AQA GCSE Combined Science: Trilogy Chemistry Paper 2 (Higher), 2020: Question 4

11 marks · Standard Demand difficulty · Short Answer

Investigate dissolved solids in water samples using evaporation, identify variables and errors, interpret repeat results, and calculate mass in 1 m³ in standard form.

Practise this question

Question

The question page shows an investigation into the mass of dissolved solids in four water samples A, B, C and D. A labelled diagram shows an evaporating basin containing a water sample resting on a beaker of boiling water above a Bunsen burner on a tripod; labels include evaporating basin, beaker, water sample, droplets of water, boiling water and Bunsen burner. The method lists weighing a dry evaporating basin, adding 25 cm³ of water, heating for 10 minutes, reweighing the basin and contents, repeating with sample A three more times and then with samples B, C and D; follow-up questions ask for the variable type of mass of dissolved solids, an error and improvement in step 4, calculation of a missing value X from a results table, identification of the sample with the greatest range, and a calculation of dissolved solids in 1 m³ when 25 cm³ contains 0.016 g, with 1 m³ = 1000 dm³ given. The table gives masses of dissolved solids in g for four tests and a mean: A has 0.22, 0.23, 0.20, X, mean 0.21; B has 0.03, 0.08, 0.02, 0.03, mean 0.04; C has 0.45, 0.60, 0.49, 0.58, mean 0.53; D has 0.80, 0.91, 0.79, 0.86, mean 0.84.
Question text

04 A student investigated the mass of dissolved solids in four water samples

A, B, C and D.

Figure 4 shows the apparatus used.

Figure 4

This is the method used.

1. Record the mass of a dry evaporating basin.

2. Pour 25 cm3 of water sample A into the evaporating basin.

3. Place the evaporating basin on the beaker for 10 minutes.

4. Record the mass of the evaporating basin and contents.

5. Repeat steps 1 to 4 with water sample A three more times.

6. Repeat steps 1 to 5 with water samples B, C and D.

04.1 What type of variable is the mass of dissolved solids?

[1 mark]

Tick ( ) one box.

Categoric

Control

Dependent

Independent

04.2 The method produced an error in the mass recorded in step 4.

Suggest what caused the error.

How could the error be avoided?

[2 marks]

Error

Avoided by

Another student carried out the investigation correctly.

Table 1 shows the results.

Table 1

Water

Mass of dissolved solids in g

sample

Test 1 Test 2 Test 3 Test 4 Mean

A 0.22 0.23 0.20 X 0.21

B 0.03 0.08 0.02 0.03 0.04

C 0.45 0.60 0.49 0.58 0.53

D 0.80 0.91 0.79 0.86 0.84

*0134.*3 Calculate value X in Table 1.

[2 marks]

X = g

04.4 Which water sample has the greatest range of masses of dissolved solids?

Give the reason for your answer.

[2 marks]

Water sample

Reason

04.5 Water companies measure the volume of water used by households in

cubic metres (m3).

25 cm3 of a different water sample contained 0.016 g of dissolved solids.

*14* 3

Calculate the mass of dissolved solid in 1 m of this water sample.

1 m3 = 1000 dm3

Give your answer in standard form.

[4 marks]

Mass (in standard form) = g

Mark scheme

Show the mark scheme The mark scheme is a table with columns for question number, answers, extra information, mark and AO/specification reference. It gives 04.1 as 'dependent'; 04.2 as not all water had been removed from the sample and avoid by heating to constant mass, with alternatives that water droplets on the bottom of the evaporating basin added mass and should be dried or wiped off; 04.3 uses the mean equation (0.22 + 0.23 + 0.20 + X) divided by 4 equals 0.21 to obtain X = 0.19 g. For 04.4 the correct sample is C because it has the biggest difference between maximum and minimum values, with ranges allowed as A 0.04, B 0.06, C 0.15 and D 0.12; 04.5 converts 1 m³ to 1 × 10^6 cm³, calculates mass as 1 × 10^6 × 0.016 divided by 25 = 640 g, and gives the final answer in standard form as 6.4 × 10^2 g. The total mark shown is 11.

AO /

Question Answers Extra information Mark

Spec. Ref.

04.1 dependent 1 AO1

5.10.1.2

04.2 not all water had been removed allow description of process 1 AO3

from the sample 5.10.1.2

heat to constant mass 1

alternative approach:

mass included (droplets of) allow bottom of evaporating

water on the bottom of the basin was wet

evaporating basin (1) ignore spillages

ignore weighing errors

dry the bottom of the allow wipe off droplets

evaporating basin (1)

04.3 0.22 + 0.23 + 0.20 + X 1 AO2

= 0.21 5.10.1.2

(X = ) 0.19 (g) 1

04.4 allow ecf from question 04.3 AO2

5.10.1.2

C 1

biggest difference between the allow calculated range if all 1

maximum and minimum values ranges are shown A 0.04; B

0.06; C 0.15 and D 0.12

04.5 (conversion m3 to cm3) AO2

1 m3 = 1 x 106 cm3 1 5.3.2.5

5.10.1.2

6 0.016

(mass =) 1 x 10 × allow correct use of an incorrect 1

25 / no conversion value

= 640 (g) 1

= 6.4 × 102 (g) allow a correctly calculated 1

answer in standard form from an

incorrect calculation of mass

Total 11

How to answer it

Water Samples: Dissolved Solids

What this question tests
This question checks your ability to identify variables, explain an experimental error, use table data, find a mean-related missing value, compare ranges, and do a mass conversion calculation. It also tests whether you can give answers in the exact form examiners want for each mark.

Question overview

Key idea

  • The student heats water samples to remove the water and leave dissolved solids behind.
  • Masses are compared to find how much dissolved solid is in each sample.
  • You need to interpret a method, a results table, and a conversion from 25 cm³ to 1 m³.

How to score well

  • Use the correct scientific term for the variable.
  • Link errors to what actually happened in the method.
  • Show calculation steps clearly, including units and final answer form.

Part (04.1)

What type of variable is the mass of dissolved solids?

✅ Correct answer

Dependent

This is the variable measured at the end of the investigation, so it is the dependent variable.

💡 Key knowledge

  • Independent variable = what you change.
  • Dependent variable = what you measure.
  • Control variables = what you keep the same.

🧠 Exam technique

For 1 mark, the examiner wants the exact term. If you say “mass” or “result”, that is not specific enough.

❌ Common errors

  • Choosing independent because the water sample is changed.
  • Choosing control because the volume is kept the same.
  • Writing “categorical” — this is not the correct type here.

Part (04.2)

Why was there an error in the mass recorded in step 4? How could it be avoided?

✅ Correct answer

Error: not all the water had been removed from the sample.

Avoided by: heat to constant mass.

Alternative acceptable points: the bottom of the evaporating basin was wet, or droplets of water were left and should be dried/wiped off before weighing.

💡 Key knowledge

  • If water is still present, the measured mass is too high.
  • “Constant mass” means heating, cooling, and reweighing until the mass no longer changes.
  • A dry evaporating basin is essential for accurate results.

🧠 Exam technique

  • Give one clear cause of the error.
  • Then give one practical method to prevent it.
  • Marks are usually split: one for the cause, one for the fix.

❌ Common errors

  • Saying “weighing error” without explaining what was wrong.
  • Writing “heat longer” without mentioning constant mass.
  • Ignoring the fact that water droplets on the basin can increase the mass.

Part (04.3)

Calculate the missing value X in Table 1.

📐 Calculation steps

  1. Use the mean formula: mean = total ÷ number of values
  2. For sample A: (0.22 + 0.23 + 0.20 + X) ÷ 4 = 0.21
  3. Multiply both sides by 4: 0.22 + 0.23 + 0.20 + X = 0.84
  4. Add the known values: 0.65 + X = 0.84
  5. Subtract: X = 0.84 - 0.65 = 0.19

X = 0.19 g

✅ Correct answer

0.19 g

2 marks: one for the correct method, one for the correct final value.

🧠 Exam technique

  • Always show the mean formula if space is available.
  • Keep the unit g.
  • Use the given mean of 0.21 exactly.

❌ Common errors

  • Adding the three values and forgetting the mean is for four tests.
  • Doing 0.21 - 0.22 - 0.23 - 0.20 incorrectly.
  • Leaving the answer without units.

Part (04.4)

Which water sample has the greatest range of masses of dissolved solids? Give a reason.

✅ Correct answer

Water sample: C

Reason: it has the biggest difference between the maximum and minimum values.

Accepted equivalent idea: it has the greatest range.

📐 Working out the range

  • A: 0.23 - 0.19 = 0.04
  • B: 0.08 - 0.02 = 0.06
  • C: 0.60 - 0.45 = 0.15
  • D: 0.91 - 0.79 = 0.12

Largest range = C

🧠 Exam technique

  • You need the sample letter and the reason for both marks.
  • Using “highest mean” is not enough — the question asks for range.
  • If you made a mistake in part (04.3), you can still gain follow-through credit if your comparison is consistent.

❌ Common errors

  • Choosing D because it has the largest numbers, rather than the largest spread.
  • Writing “largest mass” instead of “largest range”.
  • Comparing only the means.

Part (04.5)

Calculate the mass of dissolved solid in 1 m³ of this water sample. Give your answer in standard form.

📐 Step-by-step calculation

  1. Start with the given data: 25 cm³ contains 0.016 g
  2. Convert volume to match the larger amount:
    1 m³ = 1000 dm³
    1 dm³ = 1000 cm³
    1 m³ = 1 × 10⁶ cm³
  3. Find how many 25 cm³ portions are in 1 × 10⁶ cm³:
    1 × 10⁶ ÷ 25 = 4 × 10⁴
  4. Multiply the mass in one portion:
    0.016 × 4 × 10⁴ = 640 g
  5. Write in standard form:
    6.4 × 10² g

✅ Correct answer

6.4 × 10² g

Equivalent form: 640 g

4 marks are available: conversion, method, correct mass, and standard form.

💡 Key knowledge

  • 1 m³ = 1 × 10⁶ cm³ is the key conversion.
  • Mass scales directly with volume if the concentration is the same.
  • Standard form should be written as a × 10ⁿ where 1 ≤ a < 10 .

❌ Common errors and traps

  • Using 1 m³ = 1000 cm³ — this is wrong.
  • Forgetting to convert the volume before scaling up.
  • Missing the unit g.
  • Writing the standard form incorrectly, such as 64 × 10¹ instead of 6.4 × 10² .

Examiner insight: what separated better answers?

Top-level responses...

  • Used precise terms like dependent variable and constant mass.
  • Explained the error clearly, rather than just naming a vague mistake.
  • Showed full calculation method, not just the final answer.
  • Compared data using the correct idea of range.

How marks were awarded

  • Short answer questions usually reward one clear scientific statement.
  • Calculation questions reward method as well as the answer.
  • For comparison questions, give both the result and the reason.

Quick revision summary

  • 04.1: The mass of dissolved solids is the dependent variable.
  • 04.2: The error was that not all the water had been removed; avoid by heating to constant mass.
  • 04.3: X = 0.19 g.
  • 04.4: C, because it has the greatest range.
  • 04.5: 6.4 × 10² g.

Topics

Chemistry · C10: Using Resources · C3: Quantitative Chemistry

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 2 (Higher), 2020. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.