AQA GCSE Chemistry Chemistry Paper 2 (Foundation), November 2021: Question 3

14 marks · Standard Demand difficulty · Short Answer

Evaluate and compare materials used for window frames, including glass, polymers, wood, and aluminium alloys, and calculate the percentage composition of an alloy.

Practise this question

Question

Question 3 presents a diagram of a window with glass and frame. Sub-question 03.1 asks to select two materials used with sand to make glass. A table lists the density and relative strength of poly(chloroethene) and HDPE, followed by 03.2 and 03.3 asking for advantages of each polymer. Sub-question 03.4 shows the polymer structure of poly(chloroethene) and asks to identify its monomer from four options. Sub-question 03.5 asks for the test and result for chlorine gas. Sub-question 03.6 gives bullet points comparing polymers and wood, asking for one advantage of each. A final data table shows the elemental composition of 6.00 kg of an aluminium alloy (5.94 kg aluminium, 0.04 kg magnesium, 0.02 kg silicon), followed by 03.7 calculating the percentage of aluminium, and 03.8 asking why an alloy is used instead of pure aluminium.
Question text

03 This question is about substances used to make windows and window frames.

Figure 2 shows a window.

Figure 2

03.1 Glass is made by heating sand with two other materials.

Which two other materials are used to make glass?

[2 marks]

Tick ( ) two boxes.

Clay

Graphite

Limestone

Sodium carbonate

Sodium hydroxide 11

Window frames need to be:

• easy to install

• resistant to damage.

The polymers poly(chloroethene) and HDPE are used to make window frames.

Table 3 shows information about poly(chloroethene) and HDPE.

Table 3

Property Poly(chloroethene) HDPE

Density in g/cm3 1.4 0.92

Relative strength 72 25

03.2 Suggest one advantage of using poly(chloroethene) compared with HDPE to make

window frames.

Give one reason for your answer.

Use Table 3.

[2 marks]

Advantage

Reason

03.3 Suggest one advantage of using HDPE compared with poly(chloroethene) to make

window frames.

Give one reason for your answer.

Use Table 3.

[2 marks]

Advantage

Reason

03.4 Figure 3 shows the displayed structural formula of poly(chloroethene).

Figure 3

Which monomer is used to make poly(chloroethene)?

[1 mark]

Tick ( ) one box.

03.5 Chlorine gas is used to produce poly(chloroethene).

Describe a test to identify chlorine gas.

Give the result of the test.

[2 marks]

Test

Result

03.6 Wood can be used instead of polymers to make window frames.

• Polymers are unreactive.

• Polymers are produced from crude oil.

• Wood breaks down in wet conditions.

• Wood is produced from trees.

Suggest one advantage of using polymers and one advantage of using wood to make

window frames.

[2 marks]

Advantage of polymers

Advantage of wood

Window frames can also be made from an alloy of aluminium.

03.7 6.00 kg of the alloy is used to make a window frame.

Table 4 shows the mass of each element in 6.00 kg of the alloy.

Table 4

Element Mass in kg

Aluminium 5.94

Magnesium 0.04

Silicon 0.02

Calculate the percentage of aluminium in 6.00 kg of the alloy.

[2 marks]

Percentage of aluminium = %

03.8 Why is an alloy used instead of pure aluminium to make window frames?

[1 mark]

Mark scheme

Show the mark scheme Mark scheme for Question 3 spanning eight sub-questions. 03.1 accepts limestone and sodium carbonate (2 marks). 03.2 awards 1 mark for stronger and 1 mark for less easily damaged. 03.3 awards 1 mark for lower density and 1 mark for lighter to install. 03.4 identifies the chloroethene monomer (1 mark). 03.5 awards 1 mark for damp litmus paper and 1 mark for bleached or turns white. 03.6 awards 1 mark for polymers lasting a long time and 1 mark for wood being renewable. 03.7 awards 1 mark for (5.94 / 6.00) * 100 and 1 mark for 99%. 03.8 awards 1 mark for harder or stronger than pure aluminium. Total: 14 marks.

Question 3

AO /

Question Answers Extra information Mark

Spec. Ref.

03.1 limestone 1 AO1

4.10.3.3

sodium carbonate 1

AO /

Spec. Ref.

03.2 (advantage) stronger 1 AO3

(reason) less easily damaged 1 AO2

4.10.3.3

AO /

Spec. Ref.

03.3 (advantage) lower density 1 AO3

(reason) lighter (to install) 1 AO2

4.10.3.3

AO /

Spec. Ref.

03.4

1 AO2

4.7.3.1

AO /

Spec. Ref.

03.5 (add damp) litmus paper 1 AO1

4.8.2.4

(litmus paper) is bleached ignore (litmus paper) turns red 1

or

(litmus paper) turns white

Question 3 continued

AO /

Spec. Ref.

03.6 ignore references to cost

(polymers)

last a long time allow break down slowly 1 AO3

(wood)

renewable allow trees can be replanted 1 AO1

allow aesthetic reasons 4.10.1.1

AO /

Spec. Ref.

03.7 (percentage of aluminium =) AO2

5.94 1 4.10.3.2

× 100

6.00

= 99 (%) 1

AO /

Spec. Ref.

03.8 (alloy is) harder (than pure allow (alloy is) stronger (than 1 AO2

aluminium) pure aluminium) 4.2.2.7

4.10.3.2

ignore references to cost

Total 14

How to answer it

Materials for Window Construction: Glass, Polymers & Alloys

WHAT THIS QUESTION TESTS

This question assesses fundamental knowledge from Using Resources, Organic Chemistry, Chemical Analysis, and Structure & Bonding:

  • Raw materials required to produce soda-lime glass.
  • Evaluating materials for specific applications using physical property data (density and strength).
  • Deducing the structure of an alkene monomer from an addition polymer.
  • Recalling the qualitative analytical test for chlorine gas.
  • Comparing sustainability and durability of natural vs synthetic materials (wood vs polymers).
  • Calculating percentage composition by mass in an alloy.
  • Explaining why alloys are used over pure metals due to their enhanced hardness.
PART 03.1 • 2 MARKS

Raw Materials for Making Glass

Identifying the ingredients of soda-lime glass

✅ Correct Answer

  • Limestone [1 mark]
  • Sodium carbonate [1 mark]
Total: 2 marks (1 mark per correct box ticked)

💡 Key Knowledge

Most everyday glass (windows and bottles) is soda-lime glass. It is made by heating a mixture of:

  • Sand (silicon dioxide, SiO₂)
  • Sodium carbonate (soda)
  • Limestone (calcium carbonate, CaCO₃)

❌ Common Errors

  • Selecting Clay — clay is heated to make ceramics/pottery and bricks, not glass.
  • Confusing Sodium carbonate with Sodium hydroxide.

🧠 Exam Technique

Pay close attention to the number of boxes: the question explicitly states "Tick (✓) two boxes". Ticking more or fewer will cost marks.

PARTS 03.2 & 03.3 • 4 MARKS

Evaluating Polymers Using Data

Linking Table 3 properties to window frame requirements

✅ Correct Answers

03.2: Poly(chloroethene) advantage:

  • Advantage: Stronger [1 mark]
  • Reason: Less easily damaged / resistant to damage [1 mark]

03.3: HDPE advantage:

  • Advantage: Lower density [1 mark]
  • Reason: Lighter (to install) / easier to install [1 mark]

🧠 Exam Technique: Use the Prompt!

The question prompt gave two essential clues right above the table:

  • "resistant to damage" → links to strength (poly(chloroethene) has a relative strength of 72 vs 25).
  • "easy to install" → links to density (HDPE density is 0.92 g/cm³ vs 1.4 g/cm³; lower density means lighter parts).

❌ Common Errors

  • Stating only numbers without interpretation: Just writing "strength is 72" does not state an advantage. You must state it is stronger.
  • Mismatched reasons: Saying HDPE is "lower density" but giving the reason "does not break" scores zero for the reason mark. Always link low density → lightweight / easier to lift and install.
PART 03.4 • 1 MARK

Deducing the Monomer

Converting addition polymer structures back to monomers

✅ Correct Answer

Tick the 2nd box:

 H  Cl
 |   |
 C = C
 |   |
 H   H
1 mark for identifying chloroethene

💡 Key Knowledge: Addition Polymerisation

  • Addition polymers form when alkene monomers open their double bonds to form a long single-bonded chain.
  • To find the monomer from a repeating unit:
    1. Replace the central single C–C bond with a double C=C bond.
    2. Remove the side-extending single bonds and the brackets/ n .
    3. Keep all surrounding atoms ( H , Cl ) on the exact same carbons.
PART 03.5 • 2 MARKS

Gas Identification: Chlorine Gas

Qualitative analysis of halogens

✅ Correct Answer

  • Test: (Add damp) litmus paper [1 mark]
  • Result: (Litmus paper is) bleached OR turns white [1 mark]
Total: 2 marks

❌ Common Errors & Examiner Commentary

  • "Turns red": The mark scheme specifically states ignore (litmus paper) turns red . Chlorine forms an acidic solution when dissolved so it briefly turns damp blue litmus red, but the defining result for chlorine is that it bleaches it white!
  • Missing "damp": Always specify damp litmus paper. Dry litmus paper does not react quickly because the gas must dissolve in moisture to act as a bleach.
  • Confusing gas tests: Do not confuse with oxygen (relights a glowing splint) or hydrogen (squeaky pop).
PART 03.6 • 2 MARKS

Comparing Materials: Polymers vs Wood

Sustainability, raw sources, and weathering

✅ Correct Answer

  • Advantage of polymers: Last a long time / unreactive / break down slowly / do not rot [1 mark]
  • Advantage of wood: Renewable / sustainable / trees can be replanted / aesthetic reasons [1 mark]
Total: 2 marks

🧠 Exam Technique: Steer Clear of "Cost"

The mark scheme strictly notes: ignore references to cost .

Saying "wood is cheaper" or "polymers are cheaper" will earn zero marks. Always base your answers on the bullet points provided in the question prompt:

  • "Polymers are unreactive / wood breaks down in wet conditions" → polymers last longer / won't rot.
  • "Wood is produced from trees / polymers from crude oil" → wood is renewable; crude oil is finite.
PART 03.7 • 2 MARKS

Calculation: Percentage by Mass in an Alloy

Finding the proportion of aluminium in a window frame

📐 Step-by-Step Calculation

Step 1: Identify the values from Table 4
Mass of aluminium = 5.94 kg
Total mass of alloy = 6.00 kg
Step 2: Apply the percentage formula
Percentage = (Mass of element ÷ Total mass) × 100
Step 3: Calculate
Percentage = (5.94 ÷ 6.00) × 100 = 99%

✅ Mark Scheme Breakdown

  • Working mark: (5.94 / 6.00) × 100 [1 mark]
  • Answer mark: 99 (%) [1 mark]

An answer of 99 with no working scores both marks, but always show working to safeguard against arithmetic slips!

PART 03.8 • 1 MARK

Properties of Alloys

Why alloys are preferred over pure metals for structures

✅ Correct Answer

The alloy is harder (than pure aluminium) OR stronger (than pure aluminium) [1 mark].

1 mark

💡 Key Knowledge: Why Alloys are Harder

  • Pure metals: Atoms are all the same size and arranged in regular layers. These layers can easily slide over each other, making pure metals relatively soft and malleable.
  • Alloys: Different elements have different-sized atoms. Adding them distorts the regular layered structure, making it harder for layers to slide over each other.

❌ Common Errors

  • Again, ignore references to cost . Window frames need structural strength and durability, not just low price.
  • Do not say "it doesn't rust" — aluminium already forms an unreactive oxide layer that resists corrosion; the key mechanical upgrade of alloying is hardness and strength.

Topics

Chemistry · C2: Bonding, Structure and the Properties of Matter · C7: Organic Chemistry · C8: Chemical Analysis · C10: Using Resources

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), November 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.