AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2020: Question 1

9 marks · Standard Demand difficulty · Short Answer

Answer short questions about aluminium extraction, including atomic structure, reduction, electrolysis of aluminium oxide, electrode wear, and charge carriers in graphite, molten ionic compounds and metals.

Practise this question

Question

The question page is a chemistry set of four linked short-answer parts about the extraction of aluminium. It shows the nuclide symbol for aluminium as 27 over 13 next to Al and asks for the numbers of electrons and neutrons. A labelled diagram of an electrolysis cell shows a container with a molten mixture of aluminium oxide and cryolite, a layer of molten aluminium at the bottom, a negative electrode lining the cell, three hanging positive carbon electrodes connected by a metal wire, and labels for each part; later parts ask for the meaning of reduction, why the positive carbon electrodes must be continually replaced when oxygen forms there, and the free-moving charged particles in a graphite electrode, the molten mixture, and a metal wire.
Question text

01 This question is about the extraction of aluminium.

01.1 An aluminium atom is represented as:

13Al

Give the number of electrons and neutrons in the aluminium atom.

[2 marks]

Number of electrons

Number of neutrons

Aluminium is extracted by the electrolysis of a molten mixture of aluminium oxide

and cryolite.

Figure 1 shows the cell used for the electrolysis.

Figure 1

01.2 Aluminium is produced by the reduction of aluminium oxide (Al2O3).

What is meant by the term reduction?

[1 mark]

01.3 Oxygen is formed at the positive carbon electrodes.

Explain why the positive carbon electrodes must be continually replaced.

*02* [3 marks]

01.4 A substance conducts electricity because of free moving, charged particles.

What are the free moving, charged particles in a:

• carbon electrode (made from graphite)

• molten mixture of aluminium oxide and cryolite

• metal wire?

[3 marks]

Carbon electrode (made from graphite)

Molten mixture of aluminium oxide and cryolite

Metal wire

Mark scheme

Show the mark scheme The mark scheme is a table with columns for question number, answers, extra information, mark and AO/specification reference. It awards 01.1: 13 electrons and 14 neutrons, in that order only; 01.2: reduction means loss of oxygen, with gain of electrons by Al3+ allowed; 01.3: oxygen reacts with the carbon positive electrode at high temperature, so the electrode burns or wears away to produce carbon dioxide, with C plus O2 gives CO2 accepted; 01.4: graphite has delocalised electrons, the molten mixture has ions, and the metal wire has delocalised electrons. The total shown is 9 marks.

AO /

Question Answers Extra information Mark

Spec. Ref.

01.1 13 this order only 1 AO2

5.1.1.4

14 1 5.1.1.5

01.2 loss of oxygen allow (Al3+) gain of electrons 1 AO1

5.4.1.1

allow aluminium oxide loses 5.4.1.3

oxygen

01.3 allow anode for (positive)

electrode

(at high temperature) 1 AO1

oxygen reacts with carbon / 5.4.3.1

electrode 5.4.3.2

5.4.3.3

(so the positive) electrode 1

burns / wears away

to produce carbon dioxide 1

C + O2 → CO2 scores MP1 and

MP3

01.4 (delocalised) electron(s) 1 AO1

ion(s) 1 AO2

(delocalised) electron(s) 1 AO1

5.2.2.3

5.2.2.8

5.2.3.2

Total 9

How to answer it

Extraction of Aluminium

What this question tests

Knowing the structure of an aluminium atom, understanding reduction as loss of oxygen, explaining why carbon electrodes wear away in electrolysis, and identifying the charged particles that carry current in different materials.

Question overview

This is a straightforward GCSE electrolysis question. The marks are mainly for recall: atomic structure, reduction, electrode reactions, and electrical conduction in solids and molten compounds.

Total marks for the question: 9
Exam tip: many marks are one-word answers, so precision matters.

Part (a) / 01.1 — Number of electrons and neutrons in aluminium

Aluminium shown as ²⁷₁₃Al

✅ Correct answers

  • Number of electrons = 13
  • Number of neutrons = 14

Marks are awarded in this order only: electrons first, then neutrons.

💡 Key knowledge

  • In a neutral atom, electrons = protons.
  • The atomic number of aluminium is 13, so it has 13 protons and 13 electrons.
  • Number of neutrons = mass number − atomic number = 27 − 13 = 14.

🧠 Exam technique

  • Read the numbers from the nuclide symbol carefully.
  • Use the top number for mass number and the bottom number for atomic number.
  • Always check the answer order if the question asks for two values.

❌ Common errors

  • Mixing up atomic number and mass number.
  • Writing 27 electrons or 27 neutrons.
  • Forgetting that atoms are neutral, so electrons match protons.

Part (b) / 01.2 — What is reduction?

✅ Correct answer

Loss of oxygen.

💡 Key knowledge

  • Reduction can be remembered as removal of oxygen.
  • For aluminium oxide, reduction means aluminium oxide loses oxygen.
  • The mark scheme also allows: Al³⁺ gains electrons.

🧠 Exam technique

A one-mark definition question needs a short, exact answer. If you know both definitions, use the simplest one: loss of oxygen.

❌ Common errors

  • Saying reduction means gain of oxygen — that is the opposite.
  • Writing a long explanation but not giving the key term loss of oxygen.

Part (c) / 01.3 — Why must the positive carbon electrodes be replaced?

✅ Correct answer

  • At high temperature, oxygen reacts with the carbon electrode.
  • The positive electrode burns / wears away.
  • This produces carbon dioxide.

Equation: C + O₂ → CO₂

💡 Key knowledge

  • The positive carbon electrode is the anode.
  • Oxygen is formed at the anode during electrolysis.
  • Because carbon is reactive at high temperature, it is slowly used up.

🧠 Exam technique

  • This is a 3-mark explanation, so give linked points.
  • Full-mark answers usually include:
    • oxygen formed at the positive electrode,
    • oxygen reacts with carbon,
    • carbon dioxide is made so the electrode wears away.

❌ Common errors

  • Saying the electrode is replaced because it is “used up” without saying how.
  • Forgetting that oxygen is formed at the positive electrode.
  • Writing CO instead of CO₂.

📐 Step-by-step reaction logic

  1. Oxygen ions are discharged at the positive electrode.
  2. Oxygen gas is formed there.
  3. Hot oxygen reacts with the carbon electrode.
  4. Carbon is oxidised to carbon dioxide: C + O₂ → CO₂
  5. The electrode therefore gets smaller and must be replaced.

Part (d) / 01.4 — Free-moving charged particles in different conductors

These are recall questions about how current is carried in different substances.

✅ Correct answers

  • Carbon electrode (graphite): delocalised electrons
  • Molten mixture of aluminium oxide and cryolite: ions
  • Metal wire: delocalised electrons

💡 Key knowledge

  • Graphite and metals conduct because they contain delocalised electrons that can move through the structure.
  • Molten ionic compounds conduct because the ions are free to move when melted.
  • Solid ionic compounds do not conduct because their ions are fixed in place.

🧠 Exam technique

  • Use the exact particle name the mark scheme expects.
  • For graphite and metals, the safest answer is delocalised electrons.
  • For a molten ionic substance, write ions.

❌ Common errors

  • Saying “charged particles” instead of naming them.
  • Writing atoms for metal wire or graphite.
  • Writing electrons for the molten ionic mixture.

Mark scheme summary — what got the marks

✅ Full-mark answers in one glance

  • 01.1 13; 14
  • 01.2 Loss of oxygen
  • 01.3 Oxygen reacts with carbon at high temperature, so the positive electrode burns/wears away and carbon dioxide is formed
  • 01.4 Graphite: delocalised electrons; molten mixture: ions; metal wire: delocalised electrons

🧠 What distinguished top responses

  • They used the exact scientific terms: loss of oxygen, anode, delocalised electrons, ions.
  • For the electrode question, they explained the whole process, not just one phrase.
  • They answered in the correct order and with no extra confusion.

Topics

Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter · C4: Chemical Changes

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2020. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.