AQA GCSE Physics Physics Paper 1 (Higher), June 2025: Question 8

11 marks · Standard Demand difficulty · Short Answer

Calculate the specific latent heat of vaporisation of liquid nitrogen and explain the changes in internal energy and gas pressure during boiling and heating.

Practise this question

Question

Question 8 includes a diagram, Figure 10, of a sealed container partially filled with liquid nitrogen. Question 8.1 asks to calculate the specific latent heat of vaporisation of nitrogen given that 9950 J of thermal energy turns 50 g of nitrogen into a gas. Question 8.2 asks to explain how the internal energy of the nitrogen changed as it turned from a liquid to a gas for 3 marks. Question 8.3 asks to explain how the pressure in the container changed as the temperature of the gas increased for 4 marks.

Mark scheme

Show the mark scheme Mark scheme for question 8 shows marking points: 08.1 gives 1 mark for converting mass m = 0.050 kg, 1 mark for substitution 9950 = 0.050 x L, 1 mark for rearranging L = 9950 / 0.050, and 1 mark for L = 199 000 J/kg. 08.2 gives 1 mark for potential energy increases, 1 mark for kinetic energy does not change, and 1 mark for internal energy increases. 08.3 gives 1 mark for kinetic energy of gas particles increased, 1 mark for particles exert greater force on the walls during each collision, 1 mark for frequency of collisions increases, and 1 mark for pressure increases. Total 11 marks.

How to answer it

Specific Latent Heat, Internal Energy & Gas Pressure

Topic 4.3: Particle Model of Matter

What this question tests

This question evaluates your ability to rearrange the specific latent heat equation including a mandatory unit conversion, explain microscopic energy changes (kinetic vs potential energy) during a phase transition, and apply kinetic theory to describe how heating a gas alters wall collision frequency, collision force, and pressure.

Question 08.1 • 4 Marks

Calculating Specific Latent Heat of Vaporisation

Quantitative Problem Solving & Unit Conversion

📐 Step-by-Step Calculation

  1. Convert mass to standard SI units (kg):
    m = 50 g ÷ 1000 = 0.050 kg [1 mark]
  2. Select equation & substitute values:
    Formula: E = m × L
    9950 = 0.050 × L [1 mark]
  3. Rearrange to solve for L:
    L = 9950 ÷ 0.050 [1 mark]
  4. Calculate final value:
    L = 199 000 J/kg (or 1.99 × 10⁵ J/kg ) [1 mark]

❌ Common Traps to Avoid

  • Forgetting mass conversion: Using 50 instead of 0.050 gives 199 J/kg . This loses the first mark (though subsequent substitution and answer marks can still be awarded via error carried forward).
  • Wrong latent heat type: Don't confuse latent heat of fusion (melting/freezing) with vaporisation (boiling/condensing).
  • Rearrangement slip: Make sure you divide energy by mass ( E / m ), never mass by energy ( m / E ).
Mark Distribution: 1 mark for mass conversion (0.050 kg), 1 mark for substitution, 1 mark for rearrangement, 1 mark for correct final answer.
Question 08.2 • 3 Marks

Internal Energy During a Change of State

Microscopic Energy Breakdown

✅ Model Answer

  • The potential energy of the particles increases. [1 mark]
  • The kinetic energy of the particles does not change (because the temperature stays constant during boiling). [1 mark]
  • Therefore, the total internal energy increases. [1 mark]

💡 Key Knowledge

Internal Energy is defined as:

Internal Energy = Total Kinetic Energy + Total Potential Energy

  • Temperature depends solely on the average kinetic energy of particles.
  • During a phase change, thermal energy supplied goes into overcoming intermolecular forces, increasing potential energy, not kinetic energy.

🧠 Exam Technique

Always break "internal energy" down into its two components: kinetic energy and potential energy. Address both separately, then state what happens to the overall internal energy.

❌ Examiner Warning

Many students incorrectly state that "kinetic energy increases because gas particles move faster than liquid particles". At boiling point, the gas and liquid are at the exact same temperature, meaning their average kinetic energy is identical! Note: Mark 3 depends entirely on getting marks 1 and 2 right.

Mark Scheme Note: MP3 ("internal energy increases") is strictly dependent on scoring both MP1 (potential energy increases) and MP2 (kinetic energy unchanged).
Question 08.3 • 4 Marks

Effect of Temperature on Gas Pressure

Kinetic Theory & Particle Collisions

✅ 4-Step Explanation (Model Answer)

  1. The mean kinetic energy (or mean speed) of the gas particles increases. [1 mark]
  2. Particles collide with the container walls with a greater force per collision. [1 mark]
  3. The frequency of collisions between particles and the walls increases (more collisions per second). [1 mark]
  4. So the overall pressure increases. [1 mark]

🧠 The Pressure Chain Formula

To score full marks on gas pressure questions, you must hit all four links in the logical chain:

Temp ↑ → Speed / KE ↑ → Harder collisions (Force ↑) + More frequent collisions → Pressure ↑

❌ Common Traps & Lost Marks

  • Vague collision language: Writing "there are more collisions" gets 0 marks. You must specify that collisions are with the walls of the container and mention the rate or frequency (collisions per second).
  • Forgetting force: Students frequently mention collision frequency but forget to mention that particles hit with greater force / momentum change.
  • Dependency condition: The final mark for "pressure increases" is dependent on scoring at least 1 of the explanation marks first.

💡 Underlying Physics

Pressure is defined as force per unit area ( P = F / A ). The total force exerted on the sealed walls increases because faster particles experience a larger change in momentum upon impact (greater force) and they reach the walls more often (higher collision frequency).

Examiner Insight: High-scoring answers clearly differentiated between particle-particle collisions (which don't cause container pressure) and particle-wall collisions.

Topics

Physics · P3: Particle Model of Matter

Question and mark scheme from the AQA GCSE Physics examination, Physics Paper 1 (Higher), June 2025. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.