AQA GCSE Chemistry Chemistry Paper 2 (Foundation), June 2022: Question 7

7 marks · Low Demand difficulty · Short Answer

Answer questions on fertilisers, including calculating the mass spread per unit area, scientific bias, chemical formulae, and formulations.

Practise this question

Question

Question 7 has six parts about fertilisers: 07.1 asks to complete a sentence identifying which acid reacts with ammonia to produce ammonium nitrate from a box containing hydrochloric acid, nitric acid, and sulfuric acid. 07.2 requires calculating the mass of ammonium nitrate fertiliser spread per square metre of land given 40 bags of 600 kg each spread over 800,000 square metres. 07.3 asks to suggest one reason why a scientist's conclusion about ammonium nitrate improving crop growth might not be valid when they work for the manufacturer. 07.4 asks how many nitrogen atoms are present in the formula K2NH4PO4. 07.5 asks to select from Hydrogen, Oxygen, and Phosphorus which other element in K2NH4PO4 is important for good crop growth. 07.6 asks for the term given to a mixture of different compounds in fixed proportions.
Question text

07 This question is about fertilisers.

Ammonium nitrate is a fertiliser containing nitrogen.

07.1 Complete the sentence.

Choose the answer from the box.

[1 mark]

hydrochloric acid nitric acid sulfuric acid

Ammonium nitrate is produced by reacting ammonia with

.

07.2 Ammonium nitrate fertiliser is sold in 600 kg bags.

A farmer spreads 40 bags of ammonium nitrate fertiliser on land with an area

of 800 000 m2.

Calculate the mass of ammonium nitrate fertiliser spread per m2 of land.

[2 marks]

32 Mass per m2 = kg/m2

07.3 A scientist works for a company which makes ammonium nitrate fertiliser.

The scientist investigates the effect of different fertilisers on crop growth.

The scientist concludes that the ammonium nitrate fertiliser improves crop growth

more than other fertilisers.

Suggest one reason why this conclusion might not be valid.

[1 mark]

A different fertiliser containing nitrogen has the formula K2NH4PO4

*0317.*4 How many atoms of nitrogen are in the formula K2NH4PO4?

[1 mark]

07.5 Nitrogen and potassium in the fertiliser K2NH4PO4 are important for good crop growth.

Which other element in the fertiliser K2NH4PO4 is important for good crop growth?

[1 mark]

Tick ( ) one box.

Hydrogen

Oxygen

Phosphorus

07.6 Some fertilisers are mixtures of different compounds in fixed proportions.

What name is given to a mixture of different compounds in fixed proportions?

[1 mark]

Mark scheme

Show the mark scheme Mark scheme for Question 7 detailing acceptable answers across 7 total marks: 07.1 gives 1 mark for 'nitric acid'; 07.2 awards 1 mark for the working (40 × 600) / 800 000 and 1 mark for the answer 0.03 (kg/m²); 07.3 awards 1 mark for '(the scientist might be) biased' or '(there was) no peer review' (allowing not repeated by others); 07.4 gives 1 mark for 'one / 1'; 07.5 gives 1 mark for 'phosphorus'; 07.6 gives 1 mark for 'formulation'.

Question 7

AO /

Question Answers Extra information Mark

Spec. Ref.

07.1 nitric acid 1 AO2

4.10.4.2

AO /

Spec. Ref.

07.2 (mass =) AO2

40 × 600 1 4.10.4.2

800 000

= 0.03 (kg/m2) 1

AO /

Spec. Ref.

07.3 (the scientist might be) biased 1 AO3

or 4.10.4.2

(there was) no peer review allow the investigation was not

repeated (by others)

AO /

Spec. Ref.

07.4 one / 1 1 AO2

4.10.4.2

AO /

Spec. Ref.

07.5 phosphorus 1 AO2

4.10.4.2

AO /

Spec. Ref.

07.6 formulation 1 AO1

4.8.1.2

4.10.4.2

Total Question 7 7

How to answer it

AQA GCSE Chemistry: Agricultural Fertilisers & Formulations

Complete question walkthrough, mark scheme breakdown, and tutor tips
📌 What this question tests

This question focuses on Topic 10: Using Resources (specifically fertilisers and NPK values) and touches upon fundamental concepts from Topic 8: Chemical Analysis (formulations) and Working Scientifically.

  • Naming the acid used to make ammonium nitrate ( HNO₃ ).
  • Carrying out a multi-step mass calculation per unit area.
  • Evaluating the validity of claims made by commercial scientists (scientific bias and peer review).
  • Interpreting chemical formulae to count specific atoms.
  • Recalling the three essential plant nutrients found in NPK fertilisers.
  • Recalling the definition of a chemical formulation.
Part (a) • Question 07.1

Acid for Ammonium Nitrate Production

1 Mark • Assessment Objective: AO2 (Specification: 4.10.4.2)

✅ Correct Answer

nitric acid

awarded [1 mark] for selecting the correct acid from the box.

💡 Key Knowledge

Fertiliser salts are produced by neutralisation reactions between ammonia and an acid:

  • Ammonia + nitric acid → ammonium nitrate
  • Ammonia + sulfuric acid → ammonium sulfate
  • Ammonia + hydrochloric acid → ammonium chloride

🧠 Exam Technique

Look at the name of the salt to deduce the acid: any salt ending in nitrate must come from nitric acid.

❌ Common Errors

Selecting sulfuric acid because students vaguely remember it is used in industry, without matching the "nitrate" part of the product name.

Part (b) • Question 07.2

Calculating Fertiliser Mass per Area

2 Marks • Assessment Objective: AO2 (Specification: 4.10.4.2)

📐 Step-by-Step Calculation

  1. Step 1: Calculate the total mass of fertiliser spread
    Number of bags = 40
    Mass of each bag = 600 kg
    Total mass = 40 × 600 kg = 24 000 kg [1 mark]
  2. Step 2: Divide total mass by total area
    Area = 800 000 m²
    Mass per m² = 24 000 kg ÷ 800 000 m² = 0.03 kg/m² [1 mark]
Both marks can be awarded in one step: (40 × 600) / 800 000 = 0.03

🧠 Exam Technique

Always check the units required on the answer line. Here it asks for kg/m² , matching the quantities given in the question (kg and m²), so no unit conversions (e.g. into grams) are needed.

❌ Common Calculation Traps

  • Forgetting to multiply by 40 bags (calculating for only 1 bag: 600 ÷ 800 000).
  • Inverting the division (dividing area by mass: 800 000 ÷ 24 000 = 33.3).
  • Miscounting zeros on your calculator when entering 800 000.
Part (c) • Question 07.3

Evaluating Scientific Validity & Bias

1 Mark • Assessment Objective: AO3 (Specification: 4.10.4.2)

✅ Correct Answer (Any one of)

  • (The scientist might be) biased
  • (There was) no peer review
  • The investigation was not repeated by other scientists / independently
awarded [1 mark] for identifying a valid reason affecting scientific validity.

💡 Key Knowledge

Commercial scientists work for a company that sells products. They have a financial incentive for their company's product to look best. To be accepted as fully valid, scientific claims must be:

  • Subject to independent peer review.
  • Reproduced and verified by independent researchers.

❌ Common Errors

Vague answers such as "they might have lied" or "they didn't test all crops". Use the precise scientific terms: bias or lack of peer review.

🧠 Exam Technique

Whenever a question states that a scientist "works for a company that makes/sells" the product under test, the examiner is prompting you to identify commercial bias.

Part (d) • Question 07.4

Interpreting Chemical Formulae

1 Mark • Assessment Objective: AO2 (Specification: 4.10.4.2)

✅ Correct Answer

1 (or one)

awarded [1 mark]

💡 Formula Breakdown: K₂NH₄PO₄

  • K₂ = 2 Potassium atoms
  • N = 1 Nitrogen atom (no subscript means 1)
  • H₄ = 4 Hydrogen atoms
  • P = 1 Phosphorus atom
  • O₄ = 4 Oxygen atoms

❌ Common Errors

Writing 4 because students see the subscript 4 directly following NH₄ and assume it applies to the nitrogen rather than the hydrogen.

🧠 Exam Technique

Subscripts apply ONLY to the element directly before them. If there is no subscript written after a capital letter, the count is always 1.

Part (e) • Question 07.5

Identifying Plant Nutrients in NPK Fertilisers

1 Mark • Assessment Objective: AO2 (Specification: 4.10.4.2)

✅ Correct Answer

[ ] Hydrogen
[ ] Oxygen
[✓] Phosphorus

awarded [1 mark] for ticking Phosphorus only.

💡 Key Knowledge: The N-P-K Elements

NPK fertilisers provide the three main mineral nutrients plants require for healthy growth:

  • N = Nitrogen (for healthy leaves and growth)
  • P = Phosphorus (for root development and flowers)
  • K = Potassium (for disease resistance and fruit growth)

❌ Common Errors

Ticking oxygen or hydrogen because they are present in the formula. While plants need them, they are supplied via air and water ( CO₂ and H₂O ), not as the key nutrient supplied by NPK fertilisers.

Part (f) • Question 07.6

Definition of a Formulation

1 Mark • Assessment Objective: AO1 (Specification: 4.8.1.2 & 4.10.4.2)

✅ Correct Answer

formulation

awarded [1 mark]

💡 Definition to Memorise

A formulation is a mixture that has been designed as a useful product. In a formulation, each chemical component is present in carefully measured, fixed quantities to ensure the product has the required properties.

Examples from the GCSE course: Fertilisers, medicines, paints, cleaning agents, fuels, and foods.

❌ Common Errors

Writing "compound", "molecule", or "alloy". While an alloy is a type of formulation, the universal scientific term tested across Paper 2 for a designed mixture is formulation.

🧠 Exam Technique

The clue is right in the question prompt: "a mixture of different compounds in fixed proportions". Learn this definition word-for-word, as it appears regularly on Paper 2!

Topics

Chemistry · C10: Using Resources · C8: Chemical Analysis

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), June 2022. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.