AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2024: Question 4

8 marks · Standard Demand difficulty · Short Answer

Answer questions about nitric acid as a strong acid, dilution, pH and hydrogen ion concentration, ionic equations for acid–alkali neutralisation, reacting magnesium carbonate with nitric acid, and improving a temperature-change investigation.

Practise this question

Question

A chemistry exam question titled Question 4 with seven short parts about nitric acid. Part 4.1 asks what is meant by a strong acid, part 4.2 asks what is meant by a dilute aqueous solution, and part 4.3 asks how hydrogen ion concentration changes when nitric acid changes from pH 1 to pH 3, with four tick-box options about increases or decreases by a factor of 10 or 100. Part 4.4 asks for the ionic equation for the reaction between an acid and an alkali, shown as a blank space plus blank space leading to a blank product line. Part 4.5 gives the equation MgCO3 + 2HNO3 → Mg(NO3)2 + H2O + CO2 and asks for the ratio of moles of magnesium carbonate to moles of nitric acid, with four multiple-choice ratios. Part 4.6 describes adding excess nitric acid to magnesium carbonate, then asking the colour of universal indicator, with choices red, green and blue, and includes a diagram of a polystyrene cup, thermometer and 50 cm3 of nitric acid being mixed with 0.50 g magnesium carbonate. Part 4.7 asks for two improvements to the method to make results more accurate, not referring to apparatus improvements.
Question text

04 Nitric acid (HNO3) is a strong acid.

04.1 What is meant by a ‘strong acid’?

[1 mark]

04.2 Nitric acid is used as a dilute aqueous solution.

What is meant by ‘dilute aqueous solution’?

[1 mark]

04.3 10 cm3 of a nitric acid solution has a pH of 1

Water is added to the nitric acid solution to change the pH of the nitric acid solution to

pH 3

How does the hydrogen ion concentration change?

[1 mark]

Tick ( ) one box.

Decreases by a factor of 100

Decreases by a factor of 10

Increases by a factor of 10

Increases by a factor of 100

04.4 Write the ionic equation for the reaction between an acid and an alkali.

[1 mark]

+ →

The equation shows the reaction between magnesium carbonate and nitric acid.

MgCO3 + 2HNO3 → Mg(NO3)2 + H2O + CO2

04.5 What is the ratio of the number of moles of magnesium carbonate to the

number of moles of nitric acid in the reaction?

[1 mark]

Tick ( ) one box.

1 : 1

1 : 2

2 : 1

2 : 2

04.6 A student mixed some magnesium carbonate with excess nitric acid.

The student then added two drops of universal indicator to the solution.

What colour was the solution after the addition of universal indicator?

[1 mark]

Tick ( ) one box.

Red

Green

Blue 14

A student investigated the temperature change when different masses of

magnesium carbonate were reacted with excess nitric acid.

Figure 6 shows the apparatus.

Figure 6

This is the method used.

1. Pour 50 cm3 of nitric acid into a polystyrene cup.

2. Measure the temperature of the solution.

3. Add 0.50 g of magnesium carbonate.

4. Stir the mixture.

5. Measure the temperature.

6. Repeat steps 1 to 5 with different masses of magnesium carbonate.

04.7 Give two improvements to the method to produce more accurate results.

Do not refer to improvements to the apparatus in your answer.

[2 marks]

Mark scheme

Show the mark scheme Mark scheme for AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2024: Question 4

Question 4

AO /

Question Answers Extra information Mark

Spec. Ref.

04.1 completely ionised in aqueous allow completely ionised (when 1 AO1

solution dissolved) in water 5.4.2.5

allow fully dissociated in

aqueous solution

AO /

Spec. Ref.

04.2 low concentration of (nitric) acid allow low concentration of solute 1 AO1

dissolved in water / solid / gas dissolved in water 5.4.2.5

AO /

Spec. Ref.

04.3 decreases by a factor of 100 1 AO2

5.4.2.5

AO /

Spec. Ref.

04.4 H+ + OH– → H O ignore state symbols 1 AO1

5.4.2.4

AO /

Spec. Ref.

04.5 1 : 2 1 AO2

– – – 5.3.2.3

AO /

Spec. Ref.

04.6 red 1 AO3

5.3.2.4

5.4.2.2

RPA10

AO /

Spec. Ref.

04.7 (for each mass of magnesium 1 AO3

carbonate) repeat the 5.5.1.1

experiment (discard anomalous RPA10

results) and calculate the mean

measure the highest 1

temperature

Total Question 4 8

How to answer it

Standard Demand

Nitric Acid, pH, Ionic Equations and Method Improvements

AQA GCSE Combined Science: Trilogy – Question 4 study guide

What this question tests

  • Definitions of strong acid and dilute aqueous solution.
  • How pH changes link to hydrogen ion concentration.
  • Writing the ionic equation for neutralisation.
  • Using a balanced equation to find a mole ratio.
  • Predicting indicator colour when acid is in excess.
  • Identifying method improvements for better experimental accuracy.
Question 04.1

Part (a): What is meant by a strong acid?

✅ Correct answer

A strong acid is completely ionised in aqueous solution.

1 mark: must refer to complete ionisation / full dissociation in water.

💡 Key knowledge

  • Strong is about how much the acid ionises.
  • It is not about concentration.
  • A strong acid can still be dilute.

❌ Common errors

  • Saying “it has a low pH” — not the definition.
  • Saying “it is concentrated” — strong and concentrated are different ideas.
  • Missing in water / aqueous solution.

🧠 Exam technique

For 1-mark definition questions, give the exact science phrase. Here, the key words are completely ionised and aqueous solution .

Question 04.2

Part (b): What is meant by dilute aqueous solution?

✅ Correct answer

A low concentration of nitric acid dissolved in water.

1 mark: answers about a low concentration of solute dissolved in water are allowed.

💡 Key knowledge

  • Dilute means not much solute per volume of solution.
  • Aqueous means dissolved in water.

❌ Common errors

  • Saying “weak acid” — dilute does not mean weak.
  • Saying “lots of water” without mentioning low concentration.
Question 04.3

Part (c): pH change from 1 to 3

✅ Correct answer

The hydrogen ion concentration decreases by a factor of 100.

1 mark for choosing: Decreases by a factor of 100.

📐 Calculation idea

  1. pH increases from 1 to 3 = change of 2 pH units.
  2. Each pH unit means a factor of 10 change in H⁺ concentration.
  3. So total change = 10 × 10 = 100.
  4. Because pH went up, H⁺ concentration went down.

💡 Key knowledge

As pH increases, the solution becomes less acidic, so the concentration of H⁺ ions decreases.

❌ Common errors

  • Choosing factor of 10 instead of 100.
  • Saying “increases” instead of “decreases”.
  • Forgetting that a change of 2 pH values means two lots of ×10.

🧠 Exam technique

Whenever pH changes by more than 1, count the number of pH steps carefully. Examiner reports often show students lose easy marks by only using one factor of 10.

Question 04.4

Part (d): Ionic equation for an acid and an alkali

✅ Correct answer

H⁺ + OH⁻ → H₂O

1 mark. State symbols are not needed here.

💡 Key knowledge

This is the ionic equation for neutralisation. Hydrogen ions from the acid react with hydroxide ions from the alkali to form water.

❌ Common errors

  • Writing a full symbol equation instead of the ionic equation.
  • Forgetting the charges: H⁺ and OH⁻ .
  • Writing H₂ + O instead of H₂O.
Question 04.5

Part (e): Mole ratio from the equation

Equation given: MgCO₃ + 2HNO₃ → Mg(NO₃)₂ + H₂O + CO₂

✅ Correct answer

The ratio of magnesium carbonate to nitric acid is 1 : 2.

1 mark for selecting 1 : 2.

📐 How to get it

  1. Look at the numbers in front of each substance.
  2. MgCO₃ has no number written, so it means 1.
  3. HNO₃ has a coefficient of 2.
  4. So the mole ratio MgCO₃ : HNO₃ is 1 : 2.

🧠 Exam technique

Use the big balancing numbers in front of formulas, not the small numbers inside formulas.

❌ Common errors

  • Using the nitrate subscript and giving the wrong ratio.
  • Choosing 2 : 1 because the order of substances was not read carefully.
Question 04.6

Part (f): Universal indicator colour with excess nitric acid

✅ Correct answer

The solution would be red.

1 mark for choosing red.

💡 Key knowledge

  • The nitric acid is in excess, so after the reaction the mixture is still acidic.
  • Universal indicator is red in strongly acidic solutions.

❌ Common errors

  • Choosing green because students think “neutralisation” must mean neutral.
  • Ignoring the word excess.

🧠 Exam technique

Words like excess, limiting, and complete reaction often decide the answer. Here, excess acid means the final solution is still acidic.

Question 04.7

Part (g): Two improvements to the method

Important instruction: do not refer to improvements to the apparatus.

✅ Correct answers

Any two from:

  • Repeat the experiment for each mass of magnesium carbonate.
  • Discard anomalous results and calculate a mean.
  • Measure the highest temperature.
2 marks total: one mark for a repeat/mean idea, and one mark for measuring the highest temperature.

🧠 Exam technique

  • The question says method, not apparatus.
  • So do not say things like “use a lid” or “use a better thermometer”.
  • Best answers focus on how the experiment is carried out.

💡 Why these improvements help

  • Repeating and calculating a mean makes results more reliable.
  • Measuring the highest temperature gives a more accurate value for the temperature change, because the temperature may keep rising after stirring starts.

❌ Common errors

  • Referring to apparatus, for example “use insulation”, “use a digital thermometer”, or “use a lid”. These are not credited here.
  • Saying only “do it carefully” — too vague.
  • Saying “stir more” without linking to a mark scheme point.

📐 Full-mark sample answer

1. Repeat each test for each mass of magnesium carbonate and calculate a mean, ignoring any anomalous results.

2. Record the highest temperature reached.

Examiner insight across the whole question

💡 What strong answers did well

  • Used precise science vocabulary: completely ionised, low concentration, aqueous.
  • Read equations carefully to get the correct mole ratio.
  • Spotted that excess acid means the final solution is still acidic.
  • Followed the instruction in 04.7 and improved the method, not the apparatus.

❌ Where students lost marks

  • Mixing up strong and concentrated.
  • Not understanding that a pH change of 2 means a factor of 100.
  • Writing a general word equation instead of the required ionic equation.
  • Giving sensible practical ideas that were not allowed because they changed the apparatus.

Quick full-answer checklist

  • 04.1: completely ionised in aqueous solution
  • 04.2: low concentration of acid dissolved in water
  • 04.3: decreases by a factor of 100
  • 04.4: H⁺ + OH⁻ → H₂O
  • 04.5: 1 : 2
  • 04.6: red
  • 04.7: repeat and calculate mean / discard anomalies; measure the highest temperature

Topics

Chemistry · Required Practicals · C4: Chemical Changes · Chemistry Required Practicals

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.