OCR A-Level Chemistry Synthesis and analytical techniques (02), June 2023: Question 3

1 mark · Easy difficulty · Multiple Choice

Identify the general formula of the alkynes homologous series given propyne as an example.

Practise this question

Question

Multiple choice question 3 asking for the general formula of the alkynes homologous series, with options A (CnH2n-4), B (CnH2n-2), C (CnH2n), and D (CnH2n+2).
Question text

3 Propyne, CH3C≡CH, is a member of the alkynes homologous series with the C≡C functional group.

What is the general formula of the alkynes?

A CnH2n–4

B CnH2n–2

C CnH2n

D CnH2n+2

Your answer

[1]

Mark scheme

Show the mark scheme Mark scheme indicating the correct answer is B.

3 B 1 AO2.1

How to answer it

General Formula of Alkynes

What this question tests

This question assesses your understanding of homologous series in organic chemistry, specifically your ability to deduce or recall the general formula for unsaturated hydrocarbons containing a triple carbon-carbon bond (alkynes) by analysing molecular structures.

Question 3 (Multiple Choice)

Determining the General Formula

✅ Correct Answer

Option B: CnH₂ₙ₋₂

Alkynes contain one triple bond. Each triple bond introduces an additional ring or degree of unsaturation compared to alkenes, removing two more hydrogen atoms.

💡 Key Knowledge

  • Alkanes (saturated): CnH₂ₙ₊₂
  • Alkenes (one double bond) / Cycloalkanes: CnH₂ₙ
  • Alkynes (one triple bond) / Dienes: CnH₂ₙ₋₂

🧠 Exam Technique

If you ever forget a general formula under exam pressure, plug in a real example from the stem! Propyne is given as CH₃C≡CH , which has 3 carbons ( n = 3 ) and 4 hydrogens ( H = 4 ). Test the options:

  • A: 2(3) - 4 = 2
  • B: 2(3) - 2 = 4 (Matches!)
  • C: 2(3) = 6

❌ Common Errors

Students often confuse the degree of unsaturation for double vs. triple bonds. A common mistake is selecting CnH₂ₙ (confusing alkynes with alkenes) or guessing CnH₂ₙ₋₄ by overestimating the hydrogen loss.

Mark Scheme Allocation: 1 mark awarded for selecting B (AO2.1 - Applying chemical knowledge to identify homologous series formulas).

Topics

Module 4: Core organic chemistry · 4.1 Basic concepts and hydrocarbons

Question and mark scheme from the OCR A-Level Chemistry examination, Synthesis and analytical techniques (02), June 2023. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.