AQA GCSE Combined Science: Trilogy Chemistry Paper 2 (Foundation), 2022: Question 5

11 marks · Standard Demand difficulty · Short Answer

Identify properties, names, and reactions of alkanes, perform a percentage calculation, balance a cracking equation, and evaluate life cycle assessment data for window frames.

Practise this question

Question

A chemistry exam question about hydrocarbons and life cycle assessments. It includes a structural diagram of propane (C3H8), a multiple-choice question on calculating the percentage of carbon in a hydrocarbon, a table showing the boiling points of various alkanes from ethane to decane, a chemical equation for the cracking of hexane (C6H14) to be balanced, and a section on comparing wood and plastic window frames using life cycle assessment (LCA) data.
Question text

05 This question is about hydrocarbons.

Figure 9 shows a hydrocarbon.

Figure 9

05.1 Complete the formula for the hydrocarbon shown in Figure 9.

[1 mark]

C H

05.2 What is the name of the hydrocarbon in Figure 9?

[1 mark]

05.3 Which homologous series does the hydrocarbon in Figure 9 belong to?

[1 mark]

05.4 30 g of another hydrocarbon contains 24 g of carbon.

Which calculation gives the percentage of carbon in the hydrocarbon?

[1 mark]

Tick ( ) one box.

24 × 30

100 × 30

24 × 100

30 × 100

05.5 Table 3 shows boiling points of some hydrocarbons.

Table 3

Formula of hydrocarbon Boiling point in °C

C2H6 –89

C4H10 0

C6H14 69

C8H18 125

C10H22 174

Describe how the boiling points change as the number of carbon atoms in the

hydrocarbon increases.

[1 mark]

Hydrocarbons can be cracked.

05.6 Give one condition used to crack hydrocarbons.

*19* [1 mark]

05.7 Balance the equation for the cracking of C6H14

[1 mark]

C6H14 → C2H6 + C2H4

05.8 Give one reason why hydrocarbons are cracked.

[1 mark]

05.9 Window frames can be manufactured from wood or plastic.

Table 4 shows the results of a life cycle assessment (LCA) for making one wooden

and one plastic window frame.

Both window frames are the same size.

Table 4

Wooden frame Plastic frame

Total energy used in MJ 9150 9713

Coal and oil used in kg 5 18

Waste produced in kg 16 28

Cost to buy and maintain in £ 147 102

Give three advantages of using wood instead of plastic in the manufacture of

window frames.

[3 marks]

Advantage of wood 1

Advantage of wood 2

Advantage of wood 3

Mark scheme

Show the mark scheme The mark scheme provides answers for question 5. Correct answers include C3H8 for the formula, propane for the name, alkane for the homologous series, and (24 x 100) / 30 for the percentage calculation. It notes that boiling point increases as the number of carbon atoms increases, lists cracking conditions like high temperature and catalysts, balances the equation with a coefficient of 2 for ethene (C2H4), and gives LCA advantages for wood such as using less energy and being renewable.

Question 5

AO /

Question Answers Extra information Mark

Spec. Ref.

05.1 C3H8 1 AO2

5.7.1.1

AO /

Spec. Ref.

05.2 propane 1 AO1

5.7.1.1

AO /

Spec. Ref.

05.3 alkane(s) 1 AO1

5.7.1.1

AO /

Spec. Ref.

05.4 24 × 100 1 AO2

30 5.7.1.1

AO /

Spec. Ref.

05.5 (as the number of carbon atoms 1 AO2

increases the) boiling point 5.7.1.3

increases

AO /

16Question Answers Extra information Mark

Spec. Ref.

05.6 any one from: 1 AO1

• high temperature allow a temperature between 5.7.1.4

400 °C and 900 °C

ignore heat / hot

• steam

• high pressure

• low / no oxygen (atmosphere)

• catalyst allow aluminium oxide

allow alumina

allow zeolites

allow porous pot

AO /

Spec. Ref.

05.7 C6H14 → C2H6 + 2C2H4 allow multiples 1 AO2

5.1.1.1

5.3.1.1

5.7.1.4

AO /

Spec. Ref.

05.8 any one from: 1 AO1

• to make smaller molecules 5.7.1.4

• to make more useful

molecules

• to produce fuels

• more demand for smaller

molecules

• to make (starting materials allow to make (starting materials

for) polymers for) other chemicals

allow to make alkenes

AO /

Spec. Ref.

05.9 any three from: 3 AO3 17

(wood) 5.10.2.1

• uses less energy

• uses less coal / oil

• produces less waste

• is renewable / sustainable

Total Question 5 11

How to answer it

Hydrocarbons, Cracking, and LCAs

What this question tests

This question assesses your ability to identify and name alkanes, interpret trends in physical properties (boiling points), understand the conditions and purpose of catalytic cracking, balance chemical equations, and evaluate environmental impacts using Life Cycle Assessment (LCA) data.

Parts 05.1, 05.2 & 05.3

Alkane Basics

💡 Key Knowledge

  • Alkanes are saturated hydrocarbons (only single bonds).
  • General formula: CₙH₂ₙ₊₂
  • Naming Mnemonic: Monkeys Eat Peeled Bananas (Meth-, Eth-, Prop-, But-).

✅ Correct Answers

  • 05.1: C₃H₈
  • 05.2: Propane
  • 05.3: Alkane(s)

🧠 Exam Technique

In 05.1, simply count the atoms in Figure 9. There are 3 Carbon (C) atoms and 8 Hydrogen (H) atoms. Don't overthink it! For the name, remember that 3 carbons = "Prop-".

Part 05.4 & 05.5

Percentages & Trends

📐 Calculation (05.4)

To find the percentage of carbon:

  1. Identify the mass of carbon: 24 g
  2. Identify the total mass: 30 g
  3. Formula: (Part ÷ Total) × 100
  4. Calculation: (24 ÷ 30) × 100

❌ Common Errors

Students often flip the fraction (30/24) or multiply by 100 at the wrong stage. Always check: is your answer less than 100%? If you used 30/24, you'd get 125%, which is impossible!

✅ Correct Answer (05.5)

As the number of carbon atoms increases, the boiling point increases.

Examiner Tip: Always look for the pattern in the table. -89 to 0 to 69... the numbers are getting larger (less negative/more positive).

Parts 05.6, 05.7 & 05.8

Cracking Hydrocarbons

💡 Cracking Conditions

Cracking requires breaking strong covalent bonds. You need:

  • High temperature (400°C - 900°C)
  • A catalyst (e.g., zeolite or aluminium oxide) OR Steam

✅ Balancing the Equation (05.7)

C₆H₁₄ → C₂H₆ + 2 C₂H₄

How to solve: Count carbons on the left (6). On the right, you have 2 in C₂H₆. You need 4 more. Since each molecule of the second product has 2 carbons, you need 2 of them (2 × 2 = 4).

🧠 Why Crack? (05.8)

Short-chain molecules are in higher demand as fuels (they ignite easier). Cracking also produces alkenes, which are used to make plastics (polymers).

Part 05.9

Life Cycle Assessment (LCA)

💡 Evaluating Wood vs Plastic

When comparing materials, look at energy use, raw materials, and end-of-life. Wood is generally seen as more sustainable because:

  • It is renewable (trees can be replanted).
  • It often uses less energy to process than crude oil.
  • It acts as a carbon sink while the tree is growing.
  • It produces less waste or the waste is biodegradable.

🧠 How to get 3/3 Marks

Even if the table isn't visible, LCA questions usually want you to compare specific categories. For wood, focus on: Renewability, Lower Energy usage, and Lower Fossil Fuel (coal/oil) usage.

Topics

Chemistry · C7: Organic Chemistry · C10: Using Resources · C3: Quantitative Chemistry

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 2 (Foundation), 2022. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.