AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2024: Question 7

10 marks · Standard Demand difficulty · Extended Answer

Explain ionic bonding in calcium chloride, compare the reactivity of chlorine and bromine, and describe the boiling point trend of hydrogen halides with relative formula mass.

Practise this question

Question

The question image shows Question 7 about halogens in Group 7. Part 07.1 asks how calcium reacts with chlorine to produce calcium chloride and says to explain what happens to calcium atoms and chlorine atoms; it is worth 4 marks. Part 07.2 asks why chlorine is more reactive than bromine; it is also worth 4 marks. Part 07.3 contains Table 4 showing boiling points of four hydrogen halides: HF at 20 °C, HCl at -85 °C, HBr at -67 °C, and HI at -35 °C, followed by the instruction to describe how boiling points change as relative formula mass changes; this part is worth 2 marks. The page includes ruled answer lines beneath each part.
Question text

07 Halogens are elements in Group 7 of the periodic table.

07.1 Calcium reacts with chlorine to produce calcium chloride.

Explain what happens to calcium atoms and to chlorine atoms when calcium reacts

with chlorine to produce calcium chloride.

[4 marks]

07.2 Explain why chlorine is more reactive than bromine.

[4 marks]

07.3 Table 4 shows the boiling points of four hydrogen halides.

*24* Table 4

Hydrogen halide Boiling point in °C

HF 20

HCl –85

HBr –67

HI –35

Describe how the boiling points of the hydrogen halides change as the

relative formula mass changes.

[2 marks]

Mark scheme

Show the mark scheme Mark scheme for AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2024: Question 7

Question 7

AO /

Question Answers Extra information Mark

Spec. Ref.

07.1 each calcium atom loses two 1 AO2

electrons 5.1.2.6

allow 1 mark for calcium 5.2.1.1

atoms lose electrons and

(and) each chlorine atom gains chlorine atoms gain electrons 1

one electron

(so) one calcium atom reacts 1

with two chlorine atoms

(to form) Ca2+ ions and Cl- ions 1

or

(to form) calcium ion(s) and allow (to form) ions with full

chloride ion(s) outer shells

allow energy level for shell

AO /

Spec. Ref.

07.2 allow converse for bromine AO1

5.1.2.3

allow energy level for shell 5.1.2.6

chlorine has fewer shells allow chlorine is a smaller atom 1

(so the) outer shell is closer to allow (so the) outer electrons 1

the nucleus are closer to the nucleus

allow (so there) is less shielding

(so) stronger attraction between 1

nucleus and electron gained

or

(so) stronger attraction between

nucleus and outer shell

(so) gains the electron more 1

easily – – –

AO /

Spec. Ref.

07.3 as the relative formula mass 1 AO3

increases the boiling points (of 5.1.2.6

20 the hydrogen halides) increase

(but) HF has the highest boiling 1

point

or

(but) HF does not follow the allow (but) HF is anomalous

trend

Total Question 7 10

How to answer it

Halogens and Hydrogen Halides

What this question tests

This question tests ionic bonding, electron transfer, Group 7 reactivity trends, and interpreting data from a table. You need to explain clearly using ideas such as loss and gain of electrons, ion charges, shells, attraction to the nucleus, and identifying trends and exceptions in boiling point data.

Question overview
Total marks: 10

Short title: Group 7 explanations and data

This is a very typical GCSE Chemistry question: explain bonding, explain a periodic trend, then describe a data trend. Most marks come from using the correct scientific wording in the correct order.

Part (a) — Question 07.1

Calcium reacting with chlorine to form calcium chloride

✅ Correct answer

Each calcium atom loses two electrons.

Each chlorine atom gains one electron.

So one calcium atom reacts with two chlorine atoms.

This forms Ca²⁺ ions and Cl⁻ ions.

Full 4-mark model answer:
When calcium reacts, each calcium atom loses two electrons. Each chlorine atom gains one electron. Therefore one calcium atom reacts with two chlorine atoms. This forms Ca²⁺ ions and Cl⁻ ions.

💡 Key knowledge

  • Calcium is in Group 2, so it forms a 2+ ion.
  • Chlorine is in Group 7, so each atom gains 1 electron to form a 1− ion.
  • Two chlorine atoms are needed to take the two electrons lost by one calcium atom.
  • The mark scheme also allows wording about full outer shells.

🧠 Exam technique

  • For 4 marks, give 4 separate points rather than one vague sentence.
  • Name both substances: what calcium does and what chlorine does.
  • Include the ratio: one calcium to two chlorine atoms.
  • Finish with the ions formed to secure the final mark.

Examiner insight: students often got some credit for saying calcium loses electrons and chlorine gains electrons, but lost marks by missing the numbers: two electrons for calcium and one electron per chlorine atom.

❌ Common errors

  • Saying chlorine gains two electrons.
  • Forgetting that two chlorine atoms are needed.
  • Writing the wrong ions, such as Ca⁺ or Cl²⁻ .
  • Talking generally about “sharing electrons” — this is ionic bonding, so electrons are transferred, not shared.

📐 Structure to remember

  1. State electron loss by the metal: calcium loses 2 electrons.
  2. State electron gain by the non-metal: each chlorine gains 1 electron.
  3. Match the electrons: 1 calcium atom reacts with 2 chlorine atoms.
  4. State the ions formed: Ca²⁺ and Cl⁻.

Part (b) — Question 07.2

Why chlorine is more reactive than bromine

✅ Correct answer

Chlorine has fewer shells than bromine.

So the outer shell is closer to the nucleus.

There is a stronger attraction between the nucleus and an incoming electron.

So chlorine gains an electron more easily and is more reactive.

Full 4-mark model answer:
Chlorine has fewer electron shells than bromine, so its outer shell is closer to the nucleus. This means there is a stronger attraction between the nucleus and an incoming electron. Therefore chlorine gains an electron more easily, so it is more reactive.

💡 Key knowledge

  • Halogens react by gaining one electron.
  • Down Group 7, atoms have more shells.
  • More shells means the outer shell is further from the nucleus.
  • This causes more shielding and weaker attraction for an incoming electron.

The mark scheme allows alternatives such as: chlorine is a smaller atom, or there is less shielding.

🧠 Exam technique

  • This is a chained explanation: fewer shells → closer outer shell → stronger attraction → gains electron more easily.
  • Use the word because or so to link the ideas.
  • Make sure your answer explains reactivity, not just atomic size.

Examiner insight: stronger answers linked the size/shell idea directly to gaining an electron. Weaker answers only said “chlorine is smaller” and stopped there.

❌ Common errors

  • Saying chlorine is more reactive because it has more shells — it has fewer than bromine.
  • Talking about losing electrons. Halogens become reactive by gaining electrons.
  • Saying chlorine has a stronger attraction because it has more protons, without linking to distance and shielding.
  • Giving the trend the wrong way round and saying reactivity increases down Group 7.

Part (c) — Question 07.3

Boiling points of hydrogen halides

Data given: HF = 20 °C, HCl = −85 °C, HBr = −67 °C, HI = −35 °C

✅ Correct answer

As the relative formula mass increases, the boiling points of the hydrogen halides increase.

However, HF does not follow this trend because HF has the highest boiling point.

Full 2-mark model answer:
As relative formula mass increases, the boiling points generally increase. However, HF is anomalous because it has the highest boiling point and does not follow the trend.

💡 Key knowledge

  • Look for the overall pattern first.
  • From HCl to HI, boiling point increases.
  • HF is the exception or anomalous result.
  • For this question, you only need to describe the trend, not explain it.

🧠 Exam technique

  • For 2 marks, give both the trend and the exception.
  • Use the word however or but to show the break in pattern.
  • Do not just list the values — turn them into a sentence about the pattern.

Examiner insight: many students gained 1 mark for spotting that boiling point increases with relative formula mass, but missed the second mark by not mentioning that HF does not follow the trend.

❌ Common errors

  • Saying all four values increase smoothly — they do not, because HF is much higher.
  • Describing the trend as “decreasing” because of the jump from HF to HCl.
  • Trying to explain instead of describe, and then forgetting to state the actual trend.

How the marks are awarded

✅ Mark breakdown

  • 07.1 = 4 marks
    • calcium loses two electrons
    • each chlorine gains one electron
    • one calcium reacts with two chlorine atoms
    • Ca²⁺ and Cl⁻ ions formed
  • 07.2 = 4 marks
    • chlorine has fewer shells / is smaller
    • outer shell closer to nucleus / less shielding
    • stronger attraction for incoming electron
    • gains electron more easily
  • 07.3 = 2 marks
    • boiling point increases as relative formula mass increases
    • HF is the exception / HF has the highest boiling point

🧠 What top answers did well

  • Used precise words like loses, gains, ions, shells, and attraction.
  • Included the correct numbers: 2 electrons, 1 electron, 2 chlorine atoms.
  • Recognised that a data trend can have an exception.
  • Answered exactly what the question asked: explain for 07.1 and 07.2, describe for 07.3.

Quick full-mark recall

💡 Learn these sentences

  • 07.1: Calcium loses two electrons and each chlorine gains one electron, so one calcium reacts with two chlorines to form Ca²⁺ and Cl⁻ ions.
  • 07.2: Chlorine has fewer shells than bromine, so there is less shielding and stronger attraction for an incoming electron, so chlorine gains an electron more easily.
  • 07.3: As relative formula mass increases, boiling point increases, but HF is anomalous and has the highest boiling point.

Topics

Chemistry · C1: Atomic Structure and the Periodic Table · C2: Bonding, Structure and the Properties of Matter

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.