AQA GCSE Chemistry Chemistry Paper 1 (Foundation), June 2025: Question 6

9 marks · Standard Demand difficulty · Short Answer

Identify fullerenes and calculate the volume and surface area to volume ratio of a cubic nanoparticle.

Practise this question

Question

Question 6 consists of five parts about nanoparticles. Figure 9 shows a spherical hollow cage of carbon atoms (buckminsterfullerene). Questions 06.1 and 06.2 ask to identify the nanoparticle and explain why it is slippery from multiple-choice options. Question 06.3 asks how many times larger 1500 nm is compared to 15 nm, choosing from powers of 10. Question 06.4 shows Figure 10, a cube with side lengths of 4 nm, and asks to calculate its volume and simplest whole number ratio of surface area to volume given a surface area of 96 nm². Question 06.5 requires filling in two blanks about the thickness and light transmission of a nanoparticle scratchproof coating.
Question text

06 This question is about nanoparticles.

Figure 9 represents a type of nanoparticle made of carbon atoms.

Figure 9

06.1 What is the name of the type of nanoparticle in Figure 9?

[1 mark]

Tick ( ) one box.

Buckminsterfullerene

Carbon nanotube

Graphene

06.2 Nanoparticles of the type in Figure 9 are slippery.

Which structural feature of these nanoparticles makes them slippery?

[1 mark]

Tick ( ) one box.

The nanoparticles are hollow.

The nanoparticles are made of carbon atoms.

The nanoparticles are spherical. 25

06.3 A nanoparticle of a metal has a diameter of 15 nm.

*24A fine particle of the metal has a diameter of 1500 nm.*

How many times larger is the diameter of the fine particle than the diameter of

the nanoparticle?

[1 mark]

Tick ( ) one box.

10 102 103 104

06.4 Figure 10 represents a cubic nanoparticle.

Figure 10

The surface area of the cubic nanoparticle is 96 nm2.

Calculate:

• the volume of the cubic nanoparticle

• the simplest whole number ratio of surface area : volume

for the cubic nanoparticle.

The volume of a cube = (length of side)3

[4 marks]

Volume of nanoparticle = nm3

Ratio of surface area : volume = :

Simplest whole number ratio of surface area : volume =26 :

06.5 A substance can be used to provide a scratchproof coating on reading glasses.

The coating is a single layer of particles of the substance.

Nanoparticles are used instead of normal-sized particles.

Complete the sentences.

[2 marks]

When using nanoparticles instead of normal-sized particles, the thickness of the

layer that can be used is much .

This means the amount of light passing through the layer is .

Mark scheme

Show the mark scheme Mark scheme for Question 6: 06.1 awards 1 mark for 'Buckminsterfullerene'. 06.2 awards 1 mark for 'the nanoparticles are spherical'. 06.3 awards 1 mark for '10²'. 06.4 awards 4 marks: 1 mark for (volume =) 4³, 1 mark for 64 (nm³), 1 mark for 96 : 64, and 1 mark for 3 : 2 (with error carried forward allowed). 06.5 awards 2 marks: 1 mark for 'thinner / smaller / less' and 1 mark for 'greater / more'. Total marks: 9.

Question 6

AO /

Question Answers Extra information Mark

Spec. Ref.

06.1 Buckminsterfullerene 1 AO1

4.2.3.3

AO /

Spec. Ref.

06.2 the nanoparticles are spherical 1 AO3

4.2.3.3

4.2.4.2

AO /

Spec. Ref.

06.3 102 1 AO2

4.2.4.1

AO /

Spec. Ref.

06.4 (volume = ) 43 1 AO2

4.2.4.1

= 64 (nm3) 1

(surface area : volume ratio =)

96 : 64 allow correct use of an 1

incorrectly determined volume

= 3 : 2 allow correct use of an 1

incorrectly determined surface

area : volume ratio

AO /

Spec. Ref.

06.5 thinner / smaller / less 1 AO3

4.2.4.1

4.2.4.2

greater / more 1

Total Question 6 9

How to answer it

Nanoparticles: Fullerenes, Scale, Ratios & Applications

📋 What this question tests

This question assesses key specifications from AQA C2 (Bonding, Structure, and the Properties of Matter): identifying allotropes of carbon (fullerenes), explaining lubricating properties based on molecular shape, understanding particle scale and powers of 10, calculating volume and simplest whole-number surface area-to-volume ( SA:V ) ratios, and applying nanoparticle properties to practical uses (transparent coatings).

Question 06.1: Identifying Carbon Allotropes

1 Mark • AO1 (Recall)

✅ Correct Answer

Buckminsterfullerene (first box ticked)

Award 1 mark for correctly identifying the spherical fullerene.

💡 Key Knowledge

  • Buckminsterfullerene (C₆₀): A spherical hollow molecule made of 60 carbon atoms arranged in pentagons and hexagons.
  • Carbon nanotubes: Cylindrical fullerenes with very high length-to-diameter ratios.
  • Graphene: A single 2D layer of carbon atoms arranged in a hexagonal lattice.

Question 06.2: Lubricating Properties of Fullerenes

1 Mark • AO3 (Analysis & Reasoning)

✅ Correct Answer

The nanoparticles are spherical. (third box ticked)

Award 1 mark for linking the spherical shape to being slippery.

🧠 Exam Technique

Always link function to geometry. Fullerenes act like microscopic ball bearings. Because they are spherical, individual molecules can roll over each other, reducing friction.

❌ Common Errors

Choosing "The nanoparticles are hollow" or "made of carbon atoms". While both statements are scientifically true, they do not explain why fullerenes are slippery lubricants.

Question 06.3: Comparing Scales & Powers of 10

1 Mark • AO2 (Application of Scale)

✅ Correct Answer

10² (second box ticked)

Award 1 mark for selecting the correct order of magnitude.

📐 Step-by-Step Working

Compare the diameter of the fine particle to the nanoparticle:

Scale factor = 1500 nm ÷ 15 nm = 100

Express 100 as a power of 10:

100 = 10 × 10 = 10²

❌ Common Errors

Counting zeros incorrectly or confusing the power. Remember: 10¹ = 10, 10² = 100, 10³ = 1000.

Question 06.4: Cube Volume and Surface Area-to-Volume Ratio

4 Marks • AO2 (Multi-Step Calculation)

📐 Step-by-Step Calculation

Step 1: Calculate Volume of Cube
Given side length = 4 nm
Volume = (side)³ = 4³ = 4 × 4 × 4 = 64 nm³
[2 marks: 1 for formula/substitution 4³, 1 for answer 64]
Step 2: State the Unsimplified Ratio
Surface area = 96 nm² (given), Volume = 64 nm³
Surface area : Volume = 96 : 64
[1 mark: allow error carried forward from Step 1]
Step 3: Simplify to Simplest Whole Number Ratio
Divide both sides by their highest common factor (32):
96 ÷ 32 = 3 and 64 ÷ 32 = 2
Simplest ratio = 3 : 2
[1 mark]

✅ Final Mark Scheme Answers

  • Volume = 64 nm³
  • Ratio = 96 : 64
  • Simplest whole number ratio = 3 : 2
Total: 4 marks

❌ Common Errors & Traps

  • Reversing the ratio: Writing 2 : 3 (volume : surface area) instead of 3 : 2 . Read the question order carefully!
  • Not fully simplifying: Leaving the answer as 48 : 32 , 24 : 16 , or 12 : 8 loses the final mark.
  • Decimal form: Writing 1.5 : 1 is mathematically equal, but the question explicitly asked for simplest whole number ratio.

Question 06.5: Applications of Nanoparticles in Coatings

2 Marks • AO3 (Scientific Reasoning & Application)

✅ Correct Answer

When using nanoparticles instead of normal-sized particles, the thickness of the layer that can be used is much thinner / smaller / less. [1 mark]

This means the amount of light passing through the layer is greater / more / higher. [1 mark]

💡 Why Nanoparticles Work Here

  • Nanoparticles are tiny (1 to 100 nm). A single monolayer of nanoparticles creates an extraordinarily thin film.
  • Normal-sized particles create thicker, irregular layers that scatter or absorb visible light, making the glass cloudy or opaque.
  • Thinner coatings let significantly more light transmit through, keeping the lenses completely transparent while providing scratch resistance.

🧠 Exam Technique

Always think about the context: these are reading glasses! The wearer needs maximum light to read clearly, so any protective layer must allow maximum light transmission.

Topics

Chemistry · C2: Bonding, Structure and the Properties of Matter

Question and mark scheme from the AQA GCSE Chemistry examination, Chemistry Paper 1 (Foundation), June 2025. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.