above the (original) spot 1

03.4 run known dyes and food 1 AO2

colouring (as a chromatogram)

compare distances moved

1 AO2

or

compare Rf values

(so) can identify those that move allow (so) can identify those that 1 AO2

the same distance as known move different distances as 5.8.1.3

dyes unknown dyes

or or

(so) can identify those that have allow (so) can identify those that

the same R values as known have different Rf values as

f

unknown dyes

dyes

Total 8

How to answer it

Chromatography of Food Colourings

What this question tests
This question checks whether you can define a formulation, explain how paper chromatography separates dyes, and use chromatograms to identify unknown dyes by comparing spots or Rf values.
Overall topic: Separation techniques

Exam focus

This is a short, mark-by-mark chromatography question. The key is to use the right scientific language: mixture, stationary phase, mobile phase, different solubilities, and matching spots / Rf values.

Part 03.1 — What is a formulation? [1 mark]

✅ Correct answer

A mixture designed as a useful product.

💡 Key knowledge

  • A formulation is not just any mixture.
  • It is a mixture made for a specific purpose.
  • Food colouring is a formulation because it is designed to colour food effectively.

🧠 Exam technique

  • Use the phrase useful product or an equivalent idea.
  • One clear definition is enough for the mark.

❌ Common errors

  • Just saying “a mixture” is too vague.
  • Writing about chromatography here does not answer the question.
  • Don’t describe ingredients unless you link them to a designed product.
Mark point: 1 mark for a definition showing it is a mixture made for a purpose.

Part 03.2 — How paper chromatography separates the dyes [2 marks]

✅ Correct answer

Dyes are distributed differently between the stationary phase and the mobile phase. This means they move up the paper at different speeds or different distances.

💡 Key knowledge

  • The paper is the stationary phase.
  • The solvent is the mobile phase.
  • Dyes have different solubilities and different attractions to the paper/solvent.
  • Because of this, some dyes travel further than others.

🧠 Exam technique

  • You needed two linked ideas for 2 marks:
  • 1) dyes are distributed differently / have different solubilities or attractions,
  • 2) so they move different distances or at different rates.

❌ Common errors

  • “The dyes separate because they are different colours” is not enough.
  • Do not talk about how to set up the experiment — the question says not to.
  • “Different density” is wrong here.
Mark breakdown: 1 mark for different distribution between stationary and mobile phase; 1 mark for different speeds/distances up the paper.

Part 03.3 — How to tell the food colouring contained more than one dye [2 marks]

✅ Correct answer

The chromatogram would show different dots/colours in a vertical column, above the original spot.

💡 Key knowledge

  • If there is more than one dye, they separate into more than one spot.
  • All spots come from the same starting point, so they appear in line vertically.
  • More than one spot means more than one substance was present.

🧠 Exam technique

  • For full marks, mention both:
  • • more than one spot/colour, and
  • • the spots are in a vertical line/column above the starting point.

❌ Common errors

  • “The spot goes higher” is too vague.
  • Talking about “more than one line” is incorrect.
  • Not mentioning the vertical arrangement can lose a mark.
Examiner point: students lost marks when they only said there were “multiple spots” without stating that they appear in a vertical column above the original spot.

Part 03.4 — How to identify unknown dyes using chromatography [3 marks]

✅ Correct answer

Run known dyes and the food colouring as a chromatogram, then compare the distances moved or the Rf values. Any dye that moves the same distance or has the same Rf value as a known dye can be identified as that dye.

💡 Key knowledge

  • Matching spots means the dyes are likely the same.
  • Rf values are a reliable way to compare chromatograms.
  • Use the same solvent and conditions when comparing.

🧠 Exam technique

  • A full 3-mark answer usually needs:
  • 1) compare with known dyes,
  • 2) compare distance moved or Rf values,
  • 3) identify dyes that match.

❌ Common errors

  • Only saying “compare colours” is not enough.
  • Not mentioning known dyes loses an important mark point.
  • Confusing “same distance moved” with “same speed” is less precise.
  • If you mention Rf, make sure it is written clearly.

📐 Calculations / method note

This question does not require a calculation, but if you use Rf in an exam, remember the idea:

  1. Measure the distance from the start line to the centre of the dye spot.
  2. Measure the distance from the start line to the solvent front.
  3. Rf = distance moved by spot ÷ distance moved by solvent.
  4. Use the same solvent and same setup for a fair comparison.
Mark breakdown: 1 mark for running known dyes and the food colouring as chromatograms; 1 mark for comparing distances moved or Rf values; 1 mark for identifying dyes with the same distance or same Rf.

Quick revision summary

💡 Key knowledge to remember

  • Formulation = a mixture designed as a useful product.
  • Stationary phase = paper.
  • Mobile phase = solvent.
  • Different dyes travel different distances because of different solubilities/attractions.
  • More than one dye gives more than one spot.
  • Identify unknowns by matching to known dyes using distance moved or Rf values.

🧠 How to score well

  • Use chromatography vocabulary accurately.
  • Be concise but complete.
  • Link cause and effect: different attraction → different movement.
  • For identification, always mention comparison with known samples.

Topics

Chemistry · C8: Chemical Analysis · C10: Using Resources

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 2 (Higher), 2019. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.