AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2022: Question 4

10 marks · Standard Demand difficulty · Short Answer

Answer a series of questions about Group 7 elements, including their name, similar reactivity, a chlorine oxide formula, interpreting and completing a melting point bar chart, explaining the melting point trend, identifying bromine’s state at a given temperature, and naming a surface process at the boiling point.

Practise this question

Question

The question page is headed 'This question is about Group 7 elements' and contains seven short-answer parts labeled 04.1 to 04.7, worth a total of 10 marks. It asks what Group 7 elements are known as, why they react in similar ways, and shows a ball-and-stick diagram of a chlorine oxide molecule with chlorine and oxygen atoms labelled for students to give its molecular formula. A bar chart titled Figure 4 shows melting points in degrees Celsius for Group 7 elements fluorine, chlorine, bromine, iodine and astatine, with bars already drawn for chlorine, bromine, iodine and astatine and fluorine missing; students are told fluorine melts at −220 degrees Celsius and must complete the y-axis scale and add the fluorine bar, then use the figure to explain the trend in melting points and determine the state symbol for bromine at −50 degrees Celsius from tick-box options (aq), (g), (l), and (s). The final part asks for one more process, besides evaporation and boiling, that happens at the surface of bromine at its boiling point.
Question text

04 This question is about Group 7 elements.

04.1 What are the Group 7 elements known as?

[1 mark]

04.2 Why do Group 7 elements react in similar ways?

[1 mark]

04.3 Figure 3 shows the structure of a molecule of chlorine oxide.

Figure 3

What is the molecular formula of the chlorine oxide molecule in Figure 3?

[1 mark]

Figure 4 shows the melting points of some Group 7 elements.

Figure 4

04.4 The melting point of fluorine is –220 °C

Complete Figure 4.

You should:

• complete the scale on the y-axis

• draw the bar for the melting point of fluorine.

13 [2 marks]

04.5 Explain the trend in the melting points of the Group 7 elements.

Use Figure 4.

[3 marks]

04.6 What is the state symbol for bromine at –50 °C?

Use Figure 4.

[1 mark]

Tick ( ) one box.

(aq) (g) (l) (s)

04.7 Evaporation and boiling occur at the surface of bromine at its boiling point.

Name one more process that happens at the surface of bromine at its boiling point.

[1 mark]

Mark scheme

Show the mark scheme The mark scheme is presented as a series of tables for questions 04.1 to 04.7, each with columns for question number, answers, extra information, mark, and AO/specification reference. Accepted answers are: 04.1 halogens; 04.2 all have 7 electrons in the outer shell or 7 outer electrons; 04.3 Cl2O7; 04.4 correct y-axis scale from −100 to −250 degrees Celsius and a bar plotted at −220 degrees Celsius; 04.5 molecules increase in size down the group, intermolecular forces increase, so melting points increase down the group; 04.6 (s); 04.7 condensation. The final row shows Total Question 4 equals 10 marks.

Question 4

AO /

Question Answers Extra information Mark

Spec. Ref.

04.1 halogens 1 AO1

5.1.2.6

AO /

Spec. Ref.

04.2 allow energy level for shell

all have 7 electrons in outer 1 AO1

shell 5.1.2.6

or

all have 7 outer electrons allow same number of outer

electrons

allow one electron required to

complete the outer shell

AO /

Spec. Ref.

04.3 Cl2O7 1 AO2

5.2.1.4

AO /

Spec. Ref.

04.4 y-axis scale correct from –100 to 1 AO2

–250 °C 5.1.2.6

bar correctly plotted at –220 °C allow a tolerance of ±½ a small 1

square

AO /

Spec. Ref.

04.5 allow converse explanation in

terms of decreasing melting

12 point

(the) molecules increase in size allow atoms increase in size 1 AO3

going down the group going down the group

allow increase in number of

electron shells going down

group

(so the) forces between the 1 AO1

molecules increase

or

(so the) intermolecular forces

increase

(so the) melting points increase allow (so) more energy is 1 AO1

going down the group needed to separate the 5.1.2.6

or molecules 5.2.2.4

(so the) melting points increase

with increasing relative atomic

mass

AO /

Spec. Ref.

04.6 (s) 1 AO3

5.1.2.6

5.2.2.1

5.2.2.2

AO /

Spec. Ref.

04.7 condensation allow condensing 1 AO1

5.2.2.1

ignore evaporating and boiling

Total Question 4 10

How to answer it

AQA GCSE Combined Science: Trilogy Question 4: Group 7 elements

Group 7 Halogens: structure, trends and states

What this question tests

Recall of the name and simple properties of Group 7 elements, understanding that they have the same number of outer electrons, reading a graph carefully, drawing a missing bar to scale, explaining a trend in melting points, and using a graph to identify state symbols.

Overall question focus: 10 marks across quick recall and one explanation

This is a typical GCSE question set on the halogens. Most marks come from exact chemistry words, careful graph reading, and linking structure to properties.

Part (a) / 04.1

What are the Group 7 elements known as? [1 mark]

✅ Correct answer

halogens

Mark point: 1 mark for the correct name only.

💡 Key knowledge

  • Group 7 elements are called halogens.
  • Examples include fluorine, chlorine, bromine, iodine and astatine.

🧠 Exam technique

  • If a question asks “known as”, give the group name.
  • Do not list the elements unless asked.

❌ Common errors

  • Writing just one element, like chlorine.
  • Confusing Group 7 with Group 0 or Group 1.

Part (b) / 04.2

Why do Group 7 elements react in similar ways? [1 mark]

✅ Correct answer

They all have 7 electrons in their outer shell.

Accept: “same number of outer electrons” or “7 outer electrons”.

💡 Key knowledge

  • Elements in the same group have the same number of outer-shell electrons.
  • This is why they have similar chemical properties.
  • For Group 7, they all need one more electron to get a full outer shell.

🧠 Exam technique

  • Use the phrase outer shell or outer electrons.
  • For 1 mark, one clear sentence is enough.

❌ Common errors

  • Saying “they have the same number of shells” — this is not the reason.
  • Saying “they are all non-metals” — true, but not the marking point here.

Part (c) / 04.3

What is the molecular formula of the chlorine oxide molecule in Figure 3? [1 mark]

✅ Correct answer

Cl₂O₇

Mark point: Count the atoms shown in the model carefully.

💡 Key knowledge

  • Molecular formula shows the number of each atom in one molecule.
  • In the diagram, there are 2 chlorine atoms and 7 oxygen atoms.

🧠 Exam technique

  • Count each type of atom separately.
  • Use subscripts correctly: Cl₂O₇ .

❌ Common errors

  • Writing ClO₇ or Cl₂O₃ by miscounting.
  • Using the picture labels without counting the full model.

Part (d) / 04.4

The melting point of fluorine is −220 °C. Complete Figure 4. [2 marks]

✅ Correct answer

  • Extend/complete the y-axis scale correctly from −100 to −250 °C.
  • Draw the fluorine bar to −220 °C.
Mark point 1: correct scale on the y-axis.
Mark point 2: bar plotted at the correct value.

💡 Key knowledge

  • Graph scales must be sensible and evenly spaced.
  • Negative temperatures must be read carefully below 0.
  • Fluorine has the lowest melting point in the set shown.

🧠 Exam technique

  • First check the scale already shown.
  • Use the grid to place −220 °C accurately.
  • The mark scheme allows a small tolerance: about ±½ a small square.

❌ Common errors

  • Forgetting to include negative values on the scale.
  • Putting the bar at +220 °C instead of −220 °C.
  • Drawing the bar at the wrong height because the scale is uneven.

📐 Calculations / graph completion steps

  1. Look at the existing y-axis intervals.
  2. Extend the scale to include −220 °C.
  3. Make sure the lowest labelled value reaches at least −250 °C and the top of this section is −100 °C.
  4. Draw the fluorine bar down to −220 °C.

Part (e) / 04.5

Explain the trend in the melting points of the Group 7 elements. Use Figure 4. [3 marks]

✅ Correct answer

The molecules increase in size going down the group, so the forces between the molecules increase, so the melting points increase going down the group.

How marks are awarded: 1 mark for bigger molecules, 1 mark for stronger intermolecular forces, 1 mark for higher melting point.

💡 Key knowledge

  • Going down Group 7, atoms/molecules get larger.
  • There are more electrons and more shells.
  • This makes intermolecular forces stronger.
  • More energy is needed to separate the molecules, so melting point increases.

🧠 Exam technique

  • Use the chain: bigger particles → stronger forces → higher melting point.
  • For 3 marks, you need all three linked ideas, not just one.
  • Refer to the pattern in Figure 4: fluorine lowest, astatine highest.

❌ Common errors

  • Saying “bonds get stronger” — the question is about intermolecular forces, not covalent bonds.
  • Only stating “melting point increases” with no explanation.
  • Mixing up atoms and molecules: the mark scheme accepts “molecules increase in size” or “atoms increase in size”.

📐 Step-by-step answer structure

  1. State the trend: melting points increase down Group 7.
  2. Explain the cause: particles get bigger / more shells / more electrons.
  3. Finish with the consequence: stronger intermolecular forces, so more energy is needed to melt them.

Part (f) / 04.6

What is the state symbol for bromine at −50 °C? [1 mark]

✅ Correct answer

(s)

Bromine’s melting point is above −50 °C, so at −50 °C it is solid.

💡 Key knowledge

  • (s) = solid
  • (l) = liquid
  • (g) = gas
  • (aq) = aqueous

🧠 Exam technique

  • Read the melting point from the graph before deciding the state.
  • If the temperature is below the melting point, the substance is solid.

❌ Common errors

  • Choosing (l) because bromine is often known as a liquid at room temperature.
  • Confusing the state at room temperature with the state at −50 °C.

Part (g) / 04.7

Evaporation and boiling occur at the surface of bromine at its boiling point. Name one more process that happens at the surface of bromine at its boiling point. [1 mark]

✅ Correct answer

condensation

Accept: condensing

The mark scheme allows only the named process that happens at the surface.

💡 Key knowledge

  • At the boiling point, liquid particles are changing between liquid and gas at the surface.
  • Condensation is the reverse of evaporation/boiling.

🧠 Exam technique

  • Give the exact process name: condensation.
  • One mark = one correct science word.

❌ Common errors

  • Writing “evaporating” or “boiling” again.
  • Giving a description instead of the process name.

Quick revision summary

💡 Must-know facts

  • Group 7 elements are called halogens.
  • They all have 7 outer electrons.
  • Melting points increase down the group.
  • Bromine at −50 °C is solid.
  • At the surface of a liquid, condensation can also happen.

🧠 How to score full marks

  • Use the exact group name: halogens.
  • For explanations, link size → forces → melting point.
  • On graphs, check negative values and scale carefully.
  • For state symbols, compare the temperature with the melting point.

❌ Biggest traps in this question

  • Confusing intermolecular forces with covalent bonds.
  • Reading the wrong sign on a temperature.
  • Forgetting that Group 7 elements have the same number of outer electrons.

Topics

Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2022. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.