AQA GCSE Chemistry Chemistry Paper 1 (Foundation), November 2021: Question 8

11 marks · Standard Demand difficulty · Extended Answer

Answer questions about fullerenes, deduce the displayed and molecular formulas of propanone, and explain the physical properties of graphite based on its structure and bonding.

Practise this question

Question

Question 8 begins with two 1-mark questions asking for the shape of a Buckminsterfullerene molecule and one use of a fullerene. Figure 13 shows a dot and cross diagram of propanone, displaying three carbons, six hydrogens, and an oxygen atom with a double bond. Part 08.3 asks to complete Figure 14 to draw the displayed formula using lines for single bonds, and part 08.4 asks to determine its molecular formula. Part 08.5 is a multiple-choice question on why propanone has a low boiling point. Part 08.6 provides Figure 15 showing the layered hexagonal lattice of graphite and asks students to explain why graphite is a good electrical conductor and soft and slippery in an extended 6-mark response.
Question text

08 This question is about carbon and its compounds.

Fullerenes are molecules of carbon atoms.

The first fullerene to be discovered was Buckminsterfullerene (C60).

08.1 What shape is a Buckminsterfullerene molecule?

[1 mark]

08.2 Give one use of a fullerene.

[1 mark]

Propanone is a compound of carbon, hydrogen and oxygen.

Figure 13 shows the dot and cross diagram for a propanone molecule.

Figure 13

08.3 Complete Figure 14 to show a propanone molecule.

Use a line to represent each single bond.

Use Figure 13.

[1 mark]

Figure 14

08.4 Determine the molecular formula of propanone.

Use Figure 13.

[1 mark]

Molecular formula =

08.5 Propanone is a liquid with a low boiling point.

Why does propanone have a low boiling point?

[1 mark]

Tick ( ) one box.

The covalent bonds are strong.

The covalent bonds are weak.

The intermolecular forces are strong.

The intermolecular forces are weak.34

08.6 Figure 15 represents the structure of graphite.

Figure 15

Explain why graphite is:

• a good electrical conductor

• soft and slippery.

You should answer in terms of structure and bonding.

[6 marks]

Mark scheme

Show the mark scheme Mark scheme for Question 8 with a total of 11 marks. Part 08.1 accepts spherical or ball-shaped (1 mark). Part 08.2 accepts uses such as drug delivery, lubricants, catalysts, or strengthening materials (1 mark). Part 08.3 shows the complete displayed formula of propanone (1 mark). Part 08.4 accepts C3H6O or CH3COCH3 (1 mark). Part 08.5 identifies 'the intermolecular forces are weak' (1 mark). Part 08.6 provides a 3-level response scheme (1-6 marks) with indicative points covering covalent bonding, delocalised electrons free to move and carry charge for electrical conductivity, and hexagonal layers with weak intermolecular forces that can slide over each other for softness and slipperiness.

Question 8

AO /

Question Answers Extra information Mark

Spec. Ref.

08.1 spherical allow ball-shaped 1 AO1

ignore round / circular 4.2.3.3

AO /

Spec. Ref.

08.2 any one from: AO1

• drug delivery (round the body) 1 4.2.3.3

• hydrogen storage

• anti-oxidants

• reduction of bacterial growth

• catalysts

• (cylindrical fullerenes for)

strengthening materials

• (spherical fullerenes for)

lubricants

AO /

Spec. Ref.

08.3 AO2

1 4.2.1.4

AO /

Spec. Ref.

08.4 C3H6O allow CH3COCH3 1 AO2

allow elements in any order 4.2.1.4

Question 8 continued

AO /

Spec. Ref.

08.5 the intermolecular forces are 1 AO1

weak 4.2.2.1

22 4.2.2.4

AO/

Question Answers Mark

Spec. Ref

Level 3: Relevant points (reasons/causes) are identified, given in 5–6 AO1

08.6

detail and logically linked to form a clear account. 4.2.2.6

4.2.3.2

Level 2: Relevant points (reasons/causes) are identified, and there

3–4

are attempts at logical linking. The resulting account is not fully

clear.

Level 1: Points are identified and stated simply, but their relevance

1–2

is not clear and there is no attempt at logical linking.

No relevant content 0

Indicative content

• bonds are covalent

• giant / macromolecular structure

• three (covalent) bonds per carbon atom

or

only three electrons per carbon atom used in (covalent) bonds

• so one electron per carbon atom (is delocalised)

• these delocalised electrons

• can move through the structure

• carrying (electrical) charge

• so graphite conducts electricity

• layered structure

• of (interlocking) hexagonal rings

• with weak (intermolecular) forces between layers

or

no (covalent) bonds between layers

• so the layers can slide over each other

• so graphite is soft and slippery

Total 11

How to answer it

Allotropes of Carbon & Covalent Structures

📋 What this question tests

This 11-mark question assesses core recall, structural deduction, and extended scientific explanation across AQA Topic 2 (Bonding, Structure, and the Properties of Matter). You need to recall facts about fullerenes (C₆₀), translate dot-and-cross models into structural and molecular formulae, explain physical properties of small covalent molecules, and write a structured 6-mark answer linking the bonding of graphite to its electrical conductivity and softness.

Part 08.1 • 1 Mark

Buckminsterfullerene Molecular Shape

AQA Specification 4.2.3.3 Fullerenes

✅ Correct Answer

Spherical

Also allowed: ball-shaped

❌ Common Errors & Examiner Notes

  • Writing "round" or "circular" — these describe 2D shapes and receive zero marks.
  • Writing "hexagonal" — rings inside the fullerene are hexagonal and pentagonal, but the overall molecule shape is spherical.
Award 1 mark for identifying the three-dimensional spherical/ball shape of a C₆₀ molecule.
Part 08.2 • 1 Mark

Uses of Fullerenes

AQA Specification 4.2.3.3 Fullerenes

✅ Any ONE of the following accepted answers:

  • Drug delivery (into/round the body)
  • Lubricants
  • Catalysts (due to high surface-area-to-volume ratio)
  • Hydrogen storage
  • Anti-oxidants
  • Reduction of bacterial growth
  • Strengthening materials (cylindrical fullerenes / nanotubes)

🧠 Exam Technique

The question says "Give one use". Never write multiple guesses; if one is incorrect, you risk cancelling out your correct answer. "Drug delivery" or "lubricants" are the most reliable, standard recall points.

Award 1 mark for any single valid medical, chemical, or engineering application.
Part 08.3 • 1 Mark

Completing the Structural Formula of Propanone

AQA Specification 4.2.1.4 Covalent Bonding

✅ Completed Structural Formula

H H | | H — C — C — C — H | || | H O H

Each single shared pair of electrons in Figure 13 becomes a single line ( — ). The central carbon is already double-bonded to oxygen ( C=O ).

🧠 Exam Technique: Reading Dot-and-Cross

  • 1 pair of shared electrons (ו) = 1 single covalent bond ( — ).
  • Figure 13 shows 3 C–H bonds on the left carbon and 3 C–H bonds on the right carbon.
  • Ensure every hydrogen has one bond and all three carbons have four bonds total.
Award 1 mark for correctly displaying two methyl groups (–CH₃) single-bonded to the central carbon atom.
Part 08.4 • 1 Mark

Molecular Formula of Propanone

AQA Specification 4.2.1.4 Molecular Formulae

✅ Correct Answer

C₃H₆O

Also allowed: CH₃COCH₃ or elements in any order (e.g. H₆C₃O ).

📐 Step-by-Step Counting

  1. Count carbon atoms: 3 black central circles = C₃
  2. Count hydrogen atoms: 3 on left + 3 on right = H₆
  3. Count oxygen atoms: 1 at the bottom = O
  4. Combine using subscript numerals: C₃H₆O

❌ Common Errors

  • Writing numbers on the baseline or as superscripts instead of subscripts (e.g. C3H6O or C³H⁶O).
  • Miscounting hydrogen atoms (often writing 5 or 8).
Award 1 mark for correct symbols and subscript ratios.
Part 08.5 • 1 Mark

Explaining Low Boiling Point

AQA Specification 4.2.2.1 & 4.2.2.4 Simple Molecules

✅ Correct Checkbox Choice

☑ The intermolecular forces are weak.

💡 Key Knowledge

Propanone is a small covalent molecule. When it boils, the strong covalent bonds within the molecules do NOT break. Only the weak intermolecular forces between separate molecules are overcome.

❌ Common Misconception

Students regularly tick "The covalent bonds are weak". Covalent bonds are extremely strong! Boiling simple molecules never breaks covalent bonds.

Award 1 mark for identifying weak intermolecular forces.
Part 08.6 • 6 Marks

Properties of Graphite: Conduction & Lubrication

AQA Specification 4.2.2.6 & 4.2.3.2 Giant Covalent Structures

🧠 How Examiners Mark this 6-Marker (Level of Response)

  • Level 3 (5–6 marks): Both properties (electrical conductor AND soft/slippery) are fully explained with structured, linked reasoning using correct chemical terminology.
  • Level 2 (3–4 marks): Attempts to link structure to both properties, or gives a complete explanation of only one property.
  • Level 1 (1–2 marks): Isolated points stated without clear logical connections (e.g. states "has delocalised electrons" or "has layers").

💡 Part 1: Why Graphite Conducts Electricity

  1. Graphite has a giant covalent / macromolecular structure.
  2. Each carbon atom forms only three covalent bonds to other carbon atoms (hexagonal rings).
  3. This leaves one electron per carbon atom delocalised (free).
  4. These delocalised electrons can move throughout the structure.
  5. They carry electrical charge through the material.

💡 Part 2: Why Graphite is Soft and Slippery

  1. Graphite is arranged in layers of hexagonal rings.
  2. There are no covalent bonds between the layers (only weak intermolecular forces).
  3. Because these forces are weak, the layers can easily slide over each other.
  4. This makes graphite feel soft, slippery, and suitable as a solid lubricant or in pencil lead.

✅ Model 6/6 Answer Template

"Graphite is a giant covalent structure made of carbon atoms arranged in hexagonal layers. Each carbon atom forms three covalent bonds, leaving one delocalised electron per atom. Because these delocalised electrons are free to move throughout the structure, they carry electrical charge, making graphite a good electrical conductor."

"Furthermore, between the layers there are only weak intermolecular forces and no covalent bonds. Therefore, the layers can easily slide over one another, which makes graphite soft and slippery."

❌ Costly Mistakes to Avoid

  • Saying "ions move": Graphite is made purely of neutral carbon atoms; electrical current is carried by delocalised electrons, never ions.
  • Saying "covalent bonds break when layers slide": Only the weak forces between layers are overcome; the covalent bonds inside each sheet remain intact.
  • Missing the cause: Stating "it has delocalised electrons" without stating "because each carbon only forms 3 bonds" misses key AO1 marking points.
Mark Breakdown:
• Conductor points: 3 bonds/atom → 1 delocalised electron/atom → moves through structure carrying charge (3 marks equivalent).
• Slippery points: layered structure → weak intermolecular forces / no covalent bonds between layers → layers slide over each other (3 marks equivalent).

Topics

Chemistry · C2: Bonding, Structure and the Properties of Matter

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Foundation), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.