AQA GCSE Chemistry Chemistry Paper 1 (Foundation), November 2021: Question 5
10 marks · Low Demand difficulty · Extended Answer
Identify acid-base properties, balance a neutralisation equation, and describe the method to carry out an acid-alkali titration using given equipment.
Practise this questionQuestion
Question text
05 This question is about acids and alkalis.
05.1 Which ion do acids produce in aqueous solution?
[1 mark]
Tick ( ) one box.
H+ OH– O2–
05.2 Acids react with alkalis.
What is the name of this type of reaction?
[1 mark]
Tick ( ) one box.
Decomposition
Electrolysis
Neutralisation
Redox
05.3 Balance the equation for the reaction between sulfuric acid and potassium hydroxide.
[1 mark]
H2SO4 + … KOH → K2SO4 + … H2O
05.4 Universal indicator turns purple in potassium hydroxide solution.
What is the pH of the solution?
[1 mark]
Tick ( ) one box.
14 20 7 14
A student does a titration to find the volume of sulfuric acid that reacts with 25 cm3 of
potassium hydroxide solution.
Figure 7 shows the equipment used.
Figure 7
05.5 The 25 cm3 of potassium hydroxide solution is measured with the measuring cylinder.
Which piece of equipment could the student use to measure the 25 cm3 of
potassium hydroxide solution more accurately?
[1 mark]
Tick ( ) one box.
Beaker
Evaporating basin
Pipette
Test tube 21
05.6 Describe how the student would use the equipment in Figure 7 to
complete the titration.
[5 marks]
Mark scheme
Show the mark scheme
Question 5
AO /
Question Answers Extra information Mark
Spec. Ref.
05.1 H+ 1 AO1
4.4.2.4
AO /
Spec. Ref.
05.2 neutralisation 1 AO1
4.4.2.2
4.4.2.4
AO /
Spec. Ref.
05.3 H2SO4 + 2KOH → allow multiples 1 AO2
K2SO4 + 2H2O 4.1.1.1
4.4.2.2
4.4.2.4
AO /
Spec. Ref.
05.4 14 1 AO1
4.4.2.4
AO /
Spec. Ref.
05.5 pipette 1 AO3
4.4.2.5
RPA2
Question 5 continued
AO /
Spec. Ref.
05.6 add potassium hydroxide 1 AO1
(solution) to the (conical) flask 4.4.2.5
RPA2
add (a few drops of) indicator 1
16 add the (sulfuric) acid (from the 1
burette)
until the colour (of the indicator)
changes
read the volume from the
burette
Total 10
How to answer it
Acids, Alkalis & Titration Method
What this question tests
This question assesses foundational knowledge of acids, bases, and pH, alongside the practical methodology for a neutralisation titration (Required Practical 2). Key skills include: identifying characteristic aqueous ions, recalling reaction classifications, balancing symbol equations, selecting appropriate laboratory volumetric glassware, and ordering the procedural steps for an acid-alkali titration.
Aqueous Acid Ions
Identifying the ion responsible for acidity in solution
✅ Correct Answer
H⁺ (Tick box 1)
💡 Key Knowledge
- Acids produce hydrogen ions ( H⁺ ) in aqueous solutions.
- Alkalis produce hydroxide ions ( OH⁻ ) in aqueous solutions.
❌ Common Errors
Confusing H⁺ with OH⁻ (alkalis) or oxide ions ( O²⁻ ).
Type of Reaction
Classifying acid-alkali chemical reactions
✅ Correct Answer
Neutralisation (Tick box 3)
💡 Key Knowledge
When an acid reacts with an alkali, they neutralise each other to form a salt and water:
H⁺(aq) + OH⁻(aq) → H₂O(l)
🧠 Exam Technique
Look at the reactants: Acid + Alkali is always a neutralisation reaction at GCSE level.
Balancing the Chemical Equation
Reaction between sulfuric acid and potassium hydroxide
📐 Step-by-Step Balancing
- Identify the unbalanced equation:
H₂SO₄ + ___ KOH → K₂SO₄ + ___ H₂O - Balance potassium (K):
There are 2 potassium atoms on the right in K₂SO₄ , so you must place a 2 in front of KOH . - Balance hydrogen (H) and oxygen (O):
Left side now has 2 H (from H₂SO₄) + 2 H (from 2 KOH) = 4 H atoms.
To get 4 H atoms on the right, place a 2 in front of H₂O (2 × 2 = 4 H). - Check sulfate / oxygen:
Sulfur: 1 on each side. Oxygen: 4 (sulfate) + 2 (hydroxide) = 6 on left; 4 (sulfate) + 2 (water) = 6 on right. Fully balanced!
✅ Correct Answer
H₂SO₄ + 2 KOH → K₂SO₄ + 2 H₂O
Both numbers must be 2.
❌ Common Errors
Writing formulas instead of balancing numbers, or forgetting to balance both sides (e.g. putting a 2 in front of KOH but leaving H₂O blank).
pH of Potassium Hydroxide
Connecting indicator colour to pH scale values
✅ Correct Answer
14 (Tick box 4)
💡 Key Knowledge
- pH 1: Strongly acidic (Red)
- pH 4: Weakly acidic (Orange/Yellow)
- pH 7: Neutral (Green)
- pH 14: Strongly alkaline (Purple)
KOH is a strong alkali, so universal indicator turns purple at pH 13–14.
❌ Common Errors
Selecting 7 (neutral) assuming the reaction has already taken place, rather than reading that this is pure potassium hydroxide solution.
Apparatus Accuracy
Choosing the most precise equipment for a fixed volume
✅ Correct Answer
Pipette (Tick box 3)
💡 Key Knowledge
A volumetric pipette measures one fixed volume (e.g. 25.0 cm³) with high precision and low percentage uncertainty, much more accurately than a measuring cylinder or beaker.
❌ Common Errors
Selecting "Beaker" or "Test tube" — these have very poor accuracy and are not volumetric instruments.
Titration Method (Extended Response)
Step-by-step procedure using the provided apparatus
🧠 How to Structure a 5-Mark Practical Method
Examiners award 1 mark per distinct, logical experimental step. Write your answer in sequential bullet points following the path of the liquids:
✅ Model Answer (5 Marks)
- Add alkali to flask: Measure 25 cm³ of potassium hydroxide solution and transfer it into the conical flask. [1 mark]
- Add indicator: Add a few drops of indicator (e.g. phenolphthalein / methyl orange) to the flask. [1 mark]
- Add acid from burette: Fill the burette with sulfuric acid and slowly add it into the conical flask (swirling continuously). [1 mark]
- Observe endpoint: Stop adding acid when the indicator changes colour permanently. [1 mark]
- Take reading: Read and record the final volume on the burette (subtract initial reading to calculate volume added). [1 mark]
❌ Common Pitfalls & Lost Marks
- Swapping apparatus: Saying acid is measured in the cylinder and alkali goes in the burette. Look carefully at Figure 7: the cylinder has KOH and the burette contains sulfuric acid.
- Omitting the indicator: Forgetting to state that indicator is added to the conical flask.
- Vague endpoint: Simply saying "until it neutralises" without stating how you know (i.e. the indicator changes colour).
- Missing the final measurement: Ending the response at the colour change without stating that the volume of acid added must be read from the burette.
• Mark 1: Add potassium hydroxide (solution) to the (conical) flask
• Mark 2: Add (a few drops of) indicator
• Mark 3: Add the (sulfuric) acid (from the burette)
• Mark 4: Until the colour (of the indicator) changes
• Mark 5: Read the volume from the burette
AO1 • Spec ref: 4.4.2.5 (Required Practical 2)
Topics
Chemistry · Required Practicals · C4: Chemical Changes · Required Practicals
Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Foundation), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.