AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2020: Question 1
9 marks · Standard Demand difficulty · Short Answer
Answer short questions about aluminium extraction, including atomic structure, reduction, electrolysis of aluminium oxide, electrode wear, and charge carriers in graphite, molten ionic compounds and metals.
Practise this questionQuestion
Question text
01 This question is about the extraction of aluminium.
01.1 An aluminium atom is represented as:
13Al
Give the number of electrons and neutrons in the aluminium atom.
[2 marks]
Number of electrons
Number of neutrons
Aluminium is extracted by the electrolysis of a molten mixture of aluminium oxide
and cryolite.
Figure 1 shows the cell used for the electrolysis.
Figure 1
01.2 Aluminium is produced by the reduction of aluminium oxide (Al2O3).
What is meant by the term reduction?
[1 mark]
01.3 Oxygen is formed at the positive carbon electrodes.
Explain why the positive carbon electrodes must be continually replaced.
*02* [3 marks]
01.4 A substance conducts electricity because of free moving, charged particles.
What are the free moving, charged particles in a:
• carbon electrode (made from graphite)
• molten mixture of aluminium oxide and cryolite
• metal wire?
[3 marks]
Carbon electrode (made from graphite)
Molten mixture of aluminium oxide and cryolite
Metal wire
Mark scheme
Show the mark scheme
AO /
Question Answers Extra information Mark
Spec. Ref.
01.1 13 this order only 1 AO2
5.1.1.4
14 1 5.1.1.5
01.2 loss of oxygen allow (Al3+) gain of electrons 1 AO1
5.4.1.1
allow aluminium oxide loses 5.4.1.3
oxygen
01.3 allow anode for (positive)
electrode
(at high temperature) 1 AO1
oxygen reacts with carbon / 5.4.3.1
electrode 5.4.3.2
5.4.3.3
(so the positive) electrode 1
burns / wears away
to produce carbon dioxide 1
C + O2 → CO2 scores MP1 and
MP3
01.4 (delocalised) electron(s) 1 AO1
ion(s) 1 AO2
(delocalised) electron(s) 1 AO1
5.2.2.3
5.2.2.8
5.2.3.2
Total 9
How to answer it
Extraction of Aluminium
Knowing the structure of an aluminium atom, understanding reduction as loss of oxygen, explaining why carbon electrodes wear away in electrolysis, and identifying the charged particles that carry current in different materials.
Question overview
This is a straightforward GCSE electrolysis question. The marks are mainly for recall: atomic structure, reduction, electrode reactions, and electrical conduction in solids and molten compounds.
Exam tip: many marks are one-word answers, so precision matters.
Part (a) / 01.1 — Number of electrons and neutrons in aluminium
Aluminium shown as ²⁷₁₃Al
✅ Correct answers
- Number of electrons = 13
- Number of neutrons = 14
Marks are awarded in this order only: electrons first, then neutrons.
💡 Key knowledge
- In a neutral atom, electrons = protons.
- The atomic number of aluminium is 13, so it has 13 protons and 13 electrons.
- Number of neutrons = mass number − atomic number = 27 − 13 = 14.
🧠 Exam technique
- Read the numbers from the nuclide symbol carefully.
- Use the top number for mass number and the bottom number for atomic number.
- Always check the answer order if the question asks for two values.
❌ Common errors
- Mixing up atomic number and mass number.
- Writing 27 electrons or 27 neutrons.
- Forgetting that atoms are neutral, so electrons match protons.
Part (b) / 01.2 — What is reduction?
✅ Correct answer
Loss of oxygen.
💡 Key knowledge
- Reduction can be remembered as removal of oxygen.
- For aluminium oxide, reduction means aluminium oxide loses oxygen.
- The mark scheme also allows: Al³⁺ gains electrons.
🧠 Exam technique
A one-mark definition question needs a short, exact answer. If you know both definitions, use the simplest one: loss of oxygen.
❌ Common errors
- Saying reduction means gain of oxygen — that is the opposite.
- Writing a long explanation but not giving the key term loss of oxygen.
Part (c) / 01.3 — Why must the positive carbon electrodes be replaced?
✅ Correct answer
- At high temperature, oxygen reacts with the carbon electrode.
- The positive electrode burns / wears away.
- This produces carbon dioxide.
Equation: C + O₂ → CO₂
💡 Key knowledge
- The positive carbon electrode is the anode.
- Oxygen is formed at the anode during electrolysis.
- Because carbon is reactive at high temperature, it is slowly used up.
🧠 Exam technique
- This is a 3-mark explanation, so give linked points.
- Full-mark answers usually include:
- oxygen formed at the positive electrode,
- oxygen reacts with carbon,
- carbon dioxide is made so the electrode wears away.
❌ Common errors
- Saying the electrode is replaced because it is “used up” without saying how.
- Forgetting that oxygen is formed at the positive electrode.
- Writing CO instead of CO₂.
📐 Step-by-step reaction logic
- Oxygen ions are discharged at the positive electrode.
- Oxygen gas is formed there.
- Hot oxygen reacts with the carbon electrode.
- Carbon is oxidised to carbon dioxide: C + O₂ → CO₂
- The electrode therefore gets smaller and must be replaced.
Part (d) / 01.4 — Free-moving charged particles in different conductors
These are recall questions about how current is carried in different substances.
✅ Correct answers
- Carbon electrode (graphite): delocalised electrons
- Molten mixture of aluminium oxide and cryolite: ions
- Metal wire: delocalised electrons
💡 Key knowledge
- Graphite and metals conduct because they contain delocalised electrons that can move through the structure.
- Molten ionic compounds conduct because the ions are free to move when melted.
- Solid ionic compounds do not conduct because their ions are fixed in place.
🧠 Exam technique
- Use the exact particle name the mark scheme expects.
- For graphite and metals, the safest answer is delocalised electrons.
- For a molten ionic substance, write ions.
❌ Common errors
- Saying “charged particles” instead of naming them.
- Writing atoms for metal wire or graphite.
- Writing electrons for the molten ionic mixture.
Mark scheme summary — what got the marks
✅ Full-mark answers in one glance
- 01.1 13; 14
- 01.2 Loss of oxygen
- 01.3 Oxygen reacts with carbon at high temperature, so the positive electrode burns/wears away and carbon dioxide is formed
- 01.4 Graphite: delocalised electrons; molten mixture: ions; metal wire: delocalised electrons
🧠 What distinguished top responses
- They used the exact scientific terms: loss of oxygen, anode, delocalised electrons, ions.
- For the electrode question, they explained the whole process, not just one phrase.
- They answered in the correct order and with no extra confusion.
Topics
Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter · C4: Chemical Changes
Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2020. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.