AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Higher), 2021: Question 1

8 marks · Standard Demand difficulty · Short Answer

Answer questions on the periodic table, atomic models, isotopes, and calculate the relative atomic mass of potassium from isotope abundances.

Practise this question

Question

A Chemistry exam page headed 'This question is about the periodic table' contains five parts worth 8 marks in total. Figure 1 shows part of Mendeleev’s periodic table as a grid with symbols including H, Li, Be, B, C, N, O, F, Na, Mg, Al, Si, P, S, Cl, K, Ca, Cu, Zn, Ti, V, Cr, Mn, Fe, Co, Ni, Rb, Sr, Ag, Cd, Y, In, Zr, Nb, Sn, Sb, Mo, Te, Pd, Ru, Rh, and I, followed by a 1-mark question asking which group had not been discovered when Mendeleev’s table was published. Figure 2 shows four atom models labelled A to D: A has a central nucleus with positive particles and electrons on shells, B is a shaded sphere with embedded negative electrons, C is a solid dark circle, and D has a central 4+ nucleus with orbiting electrons; students are asked in two separate 1-mark tick-box questions which model is the plum pudding model and which resulted from Chadwick’s work. The page then states potassium has different isotopes and asks for a 2-mark definition of isotopes referring to subatomic particles, followed by Table 1 listing mass numbers 39 and 41 with percentage abundances 93.1 and 6.9, and a 3-mark calculation of the relative atomic mass of potassium to 1 decimal place with working space and an answer line.
Question text

01 This question is about the periodic table.

01.1 Figure 1 shows part of Mendeleev’s version of the periodic table.

Figure 1

Which group of elements had not been discovered when Mendeleev’s version of the

periodic table was published?

[1 mark]

Figure 2 represents different models of the atom.

Figure 2

01.2 Which model represents the plum pudding model?

[1 mark]

Tick ( ) one box.

A B C D

01.3 Which model resulted from Chadwick’s experimental work?

[1 mark]

*02* Tick ( ) one box.

A B C4 D

Potassium has different isotopes.

01.4 What is meant by ‘isotopes’?

You should refer to subatomic particles.

[2 marks]

01.5 Table 1 shows the mass numbers and the percentage abundance of two

isotopes of potassium.

*03* Table 1

Mass number Percentage abundance

39 93.1

41 6.9

Calculate the relative atomic mass (Ar) of potassium.

Give your answer to 1 decimal place.

[3 marks]

Relative atomic mass (1 decimal place) =

Mark scheme

Show the mark scheme The mark scheme is a table with columns for question number, answers, extra information, mark, and AO/specification reference. It gives 01.1 as '(Group) 0' or 'noble gases'; 01.2 as B; 01.3 as A; and for 01.4 it awards one mark for stating atoms have the same number of protons and one mark for stating they have different numbers of neutrons, with notes allowing 'same atomic number' or 'same element' and rejecting references only to different relative atomic mass. For 01.5 it shows the calculation ((39 × 93.1) + (41 × 6.9)) / 100 = 39.138, then 39.1, with marks for correct method, intermediate answer, and final rounded answer, and a note allowing correct rounding from an incorrect calculation using all given values.

AO /

Question Answers Extra information Mark

Spec. Ref.

01.1 (Group) 0 1 AO2

or 5.1.2.2

noble gases

01.2 B 1 AO2

5.1.1.3

01.3 A 1 AO3

5.1.1.3

01.4 (atoms with the) same number allow atoms with the same 1 AO1

of protons atomic number 5.1.1.5

allow atoms of the same

element

ignore the same number of

electrons

(but with) different numbers of ignore (but with) different mass 1

neutrons numbers

do not accept (but with) different

relative atomic mass

01.5 (39 × 93.1) + (41 × 6.9) AO2

100 5.1.1.6

= 39.138 1

= 39.1 allow correctly rounded answer 1

to 1 decimal place from an

incorrect calculation using all the

values given in the question

Total 8

How to answer it

Mendeleev, Atomic Models & Isotopes

What this question tests 8 marks total

You need to know key facts about the periodic table, early atomic models, isotopes, and how to calculate relative atomic mass from percentage abundance. Marks are mostly for correct recall, identifying models, using the right definition, and showing a clear weighted mean calculation.

Question title: Periodic table, atomic models and isotopes

01.1 — Which group had not been discovered when Mendeleev published his table?

✅ Correct answer

Group 0
or noble gases

1 mark for naming the correct group.

💡 Key knowledge

  • Mendeleev arranged elements mostly by atomic mass, before all modern groups were known.
  • The noble gases were discovered later because they are very unreactive and not easy to spot in reactions.

🧠 Exam technique

  • If a question asks for a group, write the group number or the family name.
  • For AQA, Group 0 and noble gases are both accepted.

❌ Common errors

  • Writing Group 7 or halogens — these were already known.
  • Giving a specific element instead of a group.

01.2 — Which model represents the plum pudding model?

✅ Correct answer

B

1 mark for ticking B.

💡 Key knowledge

  • In the plum pudding model, electrons are embedded in a sphere of positive charge.
  • It has no nucleus.

🧠 Exam technique

  • Look for a model with electrons scattered through a positive “blob”.
  • AQA often tests recognition of atomic models by their visual features.

❌ Common errors

  • Choosing the nuclear model with electrons orbiting a central nucleus.
  • Choosing the solid sphere model, which is Dalton’s model.

01.3 — Which model resulted from Chadwick’s experimental work?

✅ Correct answer

A

1 mark for ticking A.

💡 Key knowledge

  • Chadwick discovered the neutron.
  • This led to the modern nuclear model with a nucleus containing protons and neutrons.

🧠 Exam technique

  • Match the model to the scientist’s contribution:
  • Dalton = solid sphere
  • Thomson = plum pudding
  • Rutherford = nuclear model
  • Chadwick = nucleus with neutrons

❌ Common errors

  • Picking the model with electrons in fixed shells but no clear nucleus detail.
  • Confusing Rutherford and Chadwick.

01.4 — What is meant by isotopes?

✅ Correct answer

Atoms of the same element with the same number of protons but different numbers of neutrons.

2 marks: one for same number of protons / same atomic number, one for different numbers of neutrons.

💡 Key knowledge

  • Isotopes are still the same element because the proton number is the same.
  • Different neutrons change the mass number, not the element identity.
  • Atomic number = number of protons.

🧠 Exam technique

  • Use both parts of the definition for full marks.
  • Best answers mention protons and neutrons.
  • You can also say “same atomic number” for same protons.

❌ Common errors

  • Saying “same number of electrons” — not needed and not enough.
  • Saying “different relative atomic mass” — this is not accepted as the definition.
  • Mixing up mass number and atomic number.

01.5 — Calculate the relative atomic mass of potassium

📐 Calculation: step by step

  1. Multiply each mass number by its percentage abundance.
  2. Add the two products.
  3. Divide by 100.
  4. Round to 1 decimal place.

(39 × 93.1) + (41 × 6.9) = 363.9 + 282.9 = 3918? No — carefully calculate:

Correct working:
(39 × 93.1) = 3630.9
(41 × 6.9) = 282.9
3630.9 + 282.9 = 3913.8
3913.8 ÷ 100 = 39.138
Rounded to 1 d.p. = 39.1

3 marks: method, correct calculation, correct final answer to 1 d.p.

✅ Correct answer

39.1

This is the weighted mean of the two isotopes.

💡 Key knowledge

  • Relative atomic mass is a weighted average based on isotope abundance.
  • More abundant isotopes have a bigger effect on the final answer.
  • Potassium-39 is much more common than potassium-41, so the answer is close to 39.

🧠 Exam technique

  • Always include the divide by 100 because the abundances are percentages.
  • Write units carefully if needed, but relative atomic mass is usually unitless.
  • If your arithmetic is slightly wrong but you use all values and round correctly, you may still gain method marks.

❌ Common errors

  • Adding 39 + 41 and dividing by 2 — this ignores abundance.
  • Forgetting to divide by 100.
  • Rounding too early.
  • Using 93.1 and 6.9 as decimal fractions without adjusting the calculation.
  • Arithmetic slip: the products must be 3630.9 and 282.9, not 363.9 and 282.9.

How the marks were awarded

💡 Mark breakdown

  • 01.1: 1 mark for Group 0 / noble gases
  • 01.2: 1 mark for B
  • 01.3: 1 mark for A
  • 01.4: 2 marks for a full isotope definition
  • 01.5: 3 marks for correct method and answer

🧠 What top answers did well

  • Used precise scientific vocabulary: protons, neutrons, atomic number.
  • Recognised atomic models from their features.
  • Showed a clear weighted mean calculation rather than a guess.

❌ Where students lost marks

  • Confusing isotopes with ions or different elements.
  • Mixing up the plum pudding model and the nuclear model.
  • Making an arithmetic slip in the potassium calculation.

Topics

Chemistry · C1: Atomic Structure and the Periodic Table

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Higher), 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.