AQA GCSE Chemistry Chemistry Paper 2 (Foundation), June 2024: Question 4

13 marks · Low Demand difficulty · Short Answer

Describe changes in atmospheric nitrogen from a graph, recall details of photosynthesis, and identify properties of naturally occurring polymers including DNA and glucose polymers.

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Question

Question 4 contains a line graph showing the estimated percentage of nitrogen in the Earth's atmosphere against the age of the Earth in billions of years, starting near 5% at 0.0 billion years, rising steadily to 80% around 2.3 billion years, and remaining constant at 80% until 4.0 billion years. Sub-questions ask to describe the graph's trend, recall the effect and energy source of photosynthesis, identify organisms that photosynthesise, select polymers made from glucose (cellulose and starch), convert DNA's relative formula mass of 140,000,000,000 into standard form, calculate the mass of one chain, and recall DNA's double helix shape and number of nucleotides.
Question text

04 This question is about the Earth’s atmosphere and naturally occurring polymers.

04.1 Figure 5 shows how the estimated percentage of nitrogen in the Earth’s atmosphere

has changed since the Earth was formed.

Figure 5

Describe the trends shown by the graph.

Use data from Figure 5.

[3 marks]

The percentage of oxygen in the Earth’s atmosphere has increased since the Earth

was formed.

This is because of photosynthesis.

The word equation for the photosynthesis reaction is:

carbon dioxide + water → glucose + oxygen

04.2 What happened to the percentage of carbon dioxide in the atmosphere when

photosynthesis began?

[1 mark]

Tick ( ) one box.

The percentage of carbon dioxide decreased.

The percentage of carbon dioxide stayed the same.

The percentage of carbon dioxide increased.

04.3 The photosynthesis reaction takes in energy from the surroundings.

Complete the sentence.

Choose the answer from the box.

[1 mark]

carbon dioxide light water

The source of the energy used in photosynthesis is17 .

04.4 Which two produce oxygen by photosynthesis?

[2 marks]

Tick ( ) two es.

Algae

Animals

Plants

Viruses

Yeast

04.5 The glucose produced during photosynthesis can form naturally occurring polymers.

Which two are naturally occurring polymers that can be produced from glucose?

[2 marks]

Tick ( ) two es.

Cellulose

DNA

Poly(propene)

Protein

Starch 18

DNA molecules contain two polymer chains.

A DNA molecule has a relative formula mass (Mr) of approximately 140 000 000 000

04.6 What is the approximate relative formula mass (Mr) of the DNA molecule in

standard form?

[1 mark]

Tick ( ) one box.

1.4 × 109

*17* 10

1.4 × 10

1.4 × 1011

1.4 × 1012

04.7 What is the approximate relative formula mass (Mr) of each polymer chain in the

DNA molecule?

[1 mark]

Tick ( ) one box.

70 000 000 000

140 000 000 000

280 000 000 000

560 000 000 000

04.8 Complete the sentence.

[1 mark]

The shape of a DNA molecule is a double19 .

04.9 How many different nucleotides are present in a molecule of DNA?

[1 mark]

Tick ( ) one box.

*18* 1

Mark scheme

Show the mark scheme Mark scheme for Question 4 listing marks for 04.1 to 04.9. 04.1 awards 3 marks for: percentage of nitrogen increases, until 2.3 billion years (allow 2.1 to 2.4 or until 80%), then remains constant. 04.2: percentage of carbon dioxide decreased (1 mark). 04.3: light (1 mark). 04.4: algae and plants (2 marks). 04.5: cellulose and starch (2 marks). 04.6: 1.4 x 10^11 (1 mark). 04.7: 70 000 000 000 (1 mark). 04.8: helix (1 mark). 04.9: 4 (1 mark). Total 13 marks.

Question 4

AO /

Question Answers Extra information Mark

Spec. Ref.

04.1 percentage of nitrogen 1 AO2

increases 4.9.1.2

until 2.3 billion years allow a value in the range 2.1 to 1

2.4 billion years

allow until 80%

then remains constant 1

AO /

Spec. Ref.

04.2 the percentage of carbon 1 AO1

dioxide decreased 4.9.1.4

AO /

Spec. Ref.

04.3 light 1 AO1

4.9.1.3

AO /

Spec. Ref.

04.4 algae 1 AO1

4.9.1.3

plants 1

AO /

Spec. Ref.

04.5 cellulose 1 AO1

4.7.3.4

starch – – 1 –

AO /

Spec. Ref.

11 13

04.6 1.4 × 10 1 AO2

4.3.1.2

4.7.3.4

AO /

Spec. Ref.

04.7 70 000 000 000 1 AO2

4.7.3.4

AO /

Spec. Ref.

04.8 helix 1 AO1

4.7.3.4

AO /

Spec. Ref.

04.9 4 1 AO1

4.7.3.4

Total Question 4 13

How to answer it

Earth's Atmosphere & Naturally Occurring Polymers

📋 What this question tests

This question assesses key foundational ideas from AQA GCSE Chemistry: The Earth's Atmosphere (Topic 9) and Organic Chemistry: Synthetic & Naturally Occurring Polymers (Topic 7). You are tested on:

  • Describing graph trends using data and identifying plateaus (nitrogen accumulation).
  • Understanding how photosynthesis by plants and algae altered early atmospheric gases (decreasing CO₂ and producing O₂).
  • Identifying natural polymers formed from glucose (starch and cellulose).
  • Recalling the core structural features of DNA (double helix, 4 distinct nucleotides) and carrying out standard form and proportional mass calculations.
Part 04.1 • 3 Marks

Describing Atmospheric Nitrogen Trends

Data interpretation: Percentage of nitrogen vs. age of the Earth

✅ Correct Answer Breakdown

A full 3-mark response requires three clear features:

  1. Trend 1: The percentage of nitrogen increases / rises. [1 mark]
  2. Turning point: Until 2.3 billion years (allow values from 2.1 to 2.4 billion years, or stating "until 80%"). [1 mark]
  3. Trend 2: It then remains constant / levels off / stays the same. [1 mark]

🧠 Exam Technique: Two-Phase Graphs

Whenever a line graph curves and flattens out, you must describe both phases plus the inflection point:

  • What happens first? (increases rapidly)
  • Where does the change happen? (at 2.3 billion years)
  • What happens after that? (stays flat at 80%)

❌ Common Errors

  • Writing just "it goes up" without stating that it eventually levels off.
  • Failing to quote data from the horizontal axis (e.g. omitting 2.3 billion years).
  • Saying nitrogen reaches 100% (the plateau is at 80%, corresponding to today's atmosphere).
Parts 04.2 – 04.4 • 4 Marks Total

Photosynthesis and the Evolution of the Atmosphere

Word equation provided: carbon dioxide + water → glucose + oxygen

✅ Correct Answers

04.2 (1 mark): What happened to atmospheric CO₂?

☑ The percentage of carbon dioxide decreased.

04.3 (1 mark): Source of energy for photosynthesis:

light (taken in from surroundings)

04.4 (2 marks): Two organisms producing O₂ via photosynthesis:

☑ Algae [1 mark]
☑ Plants [1 mark]

💡 Key Knowledge

  • Early Earth: The atmosphere was mainly CO₂ with little to no O₂.
  • Algae first evolved around 2.7 billion years ago; photosynthesis took in CO₂ and released O₂.
  • Over the next billion years, green plants evolved, further decreasing CO₂ and increasing O₂ to levels that enabled animals to evolve.
  • Photosynthesis is endothermic—it absorbs energy transferred by light.

❌ Common Errors

  • Ticking Yeast: Yeast is a fungus; it respires (often anaerobically) and produces CO₂, not oxygen.
  • Ticking Viruses: Viruses are non-cellular entities that cannot carry out metabolic processes like photosynthesis.
Part 04.5 • 2 Marks

Naturally Occurring Polymers from Glucose

Identifying condensation polymers made from sugar monomers

✅ Correct Answers

Tick two boxes:

☑ Cellulose [1 mark]

☑ Starch [1 mark]

💡 Key Knowledge: Natural Polymers

Polymer Monomer
Starch & Cellulose Glucose (monosaccharide)
Proteins Amino acids
DNA Nucleotides
Poly(propene) Propene (synthetic addition polymer)
Parts 04.6 – 04.7 • 2 Marks Total

DNA Relative Formula Mass (Mᵣ) & Standard Form

Data: A DNA molecule has Mᵣ ≈ 140 000 000 000 and contains two chains

📐 Step-by-Step Calculations

04.6 Standard Form Conversion:

  1. Number: 140 000 000 000
  2. Place the decimal point between 1 and 4: 1.4
  3. Count places shifted to the left: 11 places.
  4. Result: 1.4 × 10¹¹
Correct tick: 1.4 × 10¹¹ [1 mark]

04.7 Mass of Each Polymer Chain:

  1. DNA consists of two polymer chains.
  2. Mass per chain = 140 000 000 000 ÷ 2
  3. Result = 70 000 000 000
Correct tick: 70 000 000 000 [1 mark]

❌ Common Errors

  • Counting zeros instead of powers: There are 10 zeros in 140 000 000 000, so students mistakenly select 1.4 × 10¹⁰. Remember that the "4" also counts as a place shift!
  • Multiplying instead of dividing in 04.7: Doubling to 280 000 000 000 instead of halving for an individual chain.
Parts 04.8 – 04.9 • 2 Marks Total

Structure of DNA

Core recall facts about the double helix and nucleotides

✅ Correct Answers

04.8 (1 mark): The shape of a DNA molecule is a double ________.

helix

04.9 (1 mark): Number of different nucleotides in a DNA molecule:

☑ 4

💡 Key Knowledge: DNA Specifications

  • DNA (Deoxyribonucleic acid) encodes genetic instructions for development and functioning of living organisms.
  • Most DNA molecules are two polymer chains made from four different monomers called nucleotides (bases A, T, C, G).
  • The two strands wrap around each other to form a double helix structure.

Topics

Chemistry · C7: Organic Chemistry · C9: Chemistry of the Atmosphere

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 2 (Foundation), June 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.