AQA GCSE Chemistry Chemistry Paper 2 (Foundation), November 2021: Question 2

13 marks · Low Demand difficulty · Short Answer

Analyse methods and calculations used to determine the salt concentration in sea water and methods for producing and sterilising potable water.

Practise this question

Question

Exam question spanning multiple parts about water analysis and purification: 02.1 asks for the apparatus to measure the mass of an evaporating dish and the volume of sea water. 02.2 provides a table with the mass of an evaporating dish (30.44 g) and dish with salt (30.49 g) from 50 cm³ sea water, asking to calculate the salt mass in 1000 cm³. 02.3 asks to select two steps to prove the salt is completely dry. Figure 1 shows two distillation setups: Student Y with just a delivery tube into a test tube, and Student Z with a Liebig condenser (water in/out) into a test tube; 02.4 asks why Student Y collects less water. 02.5 asks why distilled water does not need sterilisation. 02.6 asks to tick two methods of sterilising fresh water from a list of five options. 02.7 asks for the pH value when universal indicator turns green.
Question text

02 This question is about water.

A student investigated the concentration of salt in sea water.

This is the method used.

1. Filter the sea water to remove sand.

2. Measure the mass of an empty evaporating dish.

3. Measure 50 cm3 of sea water into the evaporating dish.

4. Heat the evaporating dish and sea water.

5. Evaporate the sea water to dryness.

6. Measure the mass of the evaporating dish and salt.

02.1 What equipment should the student use to measure:

• the mass of the evaporating dish

• the volume of sea water?

[2 marks]

Mass of evaporating dish

Volume of sea water

02.2 Table 2 shows the student’s results.

Table 2

Mass in g

Evaporating dish 30.44

Evaporating dish and salt 30.49

The student used 50 cm3 of sea water.

Calculate the mass of salt in 1000 cm3 of this sea water.

[3 marks]

Mass of salt = g

02.3 The salt must be completely dry.

Which two extra steps are needed to show that the salt is completely dry?

[2 marks]

Tick ( ) two boxes.

Filter the sea water again.

Heat the evaporating dish and salt again.

Measure the 50 cm3 of sea water again.

Measure the mass of the empty evaporating dish again.

Measure the mass of the evaporating dish and salt again.

Two students, Y and Z, distil sea water to collect water.

Figure 1 shows the apparatus used by each student to collect the water.

Figure 1

02.4 Students Y and Z boil the same volume of sea water for the same period of time.

Explain why student Y collects a smaller volume of water than student Z.

[2 marks]

02.5 Water obtained by distillation does not need to be sterilised and is safe to drink.

Suggest why.

[1 mark]

Fresh water needs to be sterilised before it is safe to drink.

02.6 How is fresh water sterilised?

[2 marks]

Tick ( ) two boxes.

Using ammonia

Using chlorine

Using chromatography

Using filtration

Using ozone

02.7 A student tests the pH of fresh water using universal indicator solution.

When added to the fresh water, the colour of the universal indicator solution is green.

What is the pH of this fresh water?

[1 mark]

pH =

Mark scheme

Show the mark scheme Mark scheme for Question 2 with mark allocations and guidance: 02.1 awards 1 mark each for balance and measuring cylinder (accepting burette/pipette). 02.2 awards 3 marks for calculating mass = 0.05 g, multiplying by (1000/50), giving 1.0 g. 02.3 gives 2 marks for 'heat the evaporating dish and salt again' and 'measure the mass of the evaporating dish and salt again'. 02.4 gives 2 marks for steam escaping/less condensing and cooling being less efficient/lack of condenser. 02.5 awards 1 mark for water is pure or microbes are destroyed. 02.6 awards 2 marks for ticking chlorine and ozone. 02.7 gives 1 mark for pH 7. Total 13 marks.

Question 2

AO /

Question Answers Extra information Mark

Spec. Ref.

02.1 (mass) balance allow scales 1 AO1

4.10.1.2

(volume) measuring cylinder allow burette / pipette 1 RPA 8

AO /

Spec. Ref.

02.2 (mass of salt = 30.49 – 30.44 =) AO2

0.05 (g salt) 1 4.10.1.2

RPA8

(mass of salt in 1000 cm3 =)

1000 allow correct use of incorrectly 1

× 0.05 determined mass of salt

= 1.0 (g) 1

alternative approach:

1000

(volume ratio = ) = 20 (1)

(mass of salt in 1000 cm3)

allow correct use of incorrectly

= (30.49 – 30.44) × 20 (1) determined volume ratio

= 1.0 (g) (1)

AO /

Spec. Ref.

02.3 heat the evaporating dish and 1 AO3

salt again 4.10.1.2

RPA 8

measure the mass of the 1

evaporating dish and salt again

Question 2 continued

AO /

Spec. Ref.

02.4 allow converse for condenser

allow water vapour for steam 9

(no condenser)

(more) steam escapes 1 AO1

or

less steam condenses

(because) cooling / condensing allow (because) cooling / 1 AO3

is less efficient condensing is slower

or 4.1.1.2

(because) a (liebig) condenser allow (because) cold water is 4.10.1.2

is not used not used for cooling /

condensing

AO /

Spec. Ref.

02.5 (distilled) water is pure allow microbes are destroyed 1 AO3

(by distillation) 4.8.1.1

4.10.1.2

AO /

Spec. Ref.

02.6 using chlorine 1 AO1

4.10.1.2

using ozone 1

AO /

Spec. Ref.

02.7 pH 7 1 AO2

4.4.2.4

4.10.1.2

RPA8

Total 13

How to answer it

Water Purification, Analysis & Required Practical 8

📋 What this question tests

Core Chemistry Topics: AQA Topic 10 (Using Resources - Potable Water) and Required Practical 8 (Analysis and purification of water samples).

  • Selecting appropriate laboratory apparatus for measuring mass and volume accurately.
  • Determining the mass of dissolved solids and scaling calculations up from 50 cm³ to 1000 cm³.
  • Understanding experimental techniques for heating to constant mass to prove complete dryness.
  • Comparing simple air-cooling delivery tubes versus a Liebig condenser in distillation setups.
  • Methods of sterilising potable water (chlorine, ozone, UV) and testing neutral pH with Universal Indicator.
Question 02.1

Measuring Equipment for Mass and Volume

Identifying standard laboratory measuring tools [2 marks]

✅ Correct Answers

  • Mass of evaporating dish: (mass) balance [allow: scales] (1)
  • Volume of sea water: measuring cylinder [allow: burette / pipette] (1)

❌ Common Errors

  • Writing beaker for measuring volume. Beakers have approximate scale markings and are never accepted as measuring instruments.
  • Writing weighing machine instead of balance.
🎯 Mark Breakdown: 1 mark per correct piece of apparatus named.
Question 02.2

Calculating Dissolved Solid Concentration

Scaling mass of salt from 50 cm³ to 1000 cm³ [3 marks]

📐 Step-by-Step Calculation

  1. Step 1: Calculate mass of salt in 50 cm³
    30.49 g - 30.44 g = 0.05 g (1 mark)
  2. Step 2: Find scaling factor or volume ratio
    1000 cm³ ÷ 50 cm³ = 20 (1 mark)
  3. Step 3: Multiply to find total mass in 1000 cm³
    0.05 g × 20 = 1.0 g (1 mark)
    (Alternative setup: (1000 ÷ 50) × 0.05 = 1.0 g)

❌ Calculation Traps & Tips

  • Inverting the ratio: Dividing 50 by 1000 instead of 1000 by 50. The sample is 50 cm³, so 1000 cm³ will contain 20 times more salt.
  • Error-Carried-Forward (ECF): If you miscalculate the initial subtraction (e.g. 0.04 g), you can still get the next 2 marks if you correctly multiply your value by 20.
🎯 Final Answer: 1.0 g (or 1 g) [3 marks total].
Question 02.3

Heating to Constant Mass

Proving that all water has evaporated from a solid [2 marks]

✅ Correct Ticks

  • ☑ Heat the evaporating dish and salt again. (1)
  • ☑ Measure the mass of the evaporating dish and salt again. (1)

💡 Key Knowledge: "Constant Mass"

To prove any solid is completely dry, you must:

  1. Reheat the sample.
  2. Reweigh the sample.
  3. Repeat until two consecutive mass readings are identical (no more mass lost as steam).
🎯 Exam Tip: Ticking more than 2 boxes results in marks being deducted!
Question 02.4

Evaluating Distillation Apparatus

Why Student Y collects less water than Student Z [2 marks]

✅ Mark Scheme Requirements

  • Point 1 (Escape/Condensation): (More) steam / water vapour escapes OR less steam condenses. (1)
  • Point 2 (Cooling efficiency): Because cooling / condensing is less efficient (slower) OR a condenser (Liebig condenser) is not used / cold water is not used for cooling. (1)

🧠 Exam Technique: Two-Sided Contrast

Notice the 2 marks correspond to effect and cause:

  • Effect: Steam fails to turn back into liquid and escapes into the air.
  • Cause: A delivery tube only has surrounding room air to cool it, whereas a Liebig condenser surrounds the tube with a jacket of circulating cold water.
🎯 Examiner Commentary: Do not just state "Z has better equipment". You must refer specifically to condensation, steam escaping, or the condenser / cold water jacket.
Question 02.5

Safety of Distilled Water

Why distilled water does not need sterilisation [1 mark]

✅ Accepted Answers

  • (Distilled) water is pure. (1)
  • OR Microbes / bacteria / pathogens are destroyed / killed by boiling/distillation. (1)

❌ Common Errors

  • Writing "it has no salt" — this explains why it is not salty, but sterilisation is about biological microbes, not dissolved salts.
  • Writing "it is clean" — too vague. GCSE examiners look for the words pure or microbes/bacteria killed.
Question 02.6

Methods of Sterilising Fresh Water

Recalling sterilising agents for potable water [2 marks]

✅ Correct Ticks

  • ☑ Using chlorine (1)
  • ☑ Using ozone (1)

💡 Key Knowledge: Making Potable Water

Treating fresh groundwater involves two essential stages:

  • 1. Filtration: Passes through filter beds (sand/gravel) to remove insoluble solids. (Filtration does not kill bacteria!)
  • 2. Sterilisation: Kills harmful microbes using chlorine, ozone, or ultraviolet (UV) light.
🎯 Examiner Trap: Many students confuse "filtration" with "sterilisation". Filtration removes suspended solids (sand/dirt), not microbes.
Question 02.7

Testing pH with Universal Indicator

Determining the pH of a neutral solution [1 mark]

✅ Correct Answer

pH = 7 (1 mark)

💡 Universal Indicator Colour Scale

  • Red / Orange / Yellow: Acidic (pH 1 – 6)
  • Green: Neutral (pH 7)
  • Blue / Purple: Alkaline (pH 8 – 14)

Topics

Chemistry · Required Practicals · C10: Using Resources · C4: Chemical Changes · Required Practicals

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.