AQA GCSE Combined Science: Trilogy Chemistry Paper 2 (Foundation), November 2020: Question 5

9 marks · Low Demand difficulty · Short Answer

Identify mixtures and formulations, match phases in paper chromatography, interpret a chromatogram, and calculate an Rf value.

Practise this question

Question

Question 05 contains five parts: 05.1 asks to select which substance is a mixture among Air, Gold, Methane, and Nitrogen; 05.2 asks what name is given to mixtures designed as useful products; 05.3 provides a diagram of chromatography apparatus (beaker with solvent, chromatography paper, start line, dyes A, B, C and purple food colouring Y) and asks to draw lines matching 'Mobile phase' and 'Stationary phase' to options (Beaker, Chromatography paper, Food colouring, Pencil line, Solvent); 05.4 displays a developed chromatogram showing Dye A with one spot, Dye B with one spot, Dye C with one spot, and Food colouring Y with three spots, asking for three conclusions; 05.5 gives distances moved by dye G (60 mm) and solvent (80 mm) and the Rf formula to calculate the Rf value.
Question text

05 This question is about mixtures.

05.1 Which substance is a mixture?

[1 mark]

Tick ( ) one box.

Air Gold Methane Nitrogen

05.2 Food colourings are often mixtures of dyes.

What name is given to mixtures that are designed as useful products?

[1 mark]

A student investigated a purple food colouring, Y, using chromatography.

The student compares Y with dyes A, B and C.

05.3 Figure 8 shows the apparatus used.

Figure 8

Chromatography involves a stationary phase and a mobile phase.

Draw one line from each phase to what is used for that phase.

*18* Use Figure 8.

[2 marks]

Phase What is used

Beaker

Chromatography paper

Mobile phase

Food colouring

Stationary phase

Pencil line

20 Solvent

Figure 9 shows the student’s results.

Figure 9

05.4 What three conclusions can you make about the dyes in food colouring Y?

[3 marks]

05.5 In a different experiment a student recorded these results:

Distance moved by dye G = 60 mm

Distance moved by solvent = 80 mm

Calculate the Rf value of dye G.

distance moved by dye G

Rf =

distance moved by solvent

[2 marks]

Rf =

Mark scheme

Show the mark scheme Mark scheme for Question 05: 05.1 gives 'air' (1 mark); 05.2 gives 'formulation(s)' (1 mark); 05.3 matches 'Mobile phase' to 'Solvent' and 'Stationary phase' to 'Chromatography paper' (1 mark each); 05.4 accepts that Y contains 3 dyes, Y contains 2 known dyes (or contains A and C), and Y contains an unknown dye (or does not contain B), with an alternative approach accepted (3 marks total); 05.5 awards 1 mark for substitution 60/80 and 1 mark for the answer 0.75.

AO /

Question Answers Extra information Mark

Spec. Ref.

05.1 air 1 AO1

5.8.1.1

05.2 formulation(s) 1 AO1

5.8.1.2

05.3 AO2

5.8.1.3

additional line from a box on the left negates the mark for that box

allow colour for dyes

05.4 AO3

Y contains 3 dyes 1 5.8.1.3

Y contains 2 known dyes allow Y contains A and C 1

Y contains an unknown dye allow Y does not contain dye B 1

alternative approach:

Y contains 3 dyes (1)

Y contains 1 known dye (1) allow Y contains dye C

Y contains 2 unknown dyes (1) allow Y does not contain dyes

A and B

05.5 60 AO2

(Rf =) 1

80 5.8.1.3

= 0.75 ignore units 1

Total 9

How to answer it

Mixtures, Formulations and Paper Chromatography

What this question tests
  • Substance classification: Distinguishing pure elements and compounds from mixtures.
  • Formulations: Recalling the key definition of a formulation.
  • Chromatography basics: Identifying the stationary phase and mobile phase in paper chromatography.
  • Interpreting chromatograms: Matching dye spots by height and determining pure vs mixture samples.
  • Rf calculations: Using the given formula to calculate retention factors accurately.
Part 05.1 • 1 Mark

Identifying a Mixture

Question: Which substance is a mixture? (Air / Gold / Methane / Nitrogen)

✅ Correct Answer

Air

💡 Key Knowledge

  • Air is a mixture of unbonded gases (nitrogen, oxygen, argon, carbon dioxide, water vapour).
  • Gold (Au) and Nitrogen (N₂) are elements.
  • Methane (CH₄) is a chemical compound.

❌ Common Errors

Students sometimes confuse nitrogen (an element making up ~78% of air) with air itself, or mistake methane for a mixture because it has two elements bonded together.

Mark scheme: [1 mark] for ticking the box for Air only.
Part 05.2 • 1 Mark

Useful Mixtures

Question: What name is given to mixtures that are designed as useful products?

✅ Correct Answer

Formulation (or formulations)

💡 Key Knowledge

A formulation is a complex mixture designed with exact quantities of specific chemicals to create a product with desired properties (e.g. paints, medicines, fuels, fertilisers, foods).

🧠 Exam Technique

This is direct AQA specification recall. Memorise the exact phrase: "A formulation is a mixture that has been designed as a useful product."

Mark scheme: [1 mark] for formulation(s). Any other generic term like "solution" or "compound" scores 0.
Part 05.3 • 2 Marks

Phases in Chromatography

Question: Draw one line from each phase to what is used for that phase.

✅ Correct Matching

PhaseWhat is used
Mobile phase➔ Solvent
Stationary phase➔ Chromatography paper

💡 Key Knowledge

  • Mobile phase: Moves through the setup carrying the dissolved substances (the liquid solvent, e.g. water or ethanol).
  • Stationary phase: Does not move (the paper).

🧠 Exam Technique & Traps

Read instructions carefully: "Draw one line from each phase". If you draw two lines from a single left-hand box, you negate (lose) the mark for that box even if one is correct!

Mark scheme: [1 mark] for mobile phase → solvent; [1 mark] for stationary phase → chromatography paper.
Part 05.4 • 3 Marks

Interpreting the Chromatogram

Question: What three conclusions can you make about the dyes in food colouring Y?

✅ Correct Answers (Any three)

  1. Y contains 3 dyes (or 3 colours).
  2. Y contains dye C (the lowest spot aligns exactly with Dye C).
  3. Y contains dye A (the middle spot aligns with Dye A) OR state that Y contains 2 known dyes.
  4. Y contains an unknown dye (the top spot does not match A, B, or C).
  5. Y does not contain dye B (no spot at the height of B).

🧠 How to Read a Chromatogram

  • Count the spots: Each spot directly above a sample represents a different dye. Column Y has 3 vertical spots = 3 dyes.
  • Check horizontal alignment: If a spot in Y lines up horizontally with a spot from a known dye, Y contains that dye.
  • Look for missing spots: No spot lines up with dye B, so dye B is absent.

❌ Common Errors

  • Saying "Y is a pure dye" (it clearly separates into three distinct spots, so it is a mixture).
  • Forgetting to state that one of the dyes is unknown or not from A, B, or C.
Mark scheme: [3 marks total]. 1 mark per distinct valid conclusion. Both standard analysis (contains A, C, and 1 unknown) and alternative reading (contains C and 2 unknowns) receive full credit.
Part 05.5 • 2 Marks

Calculating Retention Factor (Rf)

Question: Calculate the Rf value of dye G.

Given data: Distance moved by dye G = 60 mm | Distance moved by solvent = 80 mm

🔧 Step-by-Step Calculation

  1. Write down the formula:
    Rf = distance moved by substance ÷ distance moved by solvent
  2. Substitute the numbers:
    Rf = 60 ÷ 80
  3. Calculate and simplify:
    Rf = 0.75 (or 3/4 )

💡 Key Knowledge: Rf Rules

  • No units: Rf is a ratio of two distances, so it has no units.
  • Range check: An Rf value must always be between 0 and 1. If you get a value greater than 1, you divided upside down!

❌ Common Calculation Traps

  • Dividing solvent by dye ( 80 ÷ 60 = 1.33 ). Always double-check that your Rf ≤ 1.
  • Trying to convert units when both are already in the same unit ( mm ).
Mark scheme: [1 mark] for substitution 60 ÷ 80 , [1 mark] for final answer 0.75 . Ignore units if given.

Topics

Chemistry · C8: Chemical Analysis

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 2 (Foundation), November 2020. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.