OCR A-Level Chemistry AS Breadth in chemistry (01), November 2021: Question 2

1 mark · Medium difficulty · Multiple Choice

Identify which bond has the correct polarity using the given Pauling electronegativity values.

Practise this question

Question

A multiple choice question providing a table of Pauling electronegativity values for boron, carbon, nitrogen, oxygen, fluorine, chlorine, bromine, and iodine. Students must choose which of the four given options (A, B, C, or D) shows a covalent bond with the correct partial charges (polarity) based on the electronegativity values.
Question text

2 Pauling electronegativity values for the halogens F to I and some elements in period 2 of the

periodic table are shown below.

B C N O F

2.04 2.55 3.04 3.44 3.98

Cl

3.16

Br

2.96

I

2.66

Which bond has the correct polarity?

A B C D

δ– N—I δ+ δ– C—F δ+ δ– B—Cl δ+ δ– Br—Cl δ+

Your answer [1]

Mark scheme

Show the mark scheme The mark scheme shows that the correct answer for question 2 is option A.

2 A 1 AO2.1

How to answer it

Evaluating Bond Polarity Using Electronegativity Values

What this question tests

This question assesses your understanding of electronegativity, how to interpret Pauling electronegativity values from a table, and how electronegativity differences determine the polarity (partial charges, delta positive δ⁺ and delta negative δ⁻ ) of covalent bonds.

Question Analysis & Answer

Multiple Choice Question 2

✅ Correct Answer: A

Option A shows δ⁻ N — I δ⁺ .

Looking up the Pauling values from the table:

  • N = 3.04
  • I = 2.66

Since nitrogen has a higher electronegativity value than iodine (3.04 > 2.66), nitrogen attracts the bonding electrons more strongly and carries the partial negative charge ( δ⁻ ), making iodine δ⁺ . This polarity is correct.

💡 Key Knowledge

  • Electronegativity is the ability of an atom to attract the bonding electrons in a covalent bond.
  • The atom with the higher electronegativity value becomes delta negative ( δ⁻ ).
  • The atom with the lower electronegativity value becomes delta positive ( δ⁺ ).

🧠 Exam Technique

  • Always look up both elements given in the options from the provided data table before making your choice.
  • Double-check the positions of the δ⁻ and δ⁺ symbols in the question options against your calculated differences.

❌ Common Errors & Why Others Are Incorrect

  • B ( δ⁻ C — F δ⁺ ): Incorrect. Fluorine is the most electronegative element (3.98) compared to Carbon (2.55). Fluorine must be δ⁻ , but the option incorrectly labels F as δ⁺ .
  • C ( δ⁻ B — Cl δ⁺ ): Incorrect. Chlorine (3.16) is more electronegative than Boron (2.04), so Cl should be δ⁻ , not B.
  • D ( δ⁻ Br — Cl δ⁺ ): Incorrect. Chlorine (3.16) is more electronegative than Bromine (2.96), so Cl should be δ⁻ , not Br.
Mark Scheme Allocation: 1 mark available for identifying option A (AO2.1 - Application of knowledge and understanding).

Topics

Module 2: Foundations in chemistry · 2.2 Electrons, bonding and structure

Question and mark scheme from the OCR A-Level Chemistry examination, AS Breadth in chemistry (01), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.