OCR A-Level Chemistry AS Breadth in chemistry (01), November 2021: Question 2
1 mark · Medium difficulty · Multiple Choice
Identify which bond has the correct polarity using the given Pauling electronegativity values.
Practise this questionQuestion
Question text
2 Pauling electronegativity values for the halogens F to I and some elements in period 2 of the
periodic table are shown below.
B C N O F
2.04 2.55 3.04 3.44 3.98
Cl
3.16
Br
2.96
I
2.66
Which bond has the correct polarity?
A B C D
δ– N—I δ+ δ– C—F δ+ δ– B—Cl δ+ δ– Br—Cl δ+
Your answer [1]
Mark scheme
Show the mark scheme
2 A 1 AO2.1
How to answer it
Evaluating Bond Polarity Using Electronegativity Values
What this question tests
This question assesses your understanding of electronegativity, how to interpret Pauling electronegativity values from a table, and how electronegativity differences determine the polarity (partial charges, delta positive δ⁺ and delta negative δ⁻ ) of covalent bonds.
Multiple Choice Question 2
✅ Correct Answer: A
Option A shows δ⁻ N — I δ⁺ .
Looking up the Pauling values from the table:
- N = 3.04
- I = 2.66
Since nitrogen has a higher electronegativity value than iodine (3.04 > 2.66), nitrogen attracts the bonding electrons more strongly and carries the partial negative charge ( δ⁻ ), making iodine δ⁺ . This polarity is correct.
💡 Key Knowledge
- Electronegativity is the ability of an atom to attract the bonding electrons in a covalent bond.
- The atom with the higher electronegativity value becomes delta negative ( δ⁻ ).
- The atom with the lower electronegativity value becomes delta positive ( δ⁺ ).
🧠 Exam Technique
- Always look up both elements given in the options from the provided data table before making your choice.
- Double-check the positions of the δ⁻ and δ⁺ symbols in the question options against your calculated differences.
❌ Common Errors & Why Others Are Incorrect
- B ( δ⁻ C — F δ⁺ ): Incorrect. Fluorine is the most electronegative element (3.98) compared to Carbon (2.55). Fluorine must be δ⁻ , but the option incorrectly labels F as δ⁺ .
- C ( δ⁻ B — Cl δ⁺ ): Incorrect. Chlorine (3.16) is more electronegative than Boron (2.04), so Cl should be δ⁻ , not B.
- D ( δ⁻ Br — Cl δ⁺ ): Incorrect. Chlorine (3.16) is more electronegative than Bromine (2.96), so Cl should be δ⁻ , not Br.
Topics
Module 2: Foundations in chemistry · 2.2 Electrons, bonding and structure
Question and mark scheme from the OCR A-Level Chemistry examination, AS Breadth in chemistry (01), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.