AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2021: Question 4

10 marks · Standard Demand difficulty · Short Answer

Answer questions on carbon structures and alloys, including Buckminsterfullerene, why graphite conducts electricity, why steel is harder than iron, and calculating the mass of iron in stainless steel from percentage composition.

Practise this question

Question

A chemistry exam question page headed question 04 about carbon structures and alloys. Part 04.1 is a 1-mark multiple-choice question asking for the formula of Buckminsterfullerene, with tick boxes next to C40, C50, C60 and C70. Part 04.2 is a 2-mark written question asking why graphite conducts electricity, and part 04.3 is a 3-mark written question asking why steel is harder than iron. Part 04.4 is a 4-mark calculation about a stainless steel fork that contains 71.92% iron, with a table listing masses of elements in grams: iron X, carbon 0.05, chromium 10.44 and nickel 5.80, and asks for the mass of iron X in the fork.
Question text

04 Carbon can exist in a number of different structures.

04.1 The first fullerene to be discovered was Buckminsterfullerene.

What is the formula of Buckminsterfullerene?

[1 mark]

Tick ( ) one box.

C40

C50

C60

C70

04.2 Graphite is a form of carbon.

Explain why graphite conducts electricity.

[2 marks]

Steel is an alloy of iron and carbon.

04.3 Explain why steel is harder than iron.

[3 marks]

04.4 Iron is alloyed with carbon and other metals to make stainless steel.

A stainless steel fork contains 71.92% iron.

Table 2 shows the mass of each element in the fork.

Table 2

Element Iron Carbon Chromium Nickel

Mass of element in g X 0.05 10.44 5.80

Calculate the mass of iron (X) in the fork.

[4 marks]

X = g

Mark scheme

Show the mark scheme The mark scheme is a table with columns for question number, answers, extra information, mark and AO/specification reference. For 04.1 the correct answer is C60. For 04.2 marks are for stating that graphite has delocalised electrons and that these electrons carry charge or move through the structure. For 04.3 marks are for carbon atoms being different in size from iron atoms or ions, distorting the layers, and preventing the layers from sliding. For 04.4 the scheme shows that the other elements total 16.29 g and 28.08%, the total fork mass is 16.29 divided by 28.08 times 100 equals 58.01 g, and the iron mass is 71.92 divided by 100 times 58.01, giving 41.72 g, with 41.7 g also accepted.

AO /

Question Answers Extra information Mark

Spec. Ref.

04.1 C60 1 AO1

5.2.3.3

04.2 (graphite has) delocalised 1 AO1

electrons 5.2.3.2

(so the delocalised electrons) allow (so the delocalised 1

carry electrical charge through electrons) move through the

the structure structure

04.3 carbon atoms have different 1 AO1

sizes to iron atoms / ions 5.2.2.7

(so carbon atoms) distort the 1

layers of iron atoms / ions

(therefore) the layers cannot 1

slide

04.4 (percentage and mass of other AO2

elements) 5.2.2.7

28.08 (%) = 16.29 (g) 1

16.29

(mass of fork) = × 100 (g) 1

28.08

= 58.01 (g) 1

71.92

(mass of iron = × 58.01)

= 41.72 (g) allow (mass of fork – mass of 1

other elements) = 41.72 (g)

allow 41.7 (g)

allow correct use of incorrect

calculation of mass and / or

percentages

Total 10

How to answer it

Carbon Structures, Graphite, Steel and Percent Mass

What this question tests
This question checks recall of key carbon structures, why graphite conducts electricity, why alloys are harder than pure metals, and how to use percentages to calculate mass from composition. You need to select the correct formula, explain using scientific keywords, and show a clear percentage calculation with units.

Part (a) / 04.1 — Formula of Buckminsterfullerene

✅ Correct answer

C₆₀

1 mark for ticking the correct box.

💡 Key knowledge

  • Buckminsterfullerene is a fullerene made of 60 carbon atoms.
  • It is often called buckyball.

🧠 Exam technique

  • For a multiple-choice box question, do not overthink it: choose the exact formula from memory.
  • Check the subscript carefully: C₆₀ , not C60 written without a subscript if you are writing by hand.

❌ Common errors

  • Mixing up fullerene formulas with other carbon structures.
  • Writing C₆ or C₈₀ instead of C₆₀ .

Part (b) / 04.2 — Why graphite conducts electricity

✅ Correct answer

  • Graphite has delocalised electrons.
  • These electrons move through the structure and carry electrical charge.
Awarded as 2 separate marking points: one for delocalised electrons, one for movement/carrying charge.

💡 Key knowledge

  • In graphite, each carbon atom forms 3 bonds, leaving 1 electron per atom delocalised.
  • These electrons are free to move along the layers.

🧠 Exam technique

  • Use both idea and explanation: what the electrons are and what they do.
  • A strong 2-mark answer often looks like: “Graphite has delocalised electrons, which can move through the structure and carry charge.”

❌ Common errors

  • Saying “graphite has free electrons” without explaining they are delocalised.
  • Saying the electrons “carry heat” instead of electrical charge.
  • Confusing graphite with diamond, which has no delocalised electrons.

Part (c) / 04.3 — Why steel is harder than iron

✅ Correct answer

  • Carbon atoms are a different size from iron atoms/ions.
  • They distort the layers of iron atoms/ions.
  • The layers cannot slide over each other easily, so steel is harder.
3 marks available: one for size difference, one for distortion, one for preventing layers from sliding.

💡 Key knowledge

  • Steel is an alloy of iron and carbon.
  • Pure metals are softer because layers can slide more easily.
  • Alloys are usually harder because different-sized atoms disrupt the regular metal lattice.

🧠 Exam technique

  • Use the sequence: different size → distortion → layers cannot slide.
  • This is a classic AQA mark scheme chain. If you include all three, you are very likely to gain full marks.

❌ Common errors

  • Only saying “alloys are harder” without explaining why.
  • Talking about stronger bonds in too vague a way.
  • Forgetting the key phrase layers cannot slide.

Part (d) / 04.4 — Calculating the mass of iron in the fork

📐 Calculation: step-by-step

  1. Find the total mass of the fork using the carbon, chromium and nickel masses and the fact that iron is 71.92% of the fork.
  2. First, add the other masses:
    0.05 + 10.44 + 5.80 = 16.29 g
  3. These other elements make up:
    100% - 71.92% = 28.08%
  4. So, if 28.08% = 16.29 g , then:
    100% = 16.29 ÷ 28.08 × 100 = 58.01 g
  5. Now calculate the mass of iron:
    71.92% of 58.01 = 71.92 ÷ 100 × 58.01 = 41.72 g

Answer: X = 41.72 g
Accept 41.7 g depending on rounding.

Marks are awarded for: identifying 28.08%, using a correct proportion, calculating total fork mass, then finding 71.92% of that mass.

✅ Correct answer

X = 41.72 g

  • Allow 41.7 g for rounded final answer.
  • Allow a correct alternative method, such as: total mass − mass of other elements = iron mass.

🧠 Exam technique

  • Always write the percentage relationship clearly.
  • Show working in stages so you can gain method marks even if your final answer is wrong.
  • Keep units on every line: g and %.
  • Use sensible rounding at the end, not at every step.

❌ Common errors

  • Adding all masses together and stopping there.
  • Using 71.92 as a mass instead of a percentage.
  • Forgetting to convert percentage into a fraction by dividing by 100.
  • Mixing up which percentage belongs to iron and which belongs to the other elements.
  • Losing marks by rounding too early.

Quick revision summary

💡 Remember these facts

  • Buckminsterfullerene = C₆₀
  • Graphite conducts because of delocalised electrons
  • Steel is harder than iron because carbon atoms distort layers

🧠 How to score full marks

  • Use the exact science keyword from the mark scheme.
  • For explanations, make each sentence do one marking job.
  • For calculations, write the percentage relationship, show the arithmetic, and include units.

Topics

Chemistry · C2: Bonding, Structure and the Properties of Matter

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.