AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2021: Question 4
10 marks · Standard Demand difficulty · Short Answer
Answer questions on carbon structures and alloys, including Buckminsterfullerene, why graphite conducts electricity, why steel is harder than iron, and calculating the mass of iron in stainless steel from percentage composition.
Practise this questionQuestion
Question text
04 Carbon can exist in a number of different structures.
04.1 The first fullerene to be discovered was Buckminsterfullerene.
What is the formula of Buckminsterfullerene?
[1 mark]
Tick ( ) one box.
C40
C50
C60
C70
04.2 Graphite is a form of carbon.
Explain why graphite conducts electricity.
[2 marks]
Steel is an alloy of iron and carbon.
04.3 Explain why steel is harder than iron.
[3 marks]
04.4 Iron is alloyed with carbon and other metals to make stainless steel.
A stainless steel fork contains 71.92% iron.
Table 2 shows the mass of each element in the fork.
Table 2
Element Iron Carbon Chromium Nickel
Mass of element in g X 0.05 10.44 5.80
Calculate the mass of iron (X) in the fork.
[4 marks]
X = g
Mark scheme
Show the mark scheme
AO /
Question Answers Extra information Mark
Spec. Ref.
04.1 C60 1 AO1
5.2.3.3
04.2 (graphite has) delocalised 1 AO1
electrons 5.2.3.2
(so the delocalised electrons) allow (so the delocalised 1
carry electrical charge through electrons) move through the
the structure structure
04.3 carbon atoms have different 1 AO1
sizes to iron atoms / ions 5.2.2.7
(so carbon atoms) distort the 1
layers of iron atoms / ions
(therefore) the layers cannot 1
slide
04.4 (percentage and mass of other AO2
elements) 5.2.2.7
28.08 (%) = 16.29 (g) 1
16.29
(mass of fork) = × 100 (g) 1
28.08
= 58.01 (g) 1
71.92
(mass of iron = × 58.01)
= 41.72 (g) allow (mass of fork – mass of 1
other elements) = 41.72 (g)
allow 41.7 (g)
allow correct use of incorrect
calculation of mass and / or
percentages
Total 10
How to answer it
Carbon Structures, Graphite, Steel and Percent Mass
Part (a) / 04.1 — Formula of Buckminsterfullerene
✅ Correct answer
C₆₀
💡 Key knowledge
- Buckminsterfullerene is a fullerene made of 60 carbon atoms.
- It is often called buckyball.
🧠 Exam technique
- For a multiple-choice box question, do not overthink it: choose the exact formula from memory.
- Check the subscript carefully: C₆₀ , not C60 written without a subscript if you are writing by hand.
❌ Common errors
- Mixing up fullerene formulas with other carbon structures.
- Writing C₆ or C₈₀ instead of C₆₀ .
Part (b) / 04.2 — Why graphite conducts electricity
✅ Correct answer
- Graphite has delocalised electrons.
- These electrons move through the structure and carry electrical charge.
💡 Key knowledge
- In graphite, each carbon atom forms 3 bonds, leaving 1 electron per atom delocalised.
- These electrons are free to move along the layers.
🧠 Exam technique
- Use both idea and explanation: what the electrons are and what they do.
- A strong 2-mark answer often looks like: “Graphite has delocalised electrons, which can move through the structure and carry charge.”
❌ Common errors
- Saying “graphite has free electrons” without explaining they are delocalised.
- Saying the electrons “carry heat” instead of electrical charge.
- Confusing graphite with diamond, which has no delocalised electrons.
Part (c) / 04.3 — Why steel is harder than iron
✅ Correct answer
- Carbon atoms are a different size from iron atoms/ions.
- They distort the layers of iron atoms/ions.
- The layers cannot slide over each other easily, so steel is harder.
💡 Key knowledge
- Steel is an alloy of iron and carbon.
- Pure metals are softer because layers can slide more easily.
- Alloys are usually harder because different-sized atoms disrupt the regular metal lattice.
🧠 Exam technique
- Use the sequence: different size → distortion → layers cannot slide.
- This is a classic AQA mark scheme chain. If you include all three, you are very likely to gain full marks.
❌ Common errors
- Only saying “alloys are harder” without explaining why.
- Talking about stronger bonds in too vague a way.
- Forgetting the key phrase layers cannot slide.
Part (d) / 04.4 — Calculating the mass of iron in the fork
📐 Calculation: step-by-step
- Find the total mass of the fork using the carbon, chromium and nickel masses and the fact that iron is 71.92% of the fork.
- First, add the other masses:
0.05 + 10.44 + 5.80 = 16.29 g - These other elements make up:
100% - 71.92% = 28.08% - So, if 28.08% = 16.29 g , then:
100% = 16.29 ÷ 28.08 × 100 = 58.01 g - Now calculate the mass of iron:
71.92% of 58.01 = 71.92 ÷ 100 × 58.01 = 41.72 g
Answer: X = 41.72 g
Accept 41.7 g depending on rounding.
✅ Correct answer
X = 41.72 g
- Allow 41.7 g for rounded final answer.
- Allow a correct alternative method, such as: total mass − mass of other elements = iron mass.
🧠 Exam technique
- Always write the percentage relationship clearly.
- Show working in stages so you can gain method marks even if your final answer is wrong.
- Keep units on every line: g and %.
- Use sensible rounding at the end, not at every step.
❌ Common errors
- Adding all masses together and stopping there.
- Using 71.92 as a mass instead of a percentage.
- Forgetting to convert percentage into a fraction by dividing by 100.
- Mixing up which percentage belongs to iron and which belongs to the other elements.
- Losing marks by rounding too early.
Quick revision summary
💡 Remember these facts
- Buckminsterfullerene = C₆₀
- Graphite conducts because of delocalised electrons
- Steel is harder than iron because carbon atoms distort layers
🧠 How to score full marks
- Use the exact science keyword from the mark scheme.
- For explanations, make each sentence do one marking job.
- For calculations, write the percentage relationship, show the arithmetic, and include units.
Topics
Chemistry · C2: Bonding, Structure and the Properties of Matter
Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.