AQA GCSE Combined Science: Trilogy Chemistry Paper 2 (Higher), 2023: Question 1
12 marks · Standard Demand difficulty · Short Answer
Explain the combustion and environmental effects of burning fuels such as methane, petrol and diesel.
Practise this questionQuestion
Question text
01 The combustion of fuels is a source of atmospheric pollutants.
01.1 Methane is a fuel.
Balance the equation for the combustion of methane.
[1 mark]
CH4 + O2 → CO2 + H2O
01.2 Many fuels are mixtures.
Petrol and diesel are mixtures of hydrocarbons.
Table 1 shows properties of petrol and of diesel.
Table 1
Petrol Diesel
Range of number of carbon atoms in
4 to 12 12 to 20
a hydrocarbon molecule
Range of boiling points in °C 40 to 205 250 to 350
Compare the properties of petrol and diesel.
Use Table 1.
[2 marks]
01.3 The gases released when a fuel is burned in car engines may include:
• oxides of nitrogen
• carbon monoxide
• water vapour.
Which chemical element do all these gases contain?
[1 mark]
Tick ( ) one box.
Carbon
Hydrogen
Nitrogen
Oxygen
01.4 When diesel burns in car engines, oxides of nitrogen are produced.
Where does the nitrogen come from?
[1 mark]
01.5 When diesel burns, particulates may be produced.
What environmental effect do particulates from burning diesel cause?
[1 mark]
01.6 Carbon monoxide may be produced when diesel burns.
Give one reason why carbon monoxide is difficult to detect.
[1 mark]
01.7 Explain why water vapour and not liquid water is produced when diesel burns.
[2 marks]
01.8 Sulfur is a common impurity in diesel.
Explain why this causes an environmental problem.
[3 marks]
Mark scheme
Show the mark scheme
Question 1
AO /
Question Answers Extra information Mark
Spec. Ref.
01.1 CH4 + 2 O2 → CO2 + 2 H2O 1 AO2
5.7.1.3
AO /
Spec. Ref.
01.2 allow converse throughout AO3
5.7.1.3
hydrocarbon molecules in petrol 1
have fewer carbon atoms than
those in diesel
petrol has a lower boiling point 1
(range) than diesel
allow petrol is more flammable
than diesel
allow petrol is less viscous than
diesel
AO /
Spec. Ref.
01.3 oxygen 1 AO1
5.8.1.2
AO /
Spec. Ref.
01.4 air allow the atmosphere 1 AO1
5.9.1.1
allow from volcanoes 5.9.3.1
AO /
Spec. Ref.
01.5 global dimming 1 AO2
– OMBINED SCIENCE: TRILOGY – – 5.9.3.1
AO /
Spec. Ref.
01.6 (carbon monoxide is) colourless ignore clear 1 AO1
or 5.9.3.2
(carbon monoxide is) odourless
AO /
Spec. Ref.
01.7 (diesel) burns at a high 1 AO2
temperature
or
(diesel) burns at a temperature
greater than 100 °C
AO3
(which is) above the boiling 1
point of water 5.2.2.1
5.9.3.1
AO /
Spec. Ref.
01.8 sulfur dioxide (is produced when 1 AO1
diesel is burnt) 5.9.3.1
5.9.3.2
(which causes) acid rain 1
(which results in)
any one from: 1
• damage to buildings /
statues / bridges
• damage to trees / plants
• damage to aquatic life
• acidification of lakes /
rivers / soil
• respiratory problems allow (which affects) asthma
Total Question 1 12
How to answer it
Combustion of Fuels and Atmospheric Pollutants
This question checks your knowledge of combustion, balancing equations, comparing fuel properties from a table, identifying elements in compounds, and explaining how burning fuels causes pollution problems such as nitrogen oxides, particulates, carbon monoxide and sulfur dioxide. It also tests whether you can turn simple scientific facts into exam-style explanations worth 1–3 marks.
| Part | Topic | Marks |
|---|---|---|
| 01.1 | Balance methane combustion equation | 1 |
| 01.2 | Compare petrol and diesel using table data | 2 |
| 01.3 | Identify common element in gases | 1 |
| 01.4 | Source of nitrogen in nitrogen oxides | 1 |
| 01.5 | Environmental effect of particulates | 1 |
| 01.6 | Why carbon monoxide is hard to detect | 1 |
| 01.7 | Why water vapour forms, not liquid water | 2 |
| 01.8 | Why sulfur impurity causes environmental problems | 3 |
Total: 12 marks
Part 01.1 – Balancing methane combustion
1 mark
✅ Correct answer
CH₄ + 2O₂ → CO₂ + 2H₂O
💡 Key knowledge
- Combustion of a hydrocarbon produces carbon dioxide and water.
- You balance equations by changing big numbers in front of formulas, not the small numbers inside formulas.
- CH₄ has 4 H atoms, so you need 2H₂O to make 4 H atoms on the right.
🧠 Exam technique
- Count atoms on each side carefully: C, then H, then O.
- Leave CH₄, CO₂ and H₂O formulas unchanged.
- For a 1-mark balancing question, one wrong number means no mark.
❌ Common errors
- Writing CH₄ + O₂ → CO₂ + 2H₂O and forgetting oxygen is not balanced.
- Changing a formula, for example writing O₄ or H₄O₂.
- Not checking the total oxygen atoms at the end.
Part 01.2 – Comparing petrol and diesel
2 marks
✅ Correct answers
Any two valid comparisons from the table:
- Hydrocarbon molecules in petrol have fewer carbon atoms than those in diesel.
- Petrol has a lower boiling point range than diesel.
1 mark for comparing boiling point range.
The mark scheme allows the converse throughout, e.g. diesel has more carbon atoms / higher boiling points.
💡 Key knowledge
- Petrol range: 4 to 12 carbon atoms, 40 to 205 °C.
- Diesel range: 12 to 20 carbon atoms, 250 to 350 °C.
- Longer hydrocarbon molecules usually have higher boiling points.
- The mark scheme also allows: petrol is more flammable and petrol is less viscous than diesel.
🧠 Exam technique
- Use the wording compare: mention both fuels.
- Lift data from the table and turn it into a sentence.
- For 2 marks, make two separate comparison points.
- Best answers use phrases like lower than , higher than , fewer than , more than .
❌ Common errors
- Only describing one fuel without comparing it to the other.
- Giving unrelated facts not from the table.
- Saying petrol has “more carbon atoms” than diesel.
- Missing the idea of range and writing just one number.
Part 01.3 – Common element in the gases
1 mark
✅ Correct answer
Oxygen
💡 Key knowledge
- Oxides of nitrogen contain oxygen.
- Carbon monoxide contains oxygen.
- Water vapour is H₂O, so it contains oxygen too.
❌ Common errors
- Choosing hydrogen because of water vapour — but carbon monoxide and nitrogen oxides do not contain hydrogen.
- Choosing nitrogen because of nitrogen oxides — but carbon monoxide and water do not both contain nitrogen.
Part 01.4 – Where nitrogen oxides get their nitrogen from
1 mark
✅ Correct answer
From the air.
💡 Key knowledge
At the high temperatures inside an engine, nitrogen and oxygen from the air can react to form nitrogen oxides.
🧠 Exam technique
This is a short recall question. Give the exact source, not a long story.
❌ Common errors
- Saying the nitrogen comes from diesel itself.
- Answering just “from burning” without naming air or atmosphere.
Part 01.5 – Environmental effect of particulates
1 mark
✅ Correct answer
Global dimming
💡 Key knowledge
Particulates in the atmosphere can block or reflect sunlight, so less sunlight reaches the Earth's surface. This is called global dimming.
❌ Common errors
- Giving a health effect such as breathing problems when the question asks for an environmental effect.
- Writing global warming instead of global dimming.
Part 01.6 – Why carbon monoxide is difficult to detect
1 mark
✅ Correct answer
Carbon monoxide is colourless or odourless .
💡 Key knowledge
Carbon monoxide is dangerous because people may not notice it is present.
🧠 Exam technique
Only one reason is needed. Keep it precise and use scientific vocabulary.
❌ Common errors
- Writing “clear” — the mark scheme does not credit this.
- Talking about toxicity only. The question is about why it is hard to detect.
Part 01.7 – Why water vapour, not liquid water, is produced
2 marks
✅ Correct answer
A full 2-mark answer needs both ideas:
- Diesel burns at a high temperature / at a temperature greater than 100 °C.
- This temperature is above the boiling point of water, so the water produced is a gas (water vapour), not a liquid.
💡 Key knowledge
- Boiling point of water = 100 °C.
- If water is formed at temperatures above this, it will be water vapour.
- This question is about state change, not about how much oxygen is present.
🧠 Exam technique
For a 2-mark explain question, do not stop at “it is hot”. Add the scientific link: above boiling point.
Top answers clearly chain the idea: high temperature → above 100 °C → water is vapour .
❌ Common errors
- Saying “because water is made as a gas” with no reason.
- Talking about evaporation after the reaction instead of the combustion temperature.
- Forgetting to mention 100 °C or boiling point.
Part 01.8 – Why sulfur in diesel causes an environmental problem
3 marks
✅ Correct answer
A full-mark answer should include this chain:
- When diesel burns, sulfur produces sulfur dioxide.
- Sulfur dioxide causes acid rain.
- Acid rain causes damage, for example:
- damage to buildings, statues or bridges
- damage to trees or plants
- damage to aquatic life
- acidification of lakes, rivers or soil
- respiratory problems
1 mark for acid rain.
1 mark for one valid consequence of acid rain.
💡 Key knowledge
Sulfur is an impurity, so it is not part of the useful fuel. When it burns, it forms a pollutant. The key pollutant named by the mark scheme is sulfur dioxide.
🧠 Exam technique
This is a classic 3-mark “explain why” question. Build a clear cause-and-effect sequence:
sulfur in diesel → sulfur dioxide → acid rain → environmental damage
Students often lose the third mark by not giving the final effect.
❌ Common errors
- Saying sulfur causes global warming — not the mark scheme answer here.
- Mentioning sulfur dioxide but not acid rain.
- Mentioning acid rain but not a consequence.
- Giving vague effects like “it is bad for the environment” without an example.
Examiner insights across the whole question
💡 What strong answers did well
- Used exact scientific terms from the specification: oxygen, air, global dimming, sulfur dioxide, acid rain.
- For comparison questions, made direct comparisons rather than separate descriptions.
- For explanation questions, linked ideas in the correct order to secure all available marks.
🧠 Best strategy for similar questions
- On 1-mark questions, give the precise keyword and move on.
- On 2- or 3-mark questions, write one point per mark.
- If a table is given, use it directly.
- If the question says explain, include a reason or consequence, not just a fact.
❌ Most common misconceptions
- Confusing global dimming with global warming.
- Thinking nitrogen oxides come from the fuel rather than the air.
- Giving health effects when the question asks for environmental effects.
- Stopping too early in longer explanations and missing the final mark.
Quick full-mark model answers
✅ Concise answers you could write in the exam
- 01.1: CH₄ + 2O₂ → CO₂ + 2H₂O
- 01.2: Petrol hydrocarbons have fewer carbon atoms than diesel hydrocarbons. Petrol also has a lower boiling point range than diesel.
- 01.3: Oxygen
- 01.4: The nitrogen comes from the air.
- 01.5: Global dimming
- 01.6: Carbon monoxide is odourless. (Colourless also scores.)
- 01.7: Diesel burns at a high temperature above 100 °C, which is above the boiling point of water, so water is produced as vapour.
- 01.8: Sulfur in diesel burns to make sulfur dioxide. This causes acid rain, which can damage plants and aquatic life.
Topics
Chemistry · C7: Organic Chemistry · C9: Chemistry of the Atmosphere
Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 2 (Higher), 2023. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.