AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2024: Question 1

9 marks · Standard Demand difficulty · Short Answer

Use a graph to make conclusions about copper production, explain why a copper-zinc alloy is harder than pure copper, and calculate the mass of copper in a sample of alloy.

Practise this question

Question

The question contains three parts about copper. Part 01.1 shows a line graph titled Figure 1 with the y-axis labelled mass of copper produced each year in 10^9 kilograms and the x-axis labelled year from 1900 to 2025. The curve rises slowly at first and then more steeply, showing copper production increasing over time. Below the graph, the question asks for two conclusions from Figure 1. Part 01.2 shows Figure 2 with diagrams of particles in a regular lattice for pure copper and a mixed lattice for an alloy of copper and zinc, with arrows labelling a zinc atom and a copper atom. The question asks why the alloy is harder than pure copper using Figure 2. Part 01.3 states that a 5.25 g sample of a copper-zinc alloy contains 13.5% zinc by mass and asks for the mass of copper in the sample to 3 significant figures.
Question text

01 Copper is a useful metal.

01.1 Figure 1 shows the mass of copper produced between 1900 and 2010.

Figure 1

Give two conclusions that can be made from Figure 1.

[2 marks]

Mixtures of copper and zinc are heated to produce alloys.

01.2 Figure 2 represents the structures of pure copper and of an

alloy of copper and zinc.

Figure 2

Explain why the alloy of copper and zinc is harder than pure copper.

Use Figure 2.

[3 marks]

01.3 A 5.25 g sample of an alloy of copper and zinc contains 13.5% zinc by mass.

Calculate the mass of copper in the 5.25 g sample.

Give your answer to 3 significant figures.

[4 marks]

Mass of copper (3 significant figures) = g

Mark scheme

Show the mark scheme Mark scheme for AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2024: Question 1

Question 1

AO /

Question Answers Extra information Mark

Spec. Ref.

01.1 any two from: 2 AO3

• mass of copper produced 5.2.2.7

increased (from 1900 to 2010)

• before 1930 the mass of allow a value in the range 1925

copper produced increased to 1930

slightly

• after 1930 the mass of copper allow a value in the range 1925

produced increased rapidly to 1930

• the highest mass of copper allow the highest mass of

was produced in 2010 copper produced was 15.8

(× 109 kilograms)

• the lowest mass of copper allow the lowest mass of copper

was produced in 1900 produced was 0.2 (× 109

kilograms)

• the increase in the mass of

copper produced was not

linear

AO /

Spec. Ref.

01.2 (alloy of copper and zinc is 1 AO2

harder because) the atoms are 5.2.2.7

different sizes

(so the) layers are distorted 1

(so the) layers cannot easily allow (so the) atoms cannot 1

slide – slide over each other – –

AO /

Spec. Ref.

01.3 (% copper = 100 – 13.5 =) 1 AO2

86.5 (%) 5.2.2.7

86.5 allow correct use of an 1

(mass of copper =) × 5.25

100 incorrectly determined

percentage of copper

= 4.54125 (g) 1

= 4.54 (g) 1

allow an answer correctly 7

rounded to 3 significant figures

from an incorrect calculation

which uses the values in the

question

OR

13.5

(mass of zinc =) × 5.25 (1)

= 0.70875 (g) (1)

(mass of copper = 5.25 –

0.70875)

= 4.54125 (g) (1) allow correct use of an

incorrectly determined mass of

zinc

= 4.54 (g) (1) allow an answer correctly

rounded to 3 significant figures

from an incorrect calculation

which uses the values in the

question

Total Question 1 9

How to answer it

Standard Demand

Copper trends, alloys and percentage mass

What this question tests

Reading conclusions from a graph, explaining why alloys are harder than pure metals using particle ideas, and calculating percentage composition by mass. This question tests careful use of data, accurate science vocabulary, and clear step-by-step calculation with correct rounding.

Question 01.1

Part (a): Conclusions from Figure 1

2 marks

✅ Correct answers

Any two valid conclusions score the 2 marks. Acceptable answers include:

  • The mass of copper produced increased from 1900 to 2010.
  • Before about 1930, the mass of copper produced increased only slightly.
  • After about 1930, the mass of copper produced increased rapidly.
  • The highest mass of copper was produced in 2010.
  • The lowest mass of copper was produced in 1900.
  • The increase was not linear.
Example full-mark response:
1. The mass of copper produced increased from 1900 to 2010.
2. After about 1930, the mass of copper produced increased rapidly.

💡 Key knowledge

  • A conclusion must come from the graph, not from outside knowledge.
  • You can comment on a trend, a comparison, or a highest/lowest value.
  • The graph curves upwards, so the increase is getting faster over time.
  • The mark scheme allows about 1925 to 1930 as the turning point.

🧠 Exam technique

  • For “give two conclusions”, write two separate clear statements.
  • Use the graph language: increased, highest, lowest, rapidly, slightly, not linear.
  • If possible, include dates to make your point precise.
  • Do not explain why the trend happened unless the question asks you to.
Mark breakdown: 1 mark for each valid conclusion, up to 2 marks total.

❌ Common errors

  • Copying exact numbers incorrectly from the graph.
  • Saying “it increased steadily” — this is wrong because the increase is not linear.
  • Giving reasons such as “more demand for copper” — not needed and not from the graph.
  • Repeating the same idea twice in different words.

Examiner insight: Students often lost marks by making vague comments like “it went up a lot”. Stronger answers described how the trend changed, for example “slight increase before 1930, rapid increase after 1930”.

Question 01.2

Part (b): Why the copper-zinc alloy is harder

3 marks

✅ Correct answer

A full-mark answer should include all three ideas:

  • The atoms are different sizes.
  • This distorts the layers.
  • So the layers cannot easily slide over each other.
Example 3-mark response:
In the alloy, the copper and zinc atoms are different sizes. This distorts the layers of atoms. As a result, the layers cannot slide over each other easily, so the alloy is harder than pure copper.

💡 Key knowledge

  • Pure metals have regular layers of atoms.
  • Those regular layers can slide more easily.
  • In an alloy, atoms of different sizes disrupt the regular arrangement.
  • This makes movement of layers more difficult, so the metal is harder.

🧠 Exam technique

  • The question says Use Figure 2, so refer to the different-sized atoms shown.
  • For 3 marks, build a chain of reasoning.
  • Best structure: different sizes → distorted layers → cannot slide easily → harder
Mark breakdown:
1 mark: atoms are different sizes
1 mark: layers are distorted
1 mark: layers cannot easily slide

❌ Common errors

  • Saying “the alloy is harder because zinc is hard” — not the marking point.
  • Talking about stronger bonds — the mark scheme wants the sliding/layer idea.
  • Forgetting to mention that the atoms are different sizes.
  • Saying only “the structure is different” without explaining the effect on layers.

Examiner insight: Top answers linked the particle diagram directly to hardness. Weaker answers often stopped at “different sizes” and did not explain that this prevents layers sliding.

Question 01.3

Part (c): Calculate the mass of copper

4 marks

✅ Correct answer

Mass of copper = 4.54 g (to 3 significant figures)

Final answer: 4.54 g

📐 Calculations

Method 1: Find % copper first

  1. Percentage of copper = 100 − 13.5 = 86.5%
  2. Mass of copper = 86.5/100 × 5.25
  3. Mass of copper = 4.54125 g
  4. Round to 3 significant figures = 4.54 g

Method 2: Find zinc mass, then subtract

  1. Mass of zinc = 13.5/100 × 5.25 = 0.70875 g
  2. Mass of copper = 5.25 − 0.70875 = 4.54125 g
  3. Round to 3 significant figures = 4.54 g

💡 Key knowledge

  • Percentage by mass tells you how much of the total mass is one substance.
  • If zinc is 13.5%, then copper must be 86.5%.
  • To find a percentage of a mass: percentage ÷ 100 × total mass
  • Always give the final answer with the correct unit: g.

🧠 Exam technique

  • Show all working — this is a 4-mark calculation.
  • Write the percentage conversion clearly before using it.
  • Do not round too early; round only at the end.
  • Check if your answer is sensible: copper should be most of the 5.25 g because 86.5% is much more than half.
Mark breakdown:
1 mark: 86.5% copper
1 mark: correct calculation setup
1 mark: correct unrounded value 4.54125 g
1 mark: correct final answer 4.54 g to 3 significant figures

❌ Common errors

  • Using 13.5% as the percentage of copper instead of zinc.
  • Doing 5.25 ÷ 13.5 or another incorrect percentage method.
  • Forgetting to divide by 100.
  • Rounding to 4.5 g instead of 3 significant figures.
  • Missing the unit g.

Examiner insight: Many students got part way through correctly but lost the final mark by not rounding to 3 significant figures. The best responses showed a full method and then wrote a clearly labelled final answer.

Quick full-mark recap

✅ 01.1 Graph conclusions

Choose any two valid trend statements, such as:

  • Production increased from 1900 to 2010.
  • After about 1930, production increased rapidly.

✅ 01.2 Alloy hardness

Use this chain:

different-sized atoms → distorted layers → layers cannot slide easily → harder

✅ 01.3 Calculation

100 − 13.5 = 86.5% copper

86.5/100 × 5.25 = 4.54125 g

Answer = 4.54 g

Topics

Chemistry · Required Practicals · C2: Bonding, Structure and the Properties of Matter · C3: Quantitative Chemistry

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.