AQA GCSE Chemistry Chemistry Paper 1 (Higher), November 2020: Question 5

8 marks · Standard Demand difficulty · Short Answer

Answer questions on the development of the atomic model and Mendeleev's periodic table using a timeline of scientific discoveries.

Practise this question

Question

Question 5 shows a timeline from 1890 to 1940 detailing key atomic discoveries: electrons discovered, plum pudding model, alpha particle scattering experiment and nuclear model, Bohr model, protons discovered (circa 1920), and neutrons discovered (circa 1932). Question 5.1 asks for three differences between the nuclear model and the plum pudding model. Question 5.2 asks to describe Bohr's adaptation to the nuclear model. Question 5.3 states Mendeleev published his periodic table in 1869 in order of atomic weight and asks to explain using the timeline why a student is incorrect that Mendeleev reversed elements by atomic number. Question 5.4 asks for the correct reason Mendeleev reversed the order of some pairs of elements.
Question text

05 This question is about the development of scientific theories.

Figure 2 shows a timeline of some important steps in the development of the

model of the atom.

Figure 2

05.1 The plum pudding model did not have a nucleus.

Describe three other differences between the nuclear model of the atom and

the plum pudding model.

[3 marks]

05.2 Niels Bohr adapted the nuclear model.

Describe the change that Bohr made to the nuclear model.

[2 marks]

05.3 Mendeleev published his periodic table in 1869.

Mendeleev arranged the elements in order of atomic weight.

Mendeleev then reversed the order of some pairs of elements.

A student suggested Mendeleev’s reason for reversing the order was to arrange

the elements in order of atomic number.

Explain why the student’s suggestion cannot be correct.

Use Figure 2.

[2 marks]

05.4 Give the correct reason why Mendeleev reversed the order of some pairs of elements.

[1 mark]

Mark scheme

Show the mark scheme Mark scheme for Question 5 lists: 05.1 awards 3 marks for any three of: mostly empty space, positive charge concentrated in the nucleus, mass concentrated in the nucleus, electrons and nucleus are separate. 05.2 awards 2 marks for stating electrons orbit the nucleus at specific distances/energy levels/shells. 05.3 awards 2 marks for explaining atomic number is the number of protons and protons were not discovered until later (around 1920). 05.4 awards 1 mark for so that elements' properties matched the rest of their group.

Question 5

AO /

Question Answers Extra information Mark

Spec. Ref.

05.1 any three from: 3 AO1

(nuclear model) 4.1.1.3

• mostly empty space allow the plum pudding model

has no empty space

allow the plum pudding model is

solid

• the positive charge is (all) in allow in the plum pudding model

the nucleus the atom is a ball of positive

charge (with embedded

electrons)

do not accept reference to

protons

• the mass is concentrated in allow in the plum pudding model

the nucleus the mass is spread out

do not accept reference to

neutrons

• the electrons and the nucleus allow in the plum pudding model

are separate the electrons are embedded

allow in the nuclear model the

electrons are in orbits

05.2 do not accept reference to AO1

protons / neutrons 4.1.1.3

electrons orbit the nucleus allow electrons are in energy 1

levels around the nucleus

or

allow electrons are in shells

around the nucleus

electrons are at specific 1

distances from the nucleus

05.3 atomic number is the number of 1 AO3

protons 4.1.1.3

4.1.1.4

(and) protons were not ignore electrons / neutrons were 1 4.1.2.2

discovered until later not discovered until later

Question 5 continued15

AO /

Spec. Ref.

05.4 so their properties matched the allow converse 1 AO1

rest of the group 4.1.2.2

Total 8

How to answer it

Development of Atomic Models & Mendeleev's Periodic Table

📌 What this question tests

Specification links: AQA Chemistry 4.1.1.3 (History of the Atom) & 4.1.2.2 (Development of the Periodic Table)

  • Contrasting the plum pudding model with Rutherford's nuclear model.
  • Recalling Niels Bohr's adaptation regarding electron orbits and energy levels.
  • Interpreting a timeline to explain historical context (atomic number vs atomic weight).
  • Explaining why Mendeleev swapped certain pairs of elements (chemical properties & periodic trends).
Question 05.1 • 3 Marks

Differences Between the Plum Pudding and Nuclear Models

The plum pudding model did not have a nucleus. Describe three other differences between the nuclear model of the atom and the plum pudding model.

✅ Correct Answers (Any 3)

  • Empty space: The nuclear model is mostly empty space (plum pudding model has no empty space / is solid).
  • Distribution of charge: In the nuclear model, the positive charge is concentrated in the nucleus (plum pudding is a single sphere of diffuse positive charge).
  • Distribution of mass: In the nuclear model, mass is concentrated in the nucleus (plum pudding mass is spread out evenly).
  • Position of electrons: In the nuclear model, electrons orbit outside the nucleus (in the plum pudding model, electrons are embedded inside the sphere of charge).

🧠 Exam Technique

The question says: "The plum pudding model did not have a nucleus. Describe three other differences..."

  • Never state: "The nuclear model has a nucleus" — the question explicitly excluded this point!
  • Structure each point by comparing space, mass, or charge location.

❌ Common Errors & Historical Traps

  • Naming subatomic particles too early: Do not mention protons or neutrons . As shown on the timeline, protons (1920) and neutrons (1932) were discovered after the nuclear model (1911).
  • Only describing one model without indicating a comparative difference.

💡 Visualizing the Two Models

Plum Pudding (Thomson, 1897): Solid ball of positive charge with negatively charged electrons embedded like raisins in a pudding.

Nuclear Model (Rutherford, 1911): Tiny, dense, positive central nucleus holding nearly all mass, with electrons moving in mostly empty surrounding space.

Mark breakdown: 1 mark per valid comparative point (up to 3 max).
Question 05.2 • 2 Marks

Bohr's Adaptation to the Nuclear Model

Niels Bohr adapted the nuclear model. Describe the change that Bohr made to the nuclear model.

✅ Correct Answer

  • Electrons orbit the nucleus / are in shells / are in energy levels around the nucleus. [1 mark]
  • Electrons are at specific distances (fixed orbits/energy levels) from the nucleus. [1 mark]

🧠 Exam Technique: Two-Mark Breakdown

Many students only write "he added shells" and gain just 1 mark. To secure both marks:

  1. State where the electrons are (orbiting in shells/energy levels).
  2. State that these levels are at fixed / specific distances.

❌ Common Misconceptions

  • Do not write that Bohr discovered protons or neutrons.
  • Do not confuse Bohr's shells with Rutherford's random orbits. Bohr's key insight was quantised energy levels (fixed distances).
Mark breakdown: 1 mark for electrons in shells/orbits around the nucleus; 1 mark for specific/fixed distances.
Question 05.3 • 2 Marks

Mendeleev and Atomic Number

Mendeleev published his periodic table in 1869 in order of atomic weight, then reversed some pairs. Explain why a student's suggestion that he did this "to arrange them by atomic number" cannot be correct. Use Figure 2.

✅ Correct Answer

  • Atomic number is the number of protons. [1 mark]
  • Protons were not discovered until much later (around 1920, well after 1869). [1 mark]

🧠 Exam Technique: Using Timeline Evidence

When an exam question says "Use Figure 2", actively check the dates:

  • Mendeleev published: 1869 (stated in the question stem).
  • Figure 2 shows protons discovered: c. 1920.
  • Therefore, Mendeleev could not possibly know about atomic numbers because protons didn't exist in science yet!

❌ Common Errors

  • Saying "electrons / neutrons were not discovered yet" does not get credit. Atomic number specifically depends on protons.
  • Failing to link the term "atomic number" to the definition "number of protons".
Mark breakdown: 1 mark for defining atomic number as proton number; 1 mark for stating protons had not yet been discovered.
Question 05.4 • 1 Mark

Why Mendeleev Reversed Element Pairs

Give the correct reason why Mendeleev reversed the order of some pairs of elements.

✅ Correct Answer

So that their properties matched the rest of the group / to fit the pattern of chemical reactions and properties. [1 mark]

💡 Famous Example: Iodine and Tellurium

Tellurium (atomic weight 128) has a higher atomic weight than Iodine (atomic weight 127). If placed purely by atomic weight, Iodine would sit in Group 6 and Tellurium in Group 7.

Mendeleev swapped them so that iodine lined up with fluorine, chlorine, and bromine (Group 7 halogens), matching their chemical properties!

🧠 Top Tip

Always mention properties and groups together. For example: "To place elements with similar chemical properties in the same vertical column (group)."

Mark breakdown: 1 mark for matching properties to the rest of the group.

Topics

Chemistry · C1: Atomic Structure and the Periodic Table

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Higher), November 2020. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.