AQA GCSE Combined Science: Trilogy Chemistry Paper 2 (Higher), 2023: Question 1

12 marks · Standard Demand difficulty · Short Answer

Explain the combustion and environmental effects of burning fuels such as methane, petrol and diesel.

Practise this question

Question

An exam question page titled about the combustion of fuels as a source of atmospheric pollutants. Part 01.1 asks the student to balance the equation for the combustion of methane, shown as CH4 + __ O2 → CO2 + __ H2O, worth 1 mark. Part 01.2 includes a table comparing petrol and diesel, showing the range of carbon atoms in a hydrocarbon molecule and the range of boiling points in degrees Celsius, then asks the student to compare the properties of petrol and diesel using the table, worth 2 marks. Further parts ask: which element is contained in oxides of nitrogen, carbon monoxide and water vapour; where the nitrogen in nitrogen oxides comes from; what environmental effect particulates from diesel cause; why carbon monoxide is difficult to detect; why water vapour not liquid water is produced when diesel burns; and why sulfur impurities in diesel cause an environmental problem.
Question text

01 The combustion of fuels is a source of atmospheric pollutants.

01.1 Methane is a fuel.

Balance the equation for the combustion of methane.

[1 mark]

CH4 + O2 → CO2 + H2O

01.2 Many fuels are mixtures.

Petrol and diesel are mixtures of hydrocarbons.

Table 1 shows properties of petrol and of diesel.

Table 1

Petrol Diesel

Range of number of carbon atoms in

4 to 12 12 to 20

a hydrocarbon molecule

Range of boiling points in °C 40 to 205 250 to 350

Compare the properties of petrol and diesel.

Use Table 1.

[2 marks]

01.3 The gases released when a fuel is burned in car engines may include:

• oxides of nitrogen

• carbon monoxide

• water vapour.

Which chemical element do all these gases contain?

[1 mark]

Tick ( ) one box.

Carbon

Hydrogen

Nitrogen

Oxygen

01.4 When diesel burns in car engines, oxides of nitrogen are produced.

Where does the nitrogen come from?

[1 mark]

01.5 When diesel burns, particulates may be produced.

What environmental effect do particulates from burning diesel cause?

[1 mark]

01.6 Carbon monoxide may be produced when diesel burns.

Give one reason why carbon monoxide is difficult to detect.

[1 mark]

01.7 Explain why water vapour and not liquid water is produced when diesel burns.

[2 marks]

01.8 Sulfur is a common impurity in diesel.

Explain why this causes an environmental problem.

[3 marks]

Mark scheme

Show the mark scheme The mark scheme shows the balanced methane combustion equation CH4 + 2O2 → CO2 + 2H2O. It accepts that petrol hydrocarbons have fewer carbon atoms than diesel and that petrol has a lower boiling point range than diesel, with alternative acceptable comparisons such as petrol being more flammable or less viscous. It also gives the answers oxygen, air or the atmosphere, global dimming, carbon monoxide being colourless or odourless, diesel burning at a temperature above 100 degrees Celsius so water vapour forms, and sulfur dioxide causing acid rain leading to effects such as damage to buildings, trees, aquatic life, soil acidification or respiratory problems.

Question 1

AO /

Question Answers Extra information Mark

Spec. Ref.

01.1 CH4 + 2 O2 → CO2 + 2 H2O 1 AO2

5.7.1.3

AO /

Spec. Ref.

01.2 allow converse throughout AO3

5.7.1.3

hydrocarbon molecules in petrol 1

have fewer carbon atoms than

those in diesel

petrol has a lower boiling point 1

(range) than diesel

allow petrol is more flammable

than diesel

allow petrol is less viscous than

diesel

AO /

Spec. Ref.

01.3 oxygen 1 AO1

5.8.1.2

AO /

Spec. Ref.

01.4 air allow the atmosphere 1 AO1

5.9.1.1

allow from volcanoes 5.9.3.1

AO /

Spec. Ref.

01.5 global dimming 1 AO2

– OMBINED SCIENCE: TRILOGY – – 5.9.3.1

AO /

Spec. Ref.

01.6 (carbon monoxide is) colourless ignore clear 1 AO1

or 5.9.3.2

(carbon monoxide is) odourless

AO /

Spec. Ref.

01.7 (diesel) burns at a high 1 AO2

temperature

or

(diesel) burns at a temperature

greater than 100 °C

AO3

(which is) above the boiling 1

point of water 5.2.2.1

5.9.3.1

AO /

Spec. Ref.

01.8 sulfur dioxide (is produced when 1 AO1

diesel is burnt) 5.9.3.1

5.9.3.2

(which causes) acid rain 1

(which results in)

any one from: 1

• damage to buildings /

statues / bridges

• damage to trees / plants

• damage to aquatic life

• acidification of lakes /

rivers / soil

• respiratory problems allow (which affects) asthma

Total Question 1 12

How to answer it

Combustion of Fuels and Atmospheric Pollutants

What this question tests

This question checks your knowledge of combustion, balancing equations, comparing fuel properties from a table, identifying elements in compounds, and explaining how burning fuels causes pollution problems such as nitrogen oxides, particulates, carbon monoxide and sulfur dioxide. It also tests whether you can turn simple scientific facts into exam-style explanations worth 1–3 marks.

Question overview
Part Topic Marks
01.1Balance methane combustion equation1
01.2Compare petrol and diesel using table data2
01.3Identify common element in gases1
01.4Source of nitrogen in nitrogen oxides1
01.5Environmental effect of particulates1
01.6Why carbon monoxide is hard to detect1
01.7Why water vapour forms, not liquid water2
01.8Why sulfur impurity causes environmental problems3

Total: 12 marks

Part 01.1 – Balancing methane combustion

1 mark

✅ Correct answer

CH₄ + 2O₂ → CO₂ + 2H₂O

1 mark for both missing numbers correct: 2 in front of O₂ and 2 in front of H₂O.

💡 Key knowledge

  • Combustion of a hydrocarbon produces carbon dioxide and water.
  • You balance equations by changing big numbers in front of formulas, not the small numbers inside formulas.
  • CH₄ has 4 H atoms, so you need 2H₂O to make 4 H atoms on the right.

🧠 Exam technique

  • Count atoms on each side carefully: C, then H, then O.
  • Leave CH₄, CO₂ and H₂O formulas unchanged.
  • For a 1-mark balancing question, one wrong number means no mark.

❌ Common errors

  • Writing CH₄ + O₂ → CO₂ + 2H₂O and forgetting oxygen is not balanced.
  • Changing a formula, for example writing O₄ or H₄O₂.
  • Not checking the total oxygen atoms at the end.

Part 01.2 – Comparing petrol and diesel

2 marks

✅ Correct answers

Any two valid comparisons from the table:

  • Hydrocarbon molecules in petrol have fewer carbon atoms than those in diesel.
  • Petrol has a lower boiling point range than diesel.
1 mark for comparing carbon number.
1 mark for comparing boiling point range.
The mark scheme allows the converse throughout, e.g. diesel has more carbon atoms / higher boiling points.

💡 Key knowledge

  • Petrol range: 4 to 12 carbon atoms, 40 to 205 °C.
  • Diesel range: 12 to 20 carbon atoms, 250 to 350 °C.
  • Longer hydrocarbon molecules usually have higher boiling points.
  • The mark scheme also allows: petrol is more flammable and petrol is less viscous than diesel.

🧠 Exam technique

  • Use the wording compare: mention both fuels.
  • Lift data from the table and turn it into a sentence.
  • For 2 marks, make two separate comparison points.
  • Best answers use phrases like lower than , higher than , fewer than , more than .

❌ Common errors

  • Only describing one fuel without comparing it to the other.
  • Giving unrelated facts not from the table.
  • Saying petrol has “more carbon atoms” than diesel.
  • Missing the idea of range and writing just one number.

Part 01.3 – Common element in the gases

1 mark

✅ Correct answer

Oxygen

1 mark for selecting oxygen.

💡 Key knowledge

  • Oxides of nitrogen contain oxygen.
  • Carbon monoxide contains oxygen.
  • Water vapour is H₂O, so it contains oxygen too.

❌ Common errors

  • Choosing hydrogen because of water vapour — but carbon monoxide and nitrogen oxides do not contain hydrogen.
  • Choosing nitrogen because of nitrogen oxides — but carbon monoxide and water do not both contain nitrogen.

Part 01.4 – Where nitrogen oxides get their nitrogen from

1 mark

✅ Correct answer

From the air.

1 mark for air . The mark scheme also allows the atmosphere .

💡 Key knowledge

At the high temperatures inside an engine, nitrogen and oxygen from the air can react to form nitrogen oxides.

🧠 Exam technique

This is a short recall question. Give the exact source, not a long story.

❌ Common errors

  • Saying the nitrogen comes from diesel itself.
  • Answering just “from burning” without naming air or atmosphere.

Part 01.5 – Environmental effect of particulates

1 mark

✅ Correct answer

Global dimming

1 mark for naming global dimming.

💡 Key knowledge

Particulates in the atmosphere can block or reflect sunlight, so less sunlight reaches the Earth's surface. This is called global dimming.

❌ Common errors

  • Giving a health effect such as breathing problems when the question asks for an environmental effect.
  • Writing global warming instead of global dimming.

Part 01.6 – Why carbon monoxide is difficult to detect

1 mark

✅ Correct answer

Carbon monoxide is colourless or odourless .

1 mark for either colourless or odourless . The mark scheme says ignore clear .

💡 Key knowledge

Carbon monoxide is dangerous because people may not notice it is present.

🧠 Exam technique

Only one reason is needed. Keep it precise and use scientific vocabulary.

❌ Common errors

  • Writing “clear” — the mark scheme does not credit this.
  • Talking about toxicity only. The question is about why it is hard to detect.

Part 01.7 – Why water vapour, not liquid water, is produced

2 marks

✅ Correct answer

A full 2-mark answer needs both ideas:

  1. Diesel burns at a high temperature / at a temperature greater than 100 °C.
  2. This temperature is above the boiling point of water, so the water produced is a gas (water vapour), not a liquid.
1 mark for high temperature / greater than 100 °C. 1 mark for linking this to being above water’s boiling point.

💡 Key knowledge

  • Boiling point of water = 100 °C.
  • If water is formed at temperatures above this, it will be water vapour.
  • This question is about state change, not about how much oxygen is present.

🧠 Exam technique

For a 2-mark explain question, do not stop at “it is hot”. Add the scientific link: above boiling point.

Top answers clearly chain the idea: high temperature → above 100 °C → water is vapour .

❌ Common errors

  • Saying “because water is made as a gas” with no reason.
  • Talking about evaporation after the reaction instead of the combustion temperature.
  • Forgetting to mention 100 °C or boiling point.

Part 01.8 – Why sulfur in diesel causes an environmental problem

3 marks

✅ Correct answer

A full-mark answer should include this chain:

  1. When diesel burns, sulfur produces sulfur dioxide.
  2. Sulfur dioxide causes acid rain.
  3. Acid rain causes damage, for example:
    • damage to buildings, statues or bridges
    • damage to trees or plants
    • damage to aquatic life
    • acidification of lakes, rivers or soil
    • respiratory problems
1 mark for sulfur dioxide being produced.
1 mark for acid rain.
1 mark for one valid consequence of acid rain.

💡 Key knowledge

Sulfur is an impurity, so it is not part of the useful fuel. When it burns, it forms a pollutant. The key pollutant named by the mark scheme is sulfur dioxide.

🧠 Exam technique

This is a classic 3-mark “explain why” question. Build a clear cause-and-effect sequence:

sulfur in diesel → sulfur dioxide → acid rain → environmental damage

Students often lose the third mark by not giving the final effect.

❌ Common errors

  • Saying sulfur causes global warming — not the mark scheme answer here.
  • Mentioning sulfur dioxide but not acid rain.
  • Mentioning acid rain but not a consequence.
  • Giving vague effects like “it is bad for the environment” without an example.

Examiner insights across the whole question

💡 What strong answers did well

  • Used exact scientific terms from the specification: oxygen, air, global dimming, sulfur dioxide, acid rain.
  • For comparison questions, made direct comparisons rather than separate descriptions.
  • For explanation questions, linked ideas in the correct order to secure all available marks.

🧠 Best strategy for similar questions

  • On 1-mark questions, give the precise keyword and move on.
  • On 2- or 3-mark questions, write one point per mark.
  • If a table is given, use it directly.
  • If the question says explain, include a reason or consequence, not just a fact.

❌ Most common misconceptions

  • Confusing global dimming with global warming.
  • Thinking nitrogen oxides come from the fuel rather than the air.
  • Giving health effects when the question asks for environmental effects.
  • Stopping too early in longer explanations and missing the final mark.

Quick full-mark model answers

✅ Concise answers you could write in the exam

  • 01.1: CH₄ + 2O₂ → CO₂ + 2H₂O
  • 01.2: Petrol hydrocarbons have fewer carbon atoms than diesel hydrocarbons. Petrol also has a lower boiling point range than diesel.
  • 01.3: Oxygen
  • 01.4: The nitrogen comes from the air.
  • 01.5: Global dimming
  • 01.6: Carbon monoxide is odourless. (Colourless also scores.)
  • 01.7: Diesel burns at a high temperature above 100 °C, which is above the boiling point of water, so water is produced as vapour.
  • 01.8: Sulfur in diesel burns to make sulfur dioxide. This causes acid rain, which can damage plants and aquatic life.

Topics

Chemistry · C7: Organic Chemistry · C9: Chemistry of the Atmosphere

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 2 (Higher), 2023. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.