AQA GCSE Combined Science: Trilogy Chemistry Paper 2 (Foundation), June 2025: Question 6

14 marks · Standard Demand difficulty · Extended Answer

Describe the test for oxygen, explain how the Earth's atmosphere evolved from early times to today, and describe the production, effects, and reduction of methane and sulfur dioxide emissions.

Practise this question

Question

Question 6 comprises multiple parts about atmospheric chemistry. Part 06.1 asks for the test and result for oxygen gas. Part 06.2 provides Table 5 comparing the percentage of carbon dioxide (95% to 0.04%), nitrogen (3% to 78.0%), and oxygen (less than 1% to 21.0%) between the early atmosphere and today, asking for a 6-mark explanation of how these changed. Part 06.3 asks for two ways to reduce methane emissions. Parts 06.4 to 06.6 ask how sulfur dioxide emissions are produced, one harmful effect of sulfur dioxide, and one reason why atmospheric sulfur dioxide has decreased since 1980.
Question text

06 The proportions of most gases in the Earth’s atmosphere have not changed much

for the past 200 million years.

06.1 About one-fifth of the atmosphere is oxygen.

Describe the test for oxygen gas.

Give the result of the test.

[2 marks]

Test

Result

06.2 Table 5 shows the percentages of some gases in the Earth’s early atmosphere and in

the Earth’s atmosphere today.

Table 5

Percentage (%) of gas in the atmosphere

Earth’s early Earth’s atmosphere

Gas

atmosphere today

Carbon dioxide 95 0.04

Nitrogen 3 78.0

Oxygen Less than 125 21.0

Explain how the percentages of gases have changed from Earth’s early atmosphere

to Earth’s atmosphere today.

You should refer to all three gases in Table 5.

[6 marks]

Extra space

06.3 Methane is a greenhouse gas.

Give two ways to reduce methane emissions into the atmosphere.

[2 marks]

The percentage of sulfur dioxide in the Earth’s atmosphere increased between

*25*1850 and 1980.

06.4 Describe how sulfur dioxide emissions are produced.

[2 marks]

06.5 Give one harmful effect of sulfur dioxide emissions.

[1 mark]

06.6 Suggest one reason why the percentage of sulfur dioxide in the Earth’s atmosphere

has decreased since 1980.

[1 mark]

Mark scheme

Show the mark scheme Mark scheme for Question 6 providing criteria across 14 marks. 06.1 accepts 'glowing splint' and 'relights'. 06.2 gives a 3-level mark scheme up to 6 marks for explaining decreases in carbon dioxide (ocean dissolution, sediments, photosynthesis, fossil fuels) and increases in nitrogen and oxygen (photosynthesis, volcanic activity/bacteria). 06.3 gives 2 marks for methane reduction methods such as reducing livestock or landfill waste. 06.4 gives 2 marks for burning sulfur-containing fuels and sulfur reacting with oxygen. 06.5 gives 1 mark for respiratory problems or acid rain. 06.6 gives 1 mark for reduced use of sulfur-containing fossil fuels, sulfur removal, or legislation.

Question 6

AO /

Question Answers Extra information Mark

Spec. Ref.

06.1 (test) AO1

glowing splint do not accept burning / lit splint 1 5.8.2.2

(result)

relights allow glows more brightly 1

MP2 is dependent upon MP1

– being awarded – –

AO /

Question Answers Mark

Spec. Ref.

06.2 Level 3: Relevant points (reasons / causes) are identified, given in 5–6 AO1

detail and logically linked to form a clear account.

Level 2: Relevant points (reasons / causes) are identified, and 3–4 AO1

there are attempts at logical linking. The resulting account is not

fully clear.

Level 1: Points are identified and stated simply, but their relevance 1–2 AO3

is not clear and there is no attempt at logical linking.

5.9.1.1

No relevant content 0 5.9.1.2

5.9.1.3

5.9.1.4

Indicative content

• the percentage of carbon dioxide has decreased

o (because) carbon dioxide dissolved in the oceans

o forming sediments

o (because) algae / plants

o photosynthesised

o by the formation of sedimentary rocks

o by the formation of fossil fuels

• the percentage of nitrogen has increased

o (because) volcanic activity produced nitrogen

o denitrifying bacteria released nitrogen

• the percentage of oxygen has increased

o (because) algae / plants

o photosynthesised

for Level 3 answers must include each of the gases with an

explanation for different gases– – –

AO /

Spec. Ref.

06.3 any two from: 2 AO1

5.9.2.2

• reduce livestock farming allow reduction of specific 5.9.2.4

animals / product

• reduce the number of rice / allow reduce area of wetlands

paddy fields

• reduce the amount of rubbish allow recycle more (so less

going to landfill rubbish to landfill)

• use methane from landfill as

an energy source

• reduce fossil fuel use

• reduce the destruction of peat

bogs

AO /

Spec. Ref.

06.4 fossil fuels (containing sulfur) allow fuels containing sulfur are 1 AO1

are burnt burnt 5.9.3.1

sulfur reacts with oxygen (to

produce sulfur dioxide)

AO /

Spec. Ref.

06.5 any one from: 1 AO1

5.9.3.2

• respiratory problems

• acid rain allow immediate consequence

– of acid rain – –

AO /

Spec. Ref.

06.6 allow any named fossil fuel AO3

5.9.3.1

any one from: 1

• less use of fossil fuels allow less use of fuels

(containing sulfur) containing sulfur

allow increased use of

renewable energy

allow increased use of electric

vehicles

• sulfur is removed from fossil

fuels (before burning)

• sulfur dioxide is removed from

waste gases (after burning)

• new legislation / regulations

(since 1980)

Total Question 6 14

How to answer it

Earth's Atmosphere: Evolution, Gas Tests & Atmospheric Pollutants

📌 What This Question Tests

This question assesses core recall, data analysis, and extended explanations from AQA GCSE Chemistry / Combined Science Topic 9 (Chemistry of the Atmosphere):

  • Identifying the chemical qualitative test and positive result for oxygen gas.
  • Explaining the evolution of the Earth's atmosphere (how carbon dioxide decreased, and nitrogen and oxygen increased).
  • Human activities contributing to methane emissions and how to reduce them.
  • Origins, atmospheric consequences, and mitigation strategies for sulfur dioxide (SO₂) pollution.

Part 06.1: Testing for Oxygen Gas

[2 Marks]

✅ Correct Answer

  • Test: Insert a glowing splint into the gas. [1 mark]
  • Result: The splint relights (or burns brightly). [1 mark]

🧠 Exam Technique

The second mark is strictly dependent on getting the test right. If you write "lit splint", you score 0 for the entire question because a lit splint will already be burning, so "relights" makes no chemical sense.

❌ Common Errors

  • Writing "lit splint" or "burning splint" — that is the test for hydrogen (squeaky pop).
  • Confusing the results: stating "turns cloudy" (limewater test for CO₂) or "bleaches damp litmus" (chlorine test).

Part 06.2: Evolution of Earth's Atmosphere

[6 Marks] — Extended Writing (Level of Response)

💡 Core Chemistry: How Atmospheric Gases Changed

  • Carbon Dioxide (CO₂) decreased from ~95% to 0.04%:
    • Oceans condensed and dissolved large amounts of CO₂.
    • Dissolved CO₂ reacted to form insoluble carbonate precipitates (marine sedimentary rocks, e.g. limestone / CaCO₃).
    • Primitive photosynthetic organisms (algae and green plants) absorbed CO₂ for photosynthesis.
    • Dead plant and animal matter became trapped and locked up under pressure as fossil fuels (coal, crude oil, gas).
  • Oxygen (O₂) increased from <1% to 21%:
    • Produced by algae (~2.7 billion years ago) and subsequent plants via photosynthesis:
      6CO₂ + 6H₂O → C₆H₁₂O₆ + 6O₂
  • Nitrogen (N₂) increased from 3% to 78%:
    • Released by intense volcanic activity (along with ammonia).
    • Ammonia reacted with oxygen to produce nitrogen; denitrifying bacteria also released N₂.
    • Because nitrogen is very unreactive, it gradually built up in the atmosphere over billions of years.

✅ Model Level 3 Response (5–6 Marks)

"The percentage of carbon dioxide decreased dramatically because water vapour condensed to form oceans, in which CO₂ dissolved. Algae and green plants evolved and absorbed CO₂ for photosynthesis, and marine organisms used dissolved carbonates to form shells, which became sedimentary carbonate rocks (such as limestone). Carbon was also locked up into fossil fuels."

"Oxygen increased significantly because algae and green plants produced oxygen as a waste product of photosynthesis."

"Nitrogen increased because volcanoes released nitrogen gas and ammonia over millions of years. As nitrogen is very unreactive and stable, it accumulated in the atmosphere."

🧠 Level of Response Breakdown

  • Level 3 (5–6 marks): Explains changes for all three gases (CO₂, O₂, and N₂) with clear, logically linked scientific causes.
  • Level 2 (3–4 marks): Relevant reasons given for at least two gases, but links are incomplete.
  • Level 1 (1–2 marks): Simple statements or descriptions of the data without giving scientific reasons.
Tip: Dedicate one distinct paragraph to each gas in Table 5 to ensure you hit all criteria for Level 3.

❌ Common Errors

  • Only describing the table values (e.g. "CO₂ fell by 94.96%") without explaining how or why.
  • Forgetting to explain nitrogen entirely.
  • Saying humans caused these initial changes — these historical changes occurred hundreds of millions of years before humans existed.

Part 06.3: Reducing Methane Emissions

[2 Marks]

✅ Correct Answers (Choose Any Two)

  • Reduce cattle/livestock farming (e.g. eat less beef/dairy, switch to plant-based diets). [1 mark]
  • Reduce the amount of rubbish/organic waste sent to landfill sites (e.g. recycling, composting). [1 mark]
  • Capture and burn methane from landfill sites as a fuel/energy source. [1 mark]
  • Reduce rice cultivation / reduce paddy fields / wetland flooding. [1 mark]
  • Reduce the extraction/use of fossil fuels. [1 mark]
  • Stop the destruction/draining of peat bogs. [1 mark]

🧠 Exam Technique

Make sure your answers refer specifically to methane (CH₄), not carbon dioxide. Planting trees or driving electric cars reduces CO₂, but does not directly reduce methane emissions.

❌ Common Errors

  • Vague answers like "stop pollution" or "drive less" (fossil fuels release mainly CO₂).
  • Suggesting "banning cows" instead of accepted phrasing like "reducing cattle/livestock farming" or "eating less meat".

Part 06.4: Formation of Sulfur Dioxide Emissions

[2 Marks]

✅ Correct Answer

  • Fossil fuels (such as coal or crude oil) contain sulfur impurities. [1 mark]
  • When these fuels are burned (combusted), the sulfur reacts with oxygen to form sulfur dioxide. [1 mark]
Chemical reaction: S + O₂ → SO₂

💡 Key Knowledge

Most fossil fuels (especially coal) contain sulfur as an impurity. During combustion in power stations or internal combustion engines, the sulfur is oxidised:

sulfur + oxygen → sulfur dioxide

❌ Common Errors

  • Confusing sulfur dioxide with nitrogen oxides (NOₓ). NOₓ comes from nitrogen in the air reacting at high temperatures, whereas sulfur comes directly from impurities in the fuel.
  • Failing to mention oxygen or combustion (e.g. just writing "it comes out of coal").

Parts 06.5 & 06.6: Harmful Effects & Reduction of SO₂

[1 Mark each]

✅ 06.5: One Harmful Effect [1 Mark]

  • Causes acid rain (damages trees/plants, kills aquatic life, corrodes limestone buildings and metals).
  • Causes respiratory problems / triggers asthma in humans.
Note: Do not credit global warming or ozone depletion — SO₂ is not a greenhouse gas.

✅ 06.6: Reason for Decrease Since 1980 [1 Mark]

Any one from:

  • Reduced use of fossil fuels containing sulfur (e.g. shift from coal to natural gas, nuclear, or renewables).
  • Desulfurisation: sulfur is removed from fuels before combustion (e.g. ultra-low sulfur diesel).
  • Flue-gas desulfurisation: sulfur dioxide is removed from chimney emissions using an alkali (e.g. CaO/CaCO₃) after burning.
  • Tighter government environmental legislation / Clean Air Acts.

❌ Major Misconceptions to Avoid

  • Pollutant Confusion: Never state that sulfur dioxide damages the ozone layer (CFCs do that) or causes global warming (CO₂/methane do that).
  • Vague answers for 06.6: Avoid simply saying "people cared more about the environment" — give a concrete technological, practical, or regulatory reason.

Topics

Chemistry · C8: Chemical Analysis · C9: Chemistry of the Atmosphere

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 2 (Foundation), June 2025. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.