AQA GCSE Combined Science: Trilogy Chemistry Paper 2 (Foundation), 2024: Question 6

10 marks · Standard Demand difficulty · Short Answer

Define hydrocarbons, use the alkane formula, explain fractional distillation of crude oil, balance a cracking equation, describe the test for alkenes, and identify poly(propene) as a polymer.

Practise this question

Question

The question page is headed Question 06 and states that alkanes and alkenes are hydrocarbons. It contains six short parts: define the term hydrocarbon; use the general formula for alkanes, CnH2n+2, to determine the formula with 10 carbon atoms; explain how crude oil is separated into fractions using a diagram of a fractional distillation column with crude oil heated before entering, trays at different heights, an outlet at the bottom and side outlets, and an upward arrow labelled decreasing temperature; balance the cracking equation C14H30 → C8H18 + ___ C3H6; describe the test for alkenes and give the result; and identify the type of substance shown by the repeating unit structure of poly(propene). The final figure shows a bracketed repeating unit with two carbon atoms in the chain, hydrogens attached, a CH3 side group on one carbon, and the symbol n outside the brackets.
Question text

06 Alkanes and alkenes are hydrocarbons.

06.1 Define the term ‘hydrocarbon’.

[1 mark]

06.2 The general formula for alkanes is CnH2n+2

Determine the formula of the alkane with 10 carbon atoms.

[1 mark]

Formula22 =

06.3 Crude oil is a mixture of hydrocarbons.

Figure 4 represents industrial equipment used to separate crude oil into fractions.

Figure 4

Explain how crude oil is separated into fractions.

Use Figure 4.

[4 marks]

06.4 The alkane molecule C14H30 can be cracked to produce smaller molecules.

Balance the equation for the reaction.

[1 mark]

C14H30 → C8H18 + C3H6

Propene (C3H6) is an alkene.

06.5 Describe the test for alkenes.

Give the result.

[2 marks]

Test

Result

06.6 Poly(propene) is made from propene.

Figure 5 represents the repeating unit of poly(propene).

Figure 5

What type of substance is poly(propene)?

[1 mark]

Mark scheme

Show the mark scheme The mark scheme is a table for Question 6 with columns for question number, answers, extra information, mark, and AO/specification reference. It gives: 06.1 molecules made up of carbon and hydrogen atoms only; 06.2 C10H22; 06.3 crude oil is heated so some hydrocarbons vaporise, the column has a temperature gradient or gets cooler going up, and fractions condense at different heights or at their boiling points; 06.4 C14H30 → C8H18 + 2 C3H6; 06.5 add bromine water and it changes from orange to colourless or decolourises; 06.6 polymer, with plastic or hydrocarbon allowed. The bottom of the page shows Total Question 6 = 10 marks.

Question 6

AO /

Question Answers Extra information Mark

Spec. Ref.

06.1 (molecules) made up of carbon 1 AO1

and hydrogen (atoms only) 5.7.1.1

AO /

Spec. Ref.

06.2 C10H22 1 AO2

5.7.1.1

AO /

Spec. Ref.

06.3 (crude oil) is heated 1 AO1

5.7.1.2

(so some of the hydrocarbons) 1

vaporise

the column has a temperature allow the column gets cooler 1

gradient going up

(so) the hydrocarbons / fractions 1

condense at different heights /

temperatures in the column

or

(and) the hydrocarbons /

fractions condense at their

boiling points

AO /

Spec. Ref.

06.4 C14H30 → C8H18 + 2 C3H6 1 AO2

5.1.1.1

– – – 5.7.1.4

AO /

Spec. Ref.

06.5 add bromine (water) 1 AO1

5.7.1.4

(bromine water) changes (from allow (bromine water) 1

orange) to colourless decolourises

ignore clear

MP2 is dependent on MP1

being awarded

AO /

Spec. Ref.

06.6 polymer allow plastic 1 AO1

5.2.1.4

allow hydrocarbon 5.7.1.4

Total Question 6 10

How to answer it

Question 6: Hydrocarbons, Cracking and Polymers

What this question tests

This question checks whether you can: define a hydrocarbon, use the alkane general formula, explain fractional distillation using Figure 4, balance a cracking equation, describe the bromine water test for alkenes, and identify a polymer from its repeating unit.

Most marks come from short, accurate GCSE statements. For the separation question, you need the process in the correct order. For the cracking equation, you must get the balance right.

Overall mark focus: 10 marks

Part (a) / 06.1 — Define the term “hydrocarbon”

1 mark

✅ Correct answer

A hydrocarbon is a substance made of carbon and hydrogen atoms only.

💡 Key knowledge

  • Hydrocarbons contain only C and H.
  • They are found in crude oil and are the main fuels and feedstocks in this topic.

🧠 Exam technique

For 1 mark, keep it simple: mention carbon and hydrogen only. That is enough for full credit.

❌ Common errors

  • Saying “contains carbon and hydrogen” without saying only.
  • Including oxygen or any other element.
  • Describing a hydrocarbon as a mixture rather than a substance made of these atoms.

Part (b) / 06.2 — Formula of the alkane with 10 carbon atoms

1 mark

📐 Calculation / formula step

General formula for alkanes: CnH2n+2

  1. Substitute n = 10 .
  2. Hydrogen atoms = 2(10) + 2 = 22 .
  3. So the formula is C10H22 .

✅ Correct answer

C₁₀H₂₂

🧠 Exam technique

Always check you have the correct alkane formula pattern: CnH2n+2. The carbon number stays the same; only the hydrogen number changes.

❌ Common errors

  • Writing C10H20 or C10H18 .
  • Using the alkene formula by mistake: CnH2n .
  • Forgetting to substitute n = 10 correctly.

Part (c) / 06.3 — Explain how crude oil is separated into fractions

4 marks

✅ Correct answer

Crude oil is heated, so some of the hydrocarbons vaporise. The vapours enter a fractionating column which has a temperature gradient — it is hotter at the bottom and cooler at the top. Different hydrocarbons have different boiling points, so they condense at different heights in the column and are collected as separate fractions.

💡 Key knowledge

  • Fractional distillation separates a mixture using differences in boiling point.
  • Only some hydrocarbons vaporise at the start because crude oil contains molecules with different boiling points.
  • The column gets cooler going up.
  • Fractions with higher boiling points condense lower down.

🧠 Exam technique

Marks are awarded for the sequence:

  1. heated
  2. vapourise
  3. temperature gradient
  4. condense at different heights / boiling points

Using Figure 4, mention that the column is hot at the bottom and cooler at the top.

❌ Common errors

  • Calling it “filtering” instead of fractional distillation.
  • Saying fractions “evaporate at different heights” without mentioning condensing.
  • Forgetting the temperature gradient.
  • Not linking separation to different boiling points.
How the 4 marks were earned: one mark for heating, one for vapourisation, one for the temperature gradient, and one for fractions condensing at different heights / at their boiling points.

Part (d) / 06.4 — Balance the cracking equation

1 mark

📐 Calculation / balancing steps

  1. Start with the equation: C14H30 → C8H18 + ___ C3H6
  2. Carbon atoms: 14 on the left, 8 already on the right, so 6 carbon atoms remain.
  3. Each propene molecule has 3 carbon atoms, so 2 propene molecules are needed.
  4. Check hydrogen: 18 + 12 = 30, so it is balanced.

✅ Correct answer

C₁₄H₃₀ → C₈H₁₈ + 2C₃H₆

🧠 Exam technique

Always balance atoms on both sides. In cracking questions, the coefficient in front of the alkene is often the missing number.

❌ Common errors

  • Forgetting the 2 before C3H6 .
  • Balancing only carbon and not checking hydrogen.
  • Changing the formula of propene instead of using the correct molecule.
Why this is full marks: there is only one missing coefficient, and the completed equation must conserve both atoms exactly.

Part (e) / 06.5 — Describe the test for alkenes

2 marks

✅ Correct answer

Test: Add bromine water to the sample.

Result: Bromine water changes from orange to colourless (decolourises).

💡 Key knowledge

  • Alkenes contain a carbon-carbon double bond.
  • Bromine water is used to identify unsaturation.
  • Positive test = decolourisation.

🧠 Exam technique

For 2 marks, give both parts:

  1. The test — bromine water.
  2. The observation — orange to colourless.

“Turns clear” may be accepted, but colourless is the safest exam wording.

❌ Common errors

  • Saying “add bromine” without mentioning bromine water.
  • Writing “turns blue-black” — that is the starch test, not alkenes.
  • Forgetting to state the colour change.

Part (f) / 06.6 — What type of substance is poly(propene)?

1 mark

✅ Correct answer

Polymer

💡 Key knowledge

  • Poly(propene) is made of many repeating units joined together.
  • Substances like this are called polymers.
  • GCSE answers may also allow plastic.

🧠 Exam technique

If you see brackets and an n in the structure, that usually means a repeating unit, so the substance is a polymer.

❌ Common errors

  • Calling it a monomer — propene is the monomer, poly(propene) is the polymer.
  • Giving a vague answer like “compound” or “molecule”.
Examiner note: top responses identify the repeating pattern and name the substance type directly as polymer.

Quick revision summary

💡 Key facts to remember

  • Hydrocarbon = carbon and hydrogen only.
  • Alkane formula = CnH2n+2.
  • Fractional distillation separates crude oil by boiling point.
  • Cracking makes smaller molecules, often an alkane + alkene.
  • Bromine water tests for alkenes: orange → colourless.
  • Poly(propene) is a polymer.

🧠 How to score well

  • Use exact science words: vapourise, condense, boiling point, polymer.
  • For any process, write the steps in the correct order.
  • For equations, always check both sides balance.

Topics

Chemistry · C7: Organic Chemistry · C8: Chemical Analysis

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 2 (Foundation), 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.