AQA GCSE Chemistry Chemistry Paper 1 (Foundation), November 2021: Question 5

10 marks · Low Demand difficulty · Extended Answer

Identify acid-base properties, balance a neutralisation equation, and describe the method to carry out an acid-alkali titration using given equipment.

Practise this question

Question

Question 05 consists of six parts about acids, alkalis, and titration. Part 05.1 asks which ion acids produce in aqueous solution (choices: H+, OH-, O2-). Part 05.2 asks for the name of the reaction between acids and alkalis (choices: Decomposition, Electrolysis, Neutralisation, Redox). Part 05.3 asks to balance the equation: H2SO4 + ___ KOH -> K2SO4 + ___ H2O. Part 05.4 states that universal indicator turns purple in potassium hydroxide and asks for the pH (choices: 1, 4, 7, 14). Figure 7 shows diagrams of equipment: a measuring cylinder containing potassium hydroxide solution, an empty conical flask, a dropping bottle labelled indicator, and a burette filled with sulfuric acid. Part 05.5 asks which piece of equipment could measure the 25 cm3 of potassium hydroxide more accurately (choices: Beaker, Evaporating basin, Pipette, Test tube). Part 05.6 provides answer lines for a 5-mark question asking to describe how the student would use the equipment in Figure 7 to complete the titration.
Question text

05 This question is about acids and alkalis.

05.1 Which ion do acids produce in aqueous solution?

[1 mark]

Tick ( ) one box.

H+ OH– O2–

05.2 Acids react with alkalis.

What is the name of this type of reaction?

[1 mark]

Tick ( ) one box.

Decomposition

Electrolysis

Neutralisation

Redox

05.3 Balance the equation for the reaction between sulfuric acid and potassium hydroxide.

[1 mark]

H2SO4 + … KOH → K2SO4 + … H2O

05.4 Universal indicator turns purple in potassium hydroxide solution.

What is the pH of the solution?

[1 mark]

Tick ( ) one box.

14 20 7 14

A student does a titration to find the volume of sulfuric acid that reacts with 25 cm3 of

potassium hydroxide solution.

Figure 7 shows the equipment used.

Figure 7

05.5 The 25 cm3 of potassium hydroxide solution is measured with the measuring cylinder.

Which piece of equipment could the student use to measure the 25 cm3 of

potassium hydroxide solution more accurately?

[1 mark]

Tick ( ) one box.

Beaker

Evaporating basin

Pipette

Test tube 21

05.6 Describe how the student would use the equipment in Figure 7 to

complete the titration.

[5 marks]

Mark scheme

Show the mark scheme Mark scheme for Question 5 showing marking criteria and AO/Spec references: 05.1 accepts H+ (1 mark, AO1, 4.4.2.4). 05.2 accepts neutralisation (1 mark, AO1, 4.4.2.2/4.4.2.4). 05.3 accepts balancing coefficients 2 KOH and 2 H2O, allowing multiples (1 mark, AO2, 4.1.1.1/4.4.2.2/4.4.2.4). 05.4 accepts 14 (1 mark, AO1, 4.4.2.4). 05.5 accepts pipette (1 mark, AO3, 4.4.2.5, RPA2). 05.6 awards up to 5 marks (AO1, 4.4.2.5, RPA2) for: adding potassium hydroxide to the conical flask; adding a few drops of indicator; adding sulfuric acid from the burette; continuing until the indicator changes colour; and reading the volume from the burette.

Question 5

AO /

Question Answers Extra information Mark

Spec. Ref.

05.1 H+ 1 AO1

4.4.2.4

AO /

Spec. Ref.

05.2 neutralisation 1 AO1

4.4.2.2

4.4.2.4

AO /

Spec. Ref.

05.3 H2SO4 + 2KOH → allow multiples 1 AO2

K2SO4 + 2H2O 4.1.1.1

4.4.2.2

4.4.2.4

AO /

Spec. Ref.

05.4 14 1 AO1

4.4.2.4

AO /

Spec. Ref.

05.5 pipette 1 AO3

4.4.2.5

RPA2

Question 5 continued

AO /

Spec. Ref.

05.6 add potassium hydroxide 1 AO1

(solution) to the (conical) flask 4.4.2.5

RPA2

add (a few drops of) indicator 1

16 add the (sulfuric) acid (from the 1

burette)

until the colour (of the indicator)

changes

read the volume from the

burette

Total 10

How to answer it

Acids, Alkalis & Titration Method

AQA GCSE Chemistry • Topic 4: Chemical Changes • Required Practical 2

What this question tests

This question assesses foundational knowledge of acids, bases, and pH, alongside the practical methodology for a neutralisation titration (Required Practical 2). Key skills include: identifying characteristic aqueous ions, recalling reaction classifications, balancing symbol equations, selecting appropriate laboratory volumetric glassware, and ordering the procedural steps for an acid-alkali titration.

Question 05.1 • 1 Mark

Aqueous Acid Ions

Identifying the ion responsible for acidity in solution

✅ Correct Answer

H⁺ (Tick box 1)

💡 Key Knowledge

  • Acids produce hydrogen ions ( H⁺ ) in aqueous solutions.
  • Alkalis produce hydroxide ions ( OH⁻ ) in aqueous solutions.

❌ Common Errors

Confusing H⁺ with OH⁻ (alkalis) or oxide ions ( O²⁻ ).

Mark Scheme: 1 mark for ticking H⁺ . AO1 (Spec ref: 4.4.2.4).
Question 05.2 • 1 Mark

Type of Reaction

Classifying acid-alkali chemical reactions

✅ Correct Answer

Neutralisation (Tick box 3)

💡 Key Knowledge

When an acid reacts with an alkali, they neutralise each other to form a salt and water:

H⁺(aq) + OH⁻(aq) → H₂O(l)

🧠 Exam Technique

Look at the reactants: Acid + Alkali is always a neutralisation reaction at GCSE level.

Mark Scheme: 1 mark for ticking neutralisation. AO1 (Spec ref: 4.4.2.2 / 4.4.2.4).
Question 05.3 • 1 Mark

Balancing the Chemical Equation

Reaction between sulfuric acid and potassium hydroxide

📐 Step-by-Step Balancing

  1. Identify the unbalanced equation:
    H₂SO₄ + ___ KOH → K₂SO₄ + ___ H₂O
  2. Balance potassium (K):
    There are 2 potassium atoms on the right in K₂SO₄ , so you must place a 2 in front of KOH .
  3. Balance hydrogen (H) and oxygen (O):
    Left side now has 2 H (from H₂SO₄) + 2 H (from 2 KOH) = 4 H atoms.
    To get 4 H atoms on the right, place a 2 in front of H₂O (2 × 2 = 4 H).
  4. Check sulfate / oxygen:
    Sulfur: 1 on each side. Oxygen: 4 (sulfate) + 2 (hydroxide) = 6 on left; 4 (sulfate) + 2 (water) = 6 on right. Fully balanced!

✅ Correct Answer

H₂SO₄ + 2 KOH → K₂SO₄ + 2 H₂O

Both numbers must be 2.

❌ Common Errors

Writing formulas instead of balancing numbers, or forgetting to balance both sides (e.g. putting a 2 in front of KOH but leaving H₂O blank).

Mark Scheme: 1 mark for both numbers correct ( 2 and 2 ). Multiples are accepted (e.g. 2, 4, 2, 4). AO2 (Spec ref: 4.1.1.1).
Question 05.4 • 1 Mark

pH of Potassium Hydroxide

Connecting indicator colour to pH scale values

✅ Correct Answer

14 (Tick box 4)

💡 Key Knowledge

  • pH 1: Strongly acidic (Red)
  • pH 4: Weakly acidic (Orange/Yellow)
  • pH 7: Neutral (Green)
  • pH 14: Strongly alkaline (Purple)

KOH is a strong alkali, so universal indicator turns purple at pH 13–14.

❌ Common Errors

Selecting 7 (neutral) assuming the reaction has already taken place, rather than reading that this is pure potassium hydroxide solution.

Mark Scheme: 1 mark for 14. AO1 (Spec ref: 4.4.2.4).
Question 05.5 • 1 Mark

Apparatus Accuracy

Choosing the most precise equipment for a fixed volume

✅ Correct Answer

Pipette (Tick box 3)

💡 Key Knowledge

A volumetric pipette measures one fixed volume (e.g. 25.0 cm³) with high precision and low percentage uncertainty, much more accurately than a measuring cylinder or beaker.

❌ Common Errors

Selecting "Beaker" or "Test tube" — these have very poor accuracy and are not volumetric instruments.

Mark Scheme: 1 mark for pipette. AO3 (Spec ref: 4.4.2.5 / RPA 2).
Question 05.6 • 5 Marks

Titration Method (Extended Response)

Step-by-step procedure using the provided apparatus

🧠 How to Structure a 5-Mark Practical Method

Examiners award 1 mark per distinct, logical experimental step. Write your answer in sequential bullet points following the path of the liquids:

✅ Model Answer (5 Marks)

  1. Add alkali to flask: Measure 25 cm³ of potassium hydroxide solution and transfer it into the conical flask. [1 mark]
  2. Add indicator: Add a few drops of indicator (e.g. phenolphthalein / methyl orange) to the flask. [1 mark]
  3. Add acid from burette: Fill the burette with sulfuric acid and slowly add it into the conical flask (swirling continuously). [1 mark]
  4. Observe endpoint: Stop adding acid when the indicator changes colour permanently. [1 mark]
  5. Take reading: Read and record the final volume on the burette (subtract initial reading to calculate volume added). [1 mark]

❌ Common Pitfalls & Lost Marks

  • Swapping apparatus: Saying acid is measured in the cylinder and alkali goes in the burette. Look carefully at Figure 7: the cylinder has KOH and the burette contains sulfuric acid.
  • Omitting the indicator: Forgetting to state that indicator is added to the conical flask.
  • Vague endpoint: Simply saying "until it neutralises" without stating how you know (i.e. the indicator changes colour).
  • Missing the final measurement: Ending the response at the colour change without stating that the volume of acid added must be read from the burette.
Mark Scheme Breakdown:
• Mark 1: Add potassium hydroxide (solution) to the (conical) flask
• Mark 2: Add (a few drops of) indicator
• Mark 3: Add the (sulfuric) acid (from the burette)
• Mark 4: Until the colour (of the indicator) changes
• Mark 5: Read the volume from the burette
AO1 • Spec ref: 4.4.2.5 (Required Practical 2)

Topics

Chemistry · Required Practicals · C4: Chemical Changes · Required Practicals

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Foundation), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.