AQA GCSE Chemistry Chemistry Paper 2 (Foundation), November 2020: Question 2

8 marks · Low Demand difficulty · Short Answer

Answer questions on atmospheric pollution, including the effects of acid rain and soot, incomplete combustion, balancing an equation, and formation of oxides of nitrogen in car engines.

Practise this question

Question

The question presents Figure 3, a photograph of a damaged limestone carving showing areas blackened by soot and eroded by atmospheric pollutants. Question 02.1 asks candidates to select what reacted with limestone to cause erosion from four options: Acid rain, Ammonia, Carbon monoxide, and Oxygen. Question 02.2 requires completing two sentences about incomplete combustion using words from a box containing ammonia, carbon, methane, nitrogen, and oxygen. Question 02.3 asks to complete a sentence stating that particles of soot cause global dimming. Question 02.4 asks to balance the chemical equation: 2 CH4 + 3 O2 arrow blank CO + 4 H2O. Question 02.5 requires completing three sentences about nitrogen in car engines using words from a box containing air, methane, oxides of nitrogen, oxygen, petrol, and sulfur dioxide.
Question text

02 This question is about atmospheric pollution.

Figure 3 shows a limestone carving which has been damaged by

atmospheric pollution.

The carving has been:

• blackened by soot

• eroded where the limestone has reacted with atmospheric pollutants.

Figure 3

02.1 What reacted with the limestone to cause the erosion?

[1 mark]

Tick ( ) one box.

Acid rain

Ammonia

Carbon monoxide

Oxygen 9

02.2 Soot is produced by the incomplete combustion of diesel oil.

Complete the sentences.

Choose answers from the box.

[2 marks]

*08* ammonia carbon methane

nitrogen oxygen

Incomplete combustion happens when there is not enough .

Incomplete combustion produces particles of .

02.3 Complete the sentence.

[1 mark]

Particles of soot in the atmosphere cause global .

02.4 Carbon monoxide is produced by the incomplete combustion of methane.

Balance the equation for the reaction.

[1 mark]

2 CH + 3 O →10 … CO + 4 H O

42 2

02.5 Car engines work at high temperatures.

Complete the sentences.

Choose answers from the box.

[3 marks]

air methane oxides of nitrogen

oxygen petrol sulfur dioxide

In car engines, nitrogen is present.

The nitrogen in car engines comes from .

At high temperatures, the nitrogen reacts with .

This reaction produces .

Mark scheme

Show the mark scheme Mark scheme for Question 2 detailing answers and marks: 02.1 requires 'acid rain' for 1 mark (AO1 4.9.3.2). 02.2 requires 'oxygen' then 'carbon' in that order for 2 marks (AO1 4.9.3.1). 02.3 requires 'dimming' for 1 mark (AO1 4.9.3.1/4.9.3.2). 02.4 requires coefficient '2' in front of CO, allowing multiples, for 1 mark (AO2 4.3.1.1/4.9.3.1). 02.5 requires 'air', 'oxygen', and 'oxides of nitrogen' in that order for 3 marks (AO1 4.9.3.1). Total marks: 8.

Question 2

AO /

Question Answers Extra information Mark

Spec. Ref.

02.1 acid rain 1 AO1

4.9.3.2

must be in this order

02.2 oxygen 1 AO1

4.9.3.1

carbon 1

02.3 dimming 1 AO1

4.9.3.1

4.9.3.2

02.4 2 CH4 + 3 O2 → 2 CO + 4 H2O allow multiples 1 AO2

4.3.1.1

4.9.3.1

must be in this order

02.5 air 1 AO1

4.9.3.1

oxygen 1

oxides of nitrogen 1

Total 8

How to answer it

Atmospheric Pollutants & Combustion

📋 What this question tests

This 8-mark question tests your recall and core understanding of atmospheric chemistry (AQA Specification 4.9.3 & 4.3.1):

  • The cause and effect of acid rain on carbonate rock (limestone).
  • Conditions leading to incomplete combustion and its particulate product (soot / carbon).
  • The environmental consequence of particulates (global dimming).
  • Balancing a simple symbol equation for incomplete combustion.
  • How oxides of nitrogen form inside vehicle engines from atmospheric gases.
Question 02.1 · 1 Mark

Erosion of Limestone by Pollutants

Identifying the atmospheric pollutant responsible for chemical erosion

✅ Correct Answer

Acid rain [1 mark]

💡 Key Knowledge

Limestone is primarily calcium carbonate (CaCO₃). Acids react with metal carbonates to produce a salt, water, and carbon dioxide gas:

Acid + Carbonate → Salt + H₂O + CO₂

This neutralisation reaction dissolves and chemically erodes the stone over time.

❌ Common Errors

  • Choosing carbon monoxide: CO is toxic to humans, but it does not dissolve rock.
  • Choosing ammonia: NH₃ is alkaline, not acidic.

🧠 Exam Technique

Notice the prompt specifically says "eroded where the limestone has reacted". Only an acid reacts readily with carbonate rocks to dissolve them.

Mark Scheme: Acid rain = 1 mark (AO1, Spec 4.9.3.2)
Question 02.2 · 2 Marks

Incomplete Combustion & Soot Formation

Completing fill-in-the-blank sentences from a provided word bank

✅ Correct Answers

Incomplete combustion happens when there is not enough oxygen. [1 mark]

Incomplete combustion produces particles of carbon. [1 mark]

(Must be in this exact order)

💡 Key Knowledge

  • Complete combustion: Fuel + plenty of O₂ → CO₂ + H₂O
  • Incomplete combustion: Fuel + limited O₂ → CO (carbon monoxide) and/or solid C (carbon particulates / soot) + H₂O
  • Soot is unburnt elemental carbon.

❌ Common Errors

  • Swapping the two words around (putting carbon first, then oxygen).
  • Writing "methane" or "nitrogen" instead of oxygen. Read the sentence meaning carefully before choosing.

🧠 Exam Technique

Always cross off words from the provided word box once you use them. Make sure the word makes chemical sense in the sentence.

Mark Scheme: 1st blank = oxygen (1 mark); 2nd blank = carbon (1 mark). Must be in this order (AO1, Spec 4.9.3.1).
Question 02.3 · 1 Mark

Environmental Effect of Particulates

Sentence completion: The environmental impact of soot

✅ Correct Answer

Particles of soot in the atmosphere cause global dimming. [1 mark]

💡 Key Knowledge

Carbon particulates reflect sunlight back into space and help produce more clouds, which also reflect sunlight. This reduces the amount of sunlight reaching the Earth's surface — a phenomenon called global dimming.

❌ Common Misconceptions

  • Writing warming: Greenhouse gases (CO₂, CH₄, H₂O vapour) cause global warming, not particulates.
  • Writing cooling: Although it reduces sunlight, the specific syllabus term tested here is dimming.

🧠 Exam Technique

Pair the pollutant with its consequence:

  • Soot / particulates → Global dimming & respiratory problems
  • CO₂ / CH₄ → Global warming (climate change)
  • SO₂ / NOₓ → Acid rain
Mark Scheme: dimming = 1 mark (AO1, Spec 4.9.3.1 / 4.9.3.2)
Question 02.4 · 1 Mark

Balancing an Equation for Incomplete Combustion

Finding the missing stoichiometric coefficient

📐 Step-by-Step Balancing

Equation to balance:
2 CH₄ + 3 O₂ → ___ CO + 4 H₂O

  1. Count Carbon (C) atoms on left:
    2 CH₄ has 2 × 1 = 2 Carbon atoms.
  2. Balance Carbon on right:
    To get 2 Carbon atoms on the right, the coefficient in front of CO must be 2.
  3. Check Oxygen (O) balance:
    Left: 3 O₂ = 6 Oxygen atoms.
    Right: 2 CO (2 O) + 4 H₂O (4 O) = 6 Oxygen atoms. Perfectly balanced!

✅ Correct Answer

Missing number: 2 [1 mark]

2 CH₄ + 3 O₂ → 2 CO + 4 H₂O

❌ Common Errors

  • Leaving the space blank (thinking a coefficient of 1 is needed).
  • Writing numbers other than 2 because of forgetting to multiply the front coefficient by the subscript in 2 CH₄.

🧠 Exam Technique

Notice that only one blank is provided. All other species already have coefficients. Focus directly on the single element in that molecule (here, Carbon) to find the answer immediately.

Mark Scheme: 2 (or allowed multiples if all other coefficients are multiplied proportionally) = 1 mark (AO2, Spec 4.3.1.1 / 4.9.3.1)
Question 02.5 · 3 Marks

Formation of Oxides of Nitrogen in Car Engines

Completing sentences from a word bank

✅ Correct Answers

1. The nitrogen in car engines comes from air. [1 mark]

2. At high temperatures, the nitrogen reacts with oxygen. [1 mark]

3. This reaction produces oxides of nitrogen. [1 mark]

(Must be in this exact order)

💡 Key Knowledge

  • Nitrogen gas (N₂) is usually unreactive because of its strong triple covalent bond.
  • Inside internal combustion engines, extremely high temperatures provide the energy needed for N₂ from the air to react with O₂ from the air.
  • The products are various oxides of nitrogen (NO and NO₂), usually written as NOₓ.

❌ Common Errors

  • Saying nitrogen comes from petrol or diesel: Hydrocarbon fuels contain hydrogen and carbon (and trace sulfur impurities), but the nitrogen entering the engine comes directly from the sucked-in air.
  • Saying the reaction produces sulfur dioxide: Sulfur dioxide is formed from sulfur impurities in the fuel reacting with oxygen, not from nitrogen.

🧠 Exam Technique

Read the clues in the sentence: "nitrogen reacts with [___]" → to make an oxide, it must react with oxygen. Then, combine the names: nitrogen + oxygen = oxides of nitrogen.

Mark Scheme: 1st blank = air; 2nd blank = oxygen; 3rd blank = oxides of nitrogen. Must be in this order. 1 mark each (AO1, Spec 4.9.3.1).

Topics

Chemistry · C3: Quantitative Chemistry · C9: Chemistry of the Atmosphere

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), November 2020. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.