AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2024: Question 1
9 marks · Standard Demand difficulty · Short Answer
Use a graph to make conclusions about copper production, explain why a copper-zinc alloy is harder than pure copper, and calculate the mass of copper in a sample of alloy.
Practise this questionQuestion
Question text
01 Copper is a useful metal.
01.1 Figure 1 shows the mass of copper produced between 1900 and 2010.
Figure 1
Give two conclusions that can be made from Figure 1.
[2 marks]
Mixtures of copper and zinc are heated to produce alloys.
01.2 Figure 2 represents the structures of pure copper and of an
alloy of copper and zinc.
Figure 2
Explain why the alloy of copper and zinc is harder than pure copper.
Use Figure 2.
[3 marks]
01.3 A 5.25 g sample of an alloy of copper and zinc contains 13.5% zinc by mass.
Calculate the mass of copper in the 5.25 g sample.
Give your answer to 3 significant figures.
[4 marks]
Mass of copper (3 significant figures) = g
Mark scheme
Show the mark scheme
Question 1
AO /
Question Answers Extra information Mark
Spec. Ref.
01.1 any two from: 2 AO3
• mass of copper produced 5.2.2.7
increased (from 1900 to 2010)
• before 1930 the mass of allow a value in the range 1925
copper produced increased to 1930
slightly
• after 1930 the mass of copper allow a value in the range 1925
produced increased rapidly to 1930
• the highest mass of copper allow the highest mass of
was produced in 2010 copper produced was 15.8
(× 109 kilograms)
• the lowest mass of copper allow the lowest mass of copper
was produced in 1900 produced was 0.2 (× 109
kilograms)
• the increase in the mass of
copper produced was not
linear
AO /
Spec. Ref.
01.2 (alloy of copper and zinc is 1 AO2
harder because) the atoms are 5.2.2.7
different sizes
(so the) layers are distorted 1
(so the) layers cannot easily allow (so the) atoms cannot 1
slide – slide over each other – –
AO /
Spec. Ref.
01.3 (% copper = 100 – 13.5 =) 1 AO2
86.5 (%) 5.2.2.7
86.5 allow correct use of an 1
(mass of copper =) × 5.25
100 incorrectly determined
percentage of copper
= 4.54125 (g) 1
= 4.54 (g) 1
allow an answer correctly 7
rounded to 3 significant figures
from an incorrect calculation
which uses the values in the
question
OR
13.5
(mass of zinc =) × 5.25 (1)
= 0.70875 (g) (1)
(mass of copper = 5.25 –
0.70875)
= 4.54125 (g) (1) allow correct use of an
incorrectly determined mass of
zinc
= 4.54 (g) (1) allow an answer correctly
rounded to 3 significant figures
from an incorrect calculation
which uses the values in the
question
Total Question 1 9
How to answer it
Copper trends, alloys and percentage mass
What this question tests
Reading conclusions from a graph, explaining why alloys are harder than pure metals using particle ideas, and calculating percentage composition by mass. This question tests careful use of data, accurate science vocabulary, and clear step-by-step calculation with correct rounding.
Part (a): Conclusions from Figure 1
2 marks
✅ Correct answers
Any two valid conclusions score the 2 marks. Acceptable answers include:
- The mass of copper produced increased from 1900 to 2010.
- Before about 1930, the mass of copper produced increased only slightly.
- After about 1930, the mass of copper produced increased rapidly.
- The highest mass of copper was produced in 2010.
- The lowest mass of copper was produced in 1900.
- The increase was not linear.
1. The mass of copper produced increased from 1900 to 2010.
2. After about 1930, the mass of copper produced increased rapidly.
💡 Key knowledge
- A conclusion must come from the graph, not from outside knowledge.
- You can comment on a trend, a comparison, or a highest/lowest value.
- The graph curves upwards, so the increase is getting faster over time.
- The mark scheme allows about 1925 to 1930 as the turning point.
🧠 Exam technique
- For “give two conclusions”, write two separate clear statements.
- Use the graph language: increased, highest, lowest, rapidly, slightly, not linear.
- If possible, include dates to make your point precise.
- Do not explain why the trend happened unless the question asks you to.
❌ Common errors
- Copying exact numbers incorrectly from the graph.
- Saying “it increased steadily” — this is wrong because the increase is not linear.
- Giving reasons such as “more demand for copper” — not needed and not from the graph.
- Repeating the same idea twice in different words.
Examiner insight: Students often lost marks by making vague comments like “it went up a lot”. Stronger answers described how the trend changed, for example “slight increase before 1930, rapid increase after 1930”.
Part (b): Why the copper-zinc alloy is harder
3 marks
✅ Correct answer
A full-mark answer should include all three ideas:
- The atoms are different sizes.
- This distorts the layers.
- So the layers cannot easily slide over each other.
In the alloy, the copper and zinc atoms are different sizes. This distorts the layers of atoms. As a result, the layers cannot slide over each other easily, so the alloy is harder than pure copper.
💡 Key knowledge
- Pure metals have regular layers of atoms.
- Those regular layers can slide more easily.
- In an alloy, atoms of different sizes disrupt the regular arrangement.
- This makes movement of layers more difficult, so the metal is harder.
🧠 Exam technique
- The question says Use Figure 2, so refer to the different-sized atoms shown.
- For 3 marks, build a chain of reasoning.
- Best structure: different sizes → distorted layers → cannot slide easily → harder
1 mark: atoms are different sizes
1 mark: layers are distorted
1 mark: layers cannot easily slide
❌ Common errors
- Saying “the alloy is harder because zinc is hard” — not the marking point.
- Talking about stronger bonds — the mark scheme wants the sliding/layer idea.
- Forgetting to mention that the atoms are different sizes.
- Saying only “the structure is different” without explaining the effect on layers.
Examiner insight: Top answers linked the particle diagram directly to hardness. Weaker answers often stopped at “different sizes” and did not explain that this prevents layers sliding.
Part (c): Calculate the mass of copper
4 marks
✅ Correct answer
Mass of copper = 4.54 g (to 3 significant figures)
📐 Calculations
Method 1: Find % copper first
- Percentage of copper = 100 − 13.5 = 86.5%
- Mass of copper = 86.5/100 × 5.25
- Mass of copper = 4.54125 g
- Round to 3 significant figures = 4.54 g
Method 2: Find zinc mass, then subtract
- Mass of zinc = 13.5/100 × 5.25 = 0.70875 g
- Mass of copper = 5.25 − 0.70875 = 4.54125 g
- Round to 3 significant figures = 4.54 g
💡 Key knowledge
- Percentage by mass tells you how much of the total mass is one substance.
- If zinc is 13.5%, then copper must be 86.5%.
- To find a percentage of a mass: percentage ÷ 100 × total mass
- Always give the final answer with the correct unit: g.
🧠 Exam technique
- Show all working — this is a 4-mark calculation.
- Write the percentage conversion clearly before using it.
- Do not round too early; round only at the end.
- Check if your answer is sensible: copper should be most of the 5.25 g because 86.5% is much more than half.
1 mark: 86.5% copper
1 mark: correct calculation setup
1 mark: correct unrounded value 4.54125 g
1 mark: correct final answer 4.54 g to 3 significant figures
❌ Common errors
- Using 13.5% as the percentage of copper instead of zinc.
- Doing 5.25 ÷ 13.5 or another incorrect percentage method.
- Forgetting to divide by 100.
- Rounding to 4.5 g instead of 3 significant figures.
- Missing the unit g.
Examiner insight: Many students got part way through correctly but lost the final mark by not rounding to 3 significant figures. The best responses showed a full method and then wrote a clearly labelled final answer.
Quick full-mark recap
✅ 01.1 Graph conclusions
Choose any two valid trend statements, such as:
- Production increased from 1900 to 2010.
- After about 1930, production increased rapidly.
✅ 01.2 Alloy hardness
Use this chain:
different-sized atoms → distorted layers → layers cannot slide easily → harder
✅ 01.3 Calculation
100 − 13.5 = 86.5% copper
86.5/100 × 5.25 = 4.54125 g
Answer = 4.54 g
Topics
Chemistry · Required Practicals · C2: Bonding, Structure and the Properties of Matter · C3: Quantitative Chemistry
Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.