OCR A-Level Chemistry Periodic table, elements and physical chemistry (01), June 2022

Every question from OCR A-Level Chemistry Periodic table, elements and physical chemistry (01), June 2022 (H432): 22 questions, 100 marks, each with its mark scheme and topic.

Original question paper

  1. Question 1 1 mark

    Identify the remaining silver halide precipitates after adding silver nitrate followed by excess dilute ammonia to a mixture of chloride, bromide, and iodide ions.

    Module 3: Periodic table and energy · Practical Activity Groups · 3.1 The periodic table · PAG 4: Qualitative analysis of ions

  2. Question 2 1 mark

    Identify the correct equation for the reaction of 20 cm3 of nitrogen gas with 10 cm3 of oxygen gas to form 20 cm3 of a gaseous product.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  3. Question 3 1 mark

    Identify element X given the mass of element X and the mass of its oxide X2O3 formed by reaction with oxygen

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  4. Question 4 1 mark

    Calculate the concentration of hydrogen peroxide in a disinfectant using titration data and a balanced redox equation, choosing from multiple-choice options A to D.

    Module 2: Foundations in chemistry · Practical Activity Groups · 2.1 Atoms and reactions · PAG 2: Acid-base titration

  5. Question 5 1 mark

    Determine the formula of a substance given the mass of 4 molecules.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  6. Question 6 1 mark

    Determine the number of Fe2+ and Fe3+ ions in one formula unit of Prussian blue, C18Fe7N18.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  7. Question 7 1 mark

    Calculate the enthalpy change for the combustion of methane using the provided bond enthalpies.

    Module 3: Periodic table and energy · 3.2 Physical chemistry

  8. Question 8 1 mark

    Calculate the rate constant for a first-order reaction given its half-life is 80 seconds.

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

  9. Question 9 1 mark

    Identify the equation that represents the standard enthalpy change of atomisation of bromine.

    Module 3: Periodic table and energy · Module 5: Physical chemistry and transition elements · 3.2 Physical chemistry · 5.2 Energy

  10. Question 10 1 mark

    Determine the signs of enthalpy change (ΔH) and entropy change (ΔS) for the condensation of ammonia gas.

    Module 5: Physical chemistry and transition elements · 5.2 Energy

  11. Question 11 1 mark

    Deduce the colour change when aqueous sodium hydroxide is added to an indicator solution that is already yellow, given the equilibrium HA(aq) <=> A-(aq) + H+(aq) where HA is blue and A- is yellow

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

  12. Question 12 1 mark

    Identify the Brønsted-Lowry acids in the equilibrium mixture of ammonia and water.

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

  13. Question 13 1 mark

    Determine the standard electrode potential for the redox system Cr2+(aq) + 2e– = Cr(s) using given standard electrode potentials for chromium species.

    Module 5: Physical chemistry and transition elements · 5.2 Energy

  14. Question 14 1 mark

    Identify which given chemical reactions form a product with non-polar molecules from a multiple-choice list.

    Module 2: Foundations in chemistry · 2.2 Electrons, bonding and structure

  15. Question 15 1 mark

    Identify which of the given transition metal ions contain one or more unpaired electrons.

    Module 5: Physical chemistry and transition elements · 5.3 Transition elements

  16. Question 16 10 marks

    Explain the effect of temperature on the rate of reaction using a Boltzmann distribution, determine the orders, rate equation, rate constant and units from experimental data, and suggest a two-step mechanism for a reaction.

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

  17. Question 17 14 marks

    Calculate maximum temperature change, standard enthalpy of formation, standard entropy change, enthalpy change, and feasibility of reactions involving energy changes, enthalpy, and entropy.

    Module 3: Periodic table and energy · Module 5: Physical chemistry and transition elements · 3.2 Physical chemistry · 5.2 Energy

  18. Question 18 9 marks

    Complete the first ionisation energy graph for elements He to Ne, estimate the energy required to form one Li+ ion from one Li atom in standard form to two significant figures, and explain trends in first ionisation energies across periods based on nuclear charge, shielding, and sub-shells.

    Module 2: Foundations in chemistry · Module 3: Periodic table and energy · 3.1 The periodic table · 2.1 Atoms and reactions · 2.2 Electrons, bonding and structure

  19. Question 19 14 marks

    Calculate the mass of succinic acid in a health supplement tablet using titration data, and calculate the pH and explain the action of a glycolic acid-potassium hydroxide buffer solution.

    Module 2: Foundations in chemistry · Module 5: Physical chemistry and transition elements · Practical Activity Groups · PAG 2: Acid-base titration · 5.1 Rates, equilibrium and pH · 2.1 Atoms and reactions

  20. Question 20 8 marks

    Calculate the equilibrium constant Kc for the Haber process and explain the compromise conditions, and determine the effect of temperature and pressure on iron oxide reduction equilibria

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

  21. Question 21 14 marks

    Analyze Group 2 reactions and compounds involving magnesium, barium oxide, and calcium minerals through observations, half-equations, calculations of mass, ionic equations, and reaction equations.

    Module 3: Periodic table and energy · Module 2: Foundations in chemistry · Module 5: Physical chemistry and transition elements · 3.1 The periodic table · 2.1 Atoms and reactions · 5.1 Rates, equilibrium and pH

  22. Question 22 16 marks

    Determine the formulae, structures, ionic equations, and explanations related to transition metal complexes of iron and copper, including isomerism, redox potentials, and stoichiometry.

    Module 5: Physical chemistry and transition elements · Module 3: Periodic table and energy · 5.3 Transition elements · 3.1 The periodic table

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