OCR A-Level Chemistry Periodic table, elements and physical chemistry (01), June 2019: Question 12

1 mark · Easy difficulty · Multiple Choice

Identify the conjugate acid-base pair from the given dissociation equation of the acid H3AsO4 in water.

Practise this question

Question

Multiple choice question 12 showing the chemical equation H3AsO4 + H2O <=> H2AsO4- + H3O+. Four options A, B, C, D list pairs of chemical species: A is H3AsO4 and H2O, B is H2AsO4- and H3O+, C is H3AsO4 and H3O+, and D is H3O+ and H2O. A box labelled 'Your answer' is provided at the bottom.
Question text

12 The equation shows the dissociation of the acid H3AsO4 in water.

H AsO + H O H AsO – + H O+

34 2 2 4 3

Which pair is a conjugate acid–base pair?

A H3AsO4 and H2O

B H AsO − and H O+

24 3

C H AsO and H O+

34 3

D H O+ and H O

Your answer [1]

Mark scheme

Show the mark scheme Mark scheme for question 12 showing the correct answer is option D, worth 1 mark.

12 D 1 AO1.2

How to answer it

Identifying Conjugate Acid-Base Pairs

What this question tests

This question assesses your understanding of Bronsted-Lowry acid-base theory, specifically the ability to identify species that differ by a single proton (H⁺ ion) on opposite sides of a chemical equilibrium.

Question 12

Exam Breakdown

✅ Correct Answer

The correct option is D ( H₃O⁺ and H₂O ).

💡 Key Knowledge

  • A conjugate acid-base pair consists of two species that transform into each other by the gain or loss of a proton ( H⁺ ).
  • The acid has one more H⁺ than its conjugate base.
  • In the given equation: H₃AsO₄ + H₂O ⇌ H₂AsO₄⁻ + H₃O⁺

🧠 Exam Technique

  • Pair up species on the left with their reacting partners on the right based on structural similarity (arsenic species together, hydrogen/water species together).
  • Check the proton difference: H₃O⁺ loses an H⁺ to become H₂O . Therefore, they form a valid conjugate pair.

❌ Common Errors

  • Pairing reactants together (e.g., H₃AsO₄ and H₂O , option A) instead of matching a reactant with its corresponding product species.
  • Confusing charge balances when removing or adding a proton.
Mark Scheme Allocation: 1 mark available (AO1.2 - Demonstrate knowledge and understanding of scientific ideas). Correct option: D.

Topics

Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

Question and mark scheme from the OCR A-Level Chemistry examination, Periodic table, elements and physical chemistry (01), June 2019. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.