AQA GCSE Combined Science: Trilogy Physics Paper 1 (Higher), 2021: Question 6

15 marks · Standard Demand difficulty · Extended Answer

Explain and calculate energy transfers in an air source heat pump, including internal energy, latent heat, pressure changes, specific heat capacity and why a claimed 400% efficiency is incorrect.

Practise this question

Question

The question page shows a labelled diagram of an air source heat pump split by a vertical wall, with air outside the building on the left and air inside the building on the right. A pipe containing coolant passes through an evaporator coil on the outside, then through a compressor, condenser coil and decompressor, with labels for evaporator, condenser, compressor, decompressor, pipe and coolant; text explains that energy is transferred from outside air to the liquid coolant, causing its temperature to increase and it to evaporate. Below are six parts: explain how the coolant’s internal energy changes as temperature increases, name the energy needed for the liquid coolant to change state, choose what happens to mass as it evaporates, explain why pressure increases when the compressor increases density and temperature, calculate specific heat capacity using 1560 kJ input energy, 87.5% efficiency, mass 125 kg and temperature rise from 11.6 to 22.1 degrees C in standard form, and explain why an advert claiming 400% efficiency is incorrect when the air gains 400 J for every 100 J from the mains supply.
Question text

06 An air source heat pump transfers energy from the air outside a building to increase

the temperature of the air inside the building.

Figure 13 shows an air source heat pump.

Figure 13

The compressor is connected to the mains electricity supply.

The pipe in the heat pump contains a substance called coolant.

In the evaporator, energy is transferred from the air outside the building to

the liquid coolant.

The temperature of the coolant increases and it evaporates.

06.1 Explain what happens to the internal energy of the coolant as its

temperature increases.

[2 marks]

06.2 What name is given to the energy needed to change the state of the liquid coolant?

[1 mark]

06.3 What happens to the mass of the coolant as it evaporates and becomes

a vapour?

[1 mark]

Tick ( ) one box.

Decreases

Stays the same

Increases

06.4 The compressor increases the density and temperature of the coolant vapour inside

the pipe.

Explain why the pressure in the pipe increases.

[2 marks]

06.5 The condenser transfers energy from the coolant to the air in the building.

When the total energy input to the heat pump system is 1560 kJ the temperature of

the air in the building increases from 11.6 °C to 22.1 °C.

The efficiency of the heat pump system is 87.5%.

The mass of the air inside the building is 125 kg.

Calculate the specific heat capacity of the air in the building.

Give your answer in standard form.

[6 marks]

Specific heat capacity (standard form) =27 J/kg °C

06.6 The air in the building gains 400 J for every 100 J of energy transferred from the

mains electricity supply to the compressor.

An advertisement claims that the heat pump system has an efficiency of 400%.

Explain why the advertisement is not correct.

[3 marks]

Mark scheme

Show the mark scheme The mark scheme is a table with columns for question number, answers, extra information, marks and AO/specification references. It awards marks for stating that particle kinetic energy, and potentially potential energy, increase so internal energy increases; identifying latent heat of vaporisation; choosing that mass stays the same; and explaining pressure rise by more collisions per second and greater force per collision. For the calculation it shows using efficiency = useful output energy transfer divided by total input energy transfer to find 1 365 000 J useful energy, then substituting into 1 365 000 = 125 × c × (22.1 − 11.6), rearranging to get c = 1040 J/kg degrees C or 1.04 × 10^3 J/kg degrees C; the final part states the advert ignores energy input from surrounding air, total input is greater than electrical input alone, and efficiency must be less than 100%.

AO /

Question Answers Extra information Mark

Spec. Ref.

06.1 the kinetic energy (and the allow the speed of the particles 1 AO1

potential energy) of the particles increases 6.3.2.1

increases 6.3.2.3

so the internal energy increases 1

because it is the sum of kinetic

and potential energy (of the

particles)

06.2 latent heat (of vaporisation) allow specific latent heat (of 1 AO1

vaporisation) 6.3.2.3

06.3 stays the same 1 AO1

6.3.1.2

06.4 more collisions per second 1 AO1

6.3.3.1

a greater force per collision 1

06.5 0.875 = allow a correct substitution 1 AO2

useful output energy transfer using incorrectly/not converted

6.1.2.2

1 560 000 values of efficiency and/or

6.1.1.3

energy

6.3.2.2

useful output energy transfer

= 1 365 000(J) this answer only

the equation

efficiency =

useful output energy transfer

total input energy transfer

must have been used to score

subsequent marks

allow a correct substitution

1 365 000 = 125 × c × (22.1–11.6) using their calculated value of

useful output energy

1 365 000 allow a correct re-arrangement

c = using their value of useful 1

125 × 10.5 output energy

allow a correct calculation

c = 1040 (J/kg °C) 1

using with their value of useful

output energy

this mark can only be awarded

c = 1.04 × 10 (J/kg °C) for a calculation using the

correct equations

06.6 the advertisement has ignored the 1 AO3

energy input from the surrounding air

so the total energy input is greater an answer that the total energy 1

than the energy supplied from the input comes from the electricity AO2

electricity supply and the air outside the

building gains the first two

marking points

the efficiency must be less than 1

100% AO1

16 6.1.2.2

Total 15

How to answer it

Air Source Heat Pump

What this question tests

Topic focus: internal energy, latent heat, pressure in gases, specific heat capacity, efficiency, and explaining why heat pumps can seem “over 100% efficient”.

Skills: recall key definitions, use standard equations, rearrange formulas, calculate with units, and explain energy transfers clearly.

Exam tip: Most marks are from short precise statements. For calculations, show substitution, units, and the final answer in standard form.

Question overview

Air source heat pump question

This question uses a heat pump diagram to test how energy is transferred from outside air into a building, and how to calculate the specific heat capacity of air from an energy transfer.

Part (a) 06.1 — Internal energy increases

Explain what happens to the internal energy of the coolant as its temperature increases.

✅ Correct answer

The particles gain kinetic energy, so the internal energy increases.

For full marks you can also say the particles’ potential energy increases, because internal energy is the total of kinetic and potential energy.

Mark focus: 1 mark for kinetic energy increases, 1 mark for stating internal energy increases because it is the sum of kinetic and potential energy.

💡 Key knowledge

  • Internal energy = total kinetic energy + total potential energy of particles.
  • When temperature rises, particles move faster, so kinetic energy increases.
  • At GCSE level, linking temperature rise to faster particles is often enough for the first mark.

🧠 Exam technique

  • Use the phrase internal energy directly.
  • Explain the link: temperature up → particles move faster → kinetic energy up → internal energy up.
  • If you mention potential energy too, that is fine and can strengthen the answer.

❌ Common errors

  • Saying only “temperature increases” without explaining internal energy.
  • Confusing internal energy with heat.
  • Writing that particles “gain heat” instead of gaining kinetic energy.

Part (b) 06.2 — Change of state energy

What name is given to the energy needed to change the state of the liquid coolant?

✅ Correct answer

Latent heat of vaporisation

Accept: specific latent heat of vaporisation

Mark focus: 1 mark for the correct named energy term.

💡 Key knowledge

  • Latent heat is the energy needed for a change of state.
  • Vaporisation means liquid changing to gas.
  • In this question, the coolant evaporates, so the correct term is about vaporisation.

❌ Common errors

  • Writing just “heat” or “energy” — too vague.
  • Mixing up specific heat capacity with latent heat.
  • Writing “latent heat of fusion” — that is melting/freezing, not evaporating.

Part (c) 06.3 — Mass during evaporation

What happens to the mass of the coolant as it evaporates and becomes a vapour?

✅ Correct answer

Stays the same

Mark focus: 1 mark for the correct option.

💡 Key knowledge

  • In a closed system, mass is conserved.
  • Changing state does not change the amount of substance.
  • The particles are still there; they are just further apart in a gas.

🧠 Exam technique

  • For multiple-choice style questions, check whether the question asks about mass, not volume or density.
  • Evaporation changes arrangement and spacing, not total mass.

❌ Common errors

  • Saying it decreases because the gas “spreads out”.
  • Confusing mass with density.
  • Thinking some particles disappear during a state change.

Part (d) 06.4 — Pressure in the pipe

Explain why the pressure in the pipe increases.

✅ Correct answer

The gas particles move faster, so they collide with the walls more often and with a greater force.

This increases the pressure in the pipe.

Mark focus: 1 mark for more collisions per second, 1 mark for greater force per collision.

💡 Key knowledge

  • Gas pressure is caused by particles colliding with the walls of the container.
  • Higher temperature means higher kinetic energy and faster-moving particles.
  • Faster particles give more frequent and stronger collisions.

🧠 Exam technique

  • Use both ideas for 2 marks: more collisions and greater force.
  • Write in cause-and-effect order: temperature up → particle speed up → pressure up.

❌ Common errors

  • Just saying “particles move faster” without linking to pressure.
  • Talking about density instead of pressure.
  • Saying pressure increases because particles “take up more space” — not the key reason.

Part (e) 06.5 — Specific heat capacity calculation

Calculate the specific heat capacity of the air in the building. Give your answer in standard form.

📐 Calculations: step-by-step

  1. Find the useful energy transferred: 87.5% efficiency means the useful output energy is
    0.875 × 1 560 000 = 1 365 000 J
  2. Write the specific heat capacity equation:
    E = m × c × ΔT
  3. Calculate the temperature change:
    ΔT = 22.1 - 11.6 = 10.5 °C
  4. Substitute values:
    1 365 000 = 125 × c × 10.5
  5. Rearrange:
    c = 1 365 000 ÷ (125 × 10.5)
  6. Calculate:
    c = 1040 J/kg °C
  7. Answer in standard form:
    1.04 × 10³ J/kg °C

✅ Correct answer

c = 1.04 × 10³ J/kg °C

Equivalent form: 1040 J/kg °C

Mark focus: 6 marks total. Marks are for using efficiency, correct equation, substitution, rearrangement, calculation, and standard form.

💡 Key knowledge

  • Specific heat capacity tells you how much energy is needed to raise 1 kg of a substance by 1 °C.
  • Use the equation: E = m × c × ΔT
  • Efficiency = useful output energy ÷ total input energy
  • Temperature change must be found using subtraction, not the final temperature.

🧠 Exam technique

  • Write the equation before substituting numbers.
  • Convert 87.5% into 0.875 .
  • Use the correct unit for c: J/kg °C .
  • Give your final answer in standard form when asked.

❌ Common errors

  • Using 1560 instead of 1 560 000 J.
  • Forgetting to convert efficiency from % to a decimal.
  • Using 22.1 + 11.6 instead of subtraction.
  • Dropping the units or writing the wrong units.
  • Not giving the final answer in standard form.

Part (f) 06.6 — Why the “400% efficiency” claim is wrong

Explain why the advertisement is not correct.

✅ Correct answer

The advertisement ignores the energy taken from the surrounding air.

The total energy input is greater than the electrical energy supplied, so the system is not getting 400% efficiency from electricity alone.

Efficiency must be less than 100%.

Mark focus: 3 marks for explaining the missing energy input and stating that efficiency cannot be over 100%.

💡 Key knowledge

  • A heat pump transfers energy from the outside air into the building.
  • The useful output can be bigger than the electrical input because extra energy comes from the surroundings.
  • But efficiency is still based on input and output of the whole system, so it cannot be more than 100%.

🧠 Exam technique

  • Make sure your answer mentions surrounding air or outside air.
  • Say clearly that the electricity is not the only input.
  • Finish with the key conclusion: efficiency must be less than 100%.

❌ Common errors

  • Thinking the heat pump creates energy.
  • Saying “400% efficiency is impossible” without explaining why.
  • Forgetting the energy gained from the outside air.
  • Mixing up useful output energy with total input energy.

Examiner insight: what got marks

✅ Top-level responses

  • Used precise physics language: particles, kinetic energy, internal energy, pressure, efficiency.
  • Showed working clearly in the calculation.
  • Used the correct equation and rearranged it properly.
  • Explained the heat pump idea: extra energy comes from the air, not just the mains electricity.

❌ Where students lost marks

  • Vague explanations with no physics vocabulary.
  • Confusing latent heat with specific heat capacity.
  • Leaving out units in the calculation.
  • Claiming efficiency can be above 100% without explaining the external energy source.

Quick revision checklist

✅ You should know

  • Internal energy = kinetic + potential energy of particles.
  • Latent heat of vaporisation is the energy for liquid → gas.
  • Gas pressure comes from collisions with the walls.
  • E = m × c × ΔT
  • efficiency = useful output ÷ total input

🧠 Final exam tip

If you see a heat pump question, always ask: Where does the energy come from? The answer is usually from both the electricity supply and the surrounding air.

Topics

Physics · P1: Energy · P3: Particle Model of Matter

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Physics Paper 1 (Higher), 2021. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.