AQA GCSE Chemistry Chemistry Paper 2 (Foundation), November 2021: Question 1

9 marks · Low Demand difficulty · Short Answer

Answer questions on the formation and evolution of the Earth's atmosphere, including calculating gas percentages and completing the word equation for photosynthesis.

Practise this question

Question

Question 01 focuses on the Earth's atmosphere. 01.1 asks when the Earth was formed with choices: 4.6 billion, 4.6 million, or 4.6 thousand years ago. Table 1 shows gas percentages for Mars and Earth: carbon dioxide (95.97% vs 0.04%), nitrogen (1.89% vs 78.09%), oxygen (0.15% vs 20.95%), and other gases (1.99% vs X). 01.2 asks to calculate X. 01.3 asks students to draw lines connecting Nitrogen and Oxygen to their percentage change. 01.4 asks to tick two causes for the decrease of carbon dioxide. 01.5 asks to complete the word equation for photosynthesis: [blank] + water -> glucose + [blank]. 01.6 is a sentence completion asking why scientists are not certain about early atmospheric gas percentages due to a lack of [blank].
Question text

01 This question is about the Earth’s atmosphere.

01.1 How long ago was the Earth formed?

[1 mark]

Tick ( ) one box.

4.6 billion years ago

4.6 million years ago

4.6 thousand years ago

Table 1 shows the percentages of gases in the atmospheres of Mars and

Earth today.

Table 1

Percentage of gas in atmosphere (%)

Gas

Mars Earth

Carbon dioxide 95.97 0.04

Nitrogen 1.89 78.09

Oxygen 0.15 20.95

Other gases 1.99 X

01.2 Calculate the percentage X of other gases in the Earth’s atmosphere.

Use Table 1.

[1 mark]

3 X =

%

The atmosphere of the early Earth is thought to have been similar to the atmosphere

of Mars today.

The percentages of nitrogen and of oxygen in the Earth’s atmosphere today have

changed from the percentages in the Earth’s early atmosphere.

01.3 Draw one line from each gas to the change in the percentage of that gas.

*02* Use Table 1.

[2 marks]

Gas Change in percentage of gas

Increased by about 4 times

Nitrogen

Increased by about 21%

Increased by about 40 times

Oxygen

Increased by about 96%

01.4 The percentage of carbon dioxide in the Earth’s early atmosphere decreased.

Which two processes caused this decrease?

[2 marks]

Tick ( ) two boxes.

Carbon dioxide dissolving in sea water

Combustion of fossil fuels

Farming of animals

Formation of sedimentary rocks

Volcanoes releasing carbon dioxide4

01.5 Photosynthesis also decreased the percentage of carbon dioxide in the Earth’s

early atmosphere.

Photosynthesis increased the percentage of another gas.

Complete the word equation for photosynthesis.

[2 marks]

+ water → glucose +

01.6 Complete the sentence.

[1 mark]

Scientists are not certain about the percentages of gases in the Earth’s early

atmosphere because there is a lack of .

Mark scheme

Show the mark scheme Mark scheme for Question 1: 01.1 is '4.6 billion years ago' (1 mark, AO1); 01.2 is '0.92 (%)' (1 mark, AO2); 01.3 shows Nitrogen matched to 'Increased by about 40 times' and Oxygen matched to 'Increased by about 21%' (2 marks, AO1/AO2); 01.4 lists 'carbon dioxide dissolving in sea water' and 'formation of sedimentary rocks' (2 marks, AO1); 01.5 requires 'carbon dioxide' (allow CO2) and 'oxygen' (allow O2) (2 marks, AO1); 01.6 requires 'evidence / proof' (1 mark, AO1). Total = 9 marks.

Question 1

AO /

Question Answers Extra information Mark

Spec. Ref.

01.1 4.6 billion years ago 1 AO1

4.9.1.2

AO /

Spec. Ref.

01.2 0.92 (%) 1 AO2

4.9.1.1

AO /

Spec. Ref.

01.3

1 AO1

1 AO2

4.9.1.1

4.9.1.3

do not accept more than one line from a box on the left

AO /

Spec. Ref.

01.4 carbon dioxide dissolving in sea 1 AO1

water 4.9.1.2

4.9.1.4

formation of sedimentary rocks 1

AO /

Spec. Ref.

01.5 carbon dioxide (+ water → ) allow CO2 1 AO1

4.9.1.3

(→ glucose +) oxygen allow O2 1

Question 1 continued

AO /

Spec. Ref.

01.6 evidence / proof 1 AO1 7

4.9.1.2

Total 9

How to answer it

The Earth's Atmosphere: Origin and Evolution

📋 What this question tests

This question assesses foundational recall and data handling regarding the Earth's atmosphere (Specification 4.9.1):

  • Recall: The approximate age of the Earth and the lack of concrete evidence for its early atmosphere.
  • Data Analysis: Calculating unknown percentages from tabular data and comparing relative changes in gas concentrations.
  • Atmospheric Evolution: Mechanisms that reduced carbon dioxide levels (ocean absorption, sedimentary rock formation, photosynthesis).
  • Word Equations: Constructing the balanced word equation for photosynthesis.

Question 01.1: Age of the Earth

Multiple Choice (1 mark)

✅ Correct Answer

4.6 billion years ago

💡 Key Knowledge

Evidence from radioactive dating of rocks and meteorites suggests the Earth was formed roughly 4.6 billion (4,600,000,000) years ago.

❌ Common Errors

Confusing million and billion. Remember: geologic and planetary formation timescales are measured in billions of years.

🧠 Exam Technique

Read the question carefully: "Tick (✓) one box." Double-ticking immediately invalidates the mark.

Mark allocation: 1 mark for selecting "4.6 billion years ago". [AO1]

Question 01.2: Calculating Unknown Percentage X

Data Calculation (1 mark)

📐 Step-by-Step Calculation

  1. Total atmosphere percentage = 100%
  2. Sum the known gases in Earth's atmosphere:
    0.04 + 78.09 + 20.95 = 99.08%
  3. Subtract from 100 to find X:
    X = 100 - 99.08 = 0.92%

✅ Correct Answer

X = 0.92 (%)

❌ Common Errors

Adding the numbers incorrectly under timed conditions or accidentally calculating for Mars instead of Earth. Always double-check which column is requested!

🧠 Exam Technique

The "%" sign is already written on the answer line, so simply enter the numeric value 0.92 .

Mark allocation: 1 mark for correct value 0.92. [AO2]

Question 01.3: Comparing Early and Modern Atmospheres

Matching Lines (2 marks)

✅ Correct Matches

  • Nitrogen ➔ connects to Increased by about 40 times
  • Oxygen ➔ connects to Increased by about 21%

💡 The Logic Behind the Numbers

  • Nitrogen: Rose from 1.89% to 78.09%.
    78.09 ÷ 1.89 ≈ 41.3 (approx. 40 times multiplier).
  • Oxygen: Rose from 0.15% to 20.95%.
    20.95% - 0.15% = 20.8% (an absolute increase of about 21 percentage points).

❌ Common Errors

  • Drawing multiple lines from one box on the left (the mark scheme specifically states: "do not accept more than one line from a box on the left").
  • Confusing a percentage point difference with a multiplication factor ("times").

🧠 Exam Technique

Use a ruler to draw straight, clear lines. If you change your mind, cross out the incorrect line completely rather than leaving ambiguous lines.

Mark allocation: 1 mark for each correct line drawn. [AO1 / AO2]

Question 01.4: Processes Decreasing Carbon Dioxide

Multiple Choice (2 marks)

✅ Correct Choices (Tick 2)

  • ☑ Carbon dioxide dissolving in sea water
  • ☑ Formation of sedimentary rocks

💡 Key Knowledge

As the Earth cooled, water vapour condensed into oceans. CO₂ dissolved into the water, forming carbonate precipitates that settled to produce sedimentary rocks (like limestone, CaCO₃). Marine organisms also used dissolved carbonates to form shells and skeletons.

❌ Common Errors

  • Selecting combustion or volcanoes: both of these release CO₂ rather than decreasing it.
  • Selecting farming of animals: this increases greenhouse gases like methane (CH₄) and CO₂ in modern times, not early Earth.

🧠 Exam Technique

Notice the prompt explicitly states: "Which two processes caused this decrease?". Ticking more than two boxes will lose marks.

Mark allocation: 1 mark for each correct box ticked. [AO1]

Question 01.5: Word Equation for Photosynthesis

Completing Word Equation (2 marks)

✅ Correct Answer

carbon dioxide + water → glucose + oxygen

💡 Key Knowledge

  • Algae first produced oxygen about 2.7 billion years ago.
  • Over the next billion years, green plants evolved and photosynthesis further increased the percentage of O₂ and decreased CO₂.

🧠 Exam Technique & Allowed Alternatives

The mark scheme accepts correct chemical formulae: CO₂ and O₂ . However, writing out the standard chemical names guarantees you avoid making subscript errors!

❌ Common Errors

  • Confusing photosynthesis with respiration (writing water and glucose on the left).
  • Writing "energy" or "light" in the blank spaces instead of the chemical substances.
Mark allocation: 1 mark for carbon dioxide (or CO₂), 1 mark for oxygen (or O₂). [AO1]

Question 01.6: Uncertainty in Early Atmosphere Data

Sentence Completion (1 mark)

✅ Correct Answer

...because there is a lack of evidence / proof.

💡 Key Knowledge

The Earth formed 4.6 billion years ago, which means there are very few surviving rocks or direct samples from that time period. Theories about the early atmosphere are scientific deductions based on other planets (like Mars and Venus) rather than direct measurements.

🧠 Exam Technique

Keep the completion concise. A single word like evidence fits the sentence grammatically and matches the specification wording directly.

❌ Common Errors

Writing vague statements like "nobody was alive to see it" or "technology wasn't good back then". Always use scientific terms: lack of evidence or lack of data/proof.

Mark allocation: 1 mark for "evidence" or "proof". [AO1]

Topics

Chemistry · C9: Chemistry of the Atmosphere

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.