AQA GCSE Combined Science: Trilogy Chemistry Paper 2 (Higher), 2022: Question 4

12 marks · Standard Demand difficulty · Extended Answer

Name and define hydrocarbons, complete a cracking equation, explain why cracking products are in demand, and evaluate the sustainability of wooden versus plastic window frames using life cycle assessment data.

Practise this question

Question

The question page is headed as a question about hydrocarbons and the uses of hydrocarbons. It shows a black-and-white ball-and-stick molecular model labelled Figure 6 and asks for the name of the alkane shown for 1 mark, then asks for the definition of a hydrocarbon for 1 mark. The next part states that large hydrocarbon molecules are cracked and asks students to complete the equation C11H24 → C5H10 + 2 ____ + ____ for 2 marks, followed by a 2-mark explanation of why one product of cracking is in high demand. The final 6-mark part gives a table comparing wooden and plastic window frames of the same size, with values for hydrocarbon source use, greenhouse gases, oxides of nitrogen and sulfur dioxide, waste materials, total energy consumption, and lifetime cost, and asks students to evaluate sustainability including environmental and economic factors.
Question text

04 This question is about hydrocarbons and the uses of hydrocarbons.

04.1 Figure 6 shows a model of an alkane.

Figure 6

What is the name of the alkane in Figure 6?

[1 mark]

04.2 What is a hydrocarbon?

[1 mark]

Large hydrocarbon molecules are cracked.

04.3 When C11H24 is cracked, three products are formed.

Complete the equation for the reaction.

[2 marks]

C11H24 → C5H10 + 2 +

04.4 Explain why one of the products of cracking is in high demand.

[2 marks]

04.5 Window frames can be manufactured from wood or from plastic.

Table 2 shows data from a life cycle assessment (LCA) for a wooden window frame

and a plastic window frame.

Both window frames are the same size.

Table 2

Wood Plastic

Sources of hydrocarbons used for production in kg 5.37 18.23

Greenhouse gases released during production,

457 487

use and disposal in kg equivalent of CO2

Oxides of nitrogen and sulfur dioxide produced in

29.6 37.7

arbitrary units

Waste materials in kg 16.5 28.8

Total energy consumption in production, use and

9150 9713

disposal in MJ

Lifetime cost to customer to buy and maintain in £15 147 102

Evaluate the sustainability of wooden and plastic window frames.

You should include environmental and economic factors.

[6 marks]

Mark scheme

Show the mark scheme The mark scheme is presented as a series of tables for parts 04.1 to 04.5. It gives the answers 'butane' for the alkane name and '(molecule) made up of carbon and hydrogen (atoms) only' for the hydrocarbon definition, then allows several balanced cracking equations including C11H24 → C5H10 + 2C2H4 + C2H6, with alternative valid product combinations also credited. For the demand question it credits either a fuel use for ethane because it is more flammable, or alkene uses such as making polymers because alkenes are more reactive. For the 6-mark evaluation it uses level-based marking and indicative points including that plastic uses more non-renewable hydrocarbons, produces more greenhouse gases, sulfur dioxide, nitrogen oxides, waste and slightly more energy, but has lower lifetime cost and maintenance, with an overall judgement required.

Question 4

AO /

Question Answers Extra information Mark

Spec. Ref.

04.1 butane 1 AO2

5.7.1.1

AO /

Spec. Ref.

04.2 (molecule) made up of carbon 1 AO1

and hydrogen (atoms) only 5.7.1.1

AO /

Spec. Ref.

04.3 C11H24 → C5H10 + 2C2H4 + C2H6 2 AO2

allow 1 mark for 2C2H4 5.1.1.1

allow 1 mark for C2H6 5.3.1.1

5.7.1.4

OR

C11H24 → C5H10 + 2C3H6 + H2 (2)

allow 1 mark for 2C3H6

allow 1 mark for H2

OR

C11H24 → C5H10 + 2C2H6 + C2H2 (2)

allow 1 mark for 2C2H6

allow 1 mark for C2H2

AO /

Spec. Ref.

04.4 C2H6 is useful as a fuel allow smaller molecule so useful 1 AO1

as a fuel 5.7.1.3

5.7.1.4

(because more) flammable (than 1

larger molecules)

OR

C2H4 / C3H6 / C5H10 is used to allow C2H4 / C3H6 / C5H10 is used

make polymers (1) to make plastics

allow C2H4 / C3H6 / C5H10 is used

to make other chemicals

(because more) reactive (than

alkanes) (1)

if a named product is given,

allow 1 mark for a correct use

and 1 mark for a correct linked

reason

AO /

Question Answers Mark

Spec. Ref.

04.5 Level 3: A judgement, strongly linked and logically supported by a 5–6 AO3

sufficient range of correct reasons is given. 5.9.2.2

5.10.1.1

Level 2: Some logically linked reasons are given. There may also 3–4 5.10.2.1

be a simple judgement.

Level 1: Relevant points are made. They are not logically linked. 1–2

No relevant content 0

Indicative content

• production of plastic uses more hydrocarbons which are from

non-renewable crude oil

• production of plastic produces more greenhouse gases in the

atmosphere which contributes to global warming

• production of plastic produces more sulfur dioxide which causes

acid rain

• production of plastic produces more oxides of nitrogen which

cause acid rain and respiratory problems

• disposal of plastic produces more waste which increases landfill

14 • burning plastic produces fumes which are toxic so cause

respiratory problems

• lifetime cost of plastic frames is less

• plastic frames have lower costs for maintaining

• the total energy consumption for plastic frames is greater than for

wooden frames

• judgement

Total Question 4 12

How to answer it

Hydrocarbons, Cracking and Sustainability

What this question tests

Naming a simple alkane from a model, defining a hydrocarbon, completing a cracking equation by balancing atoms, explaining why cracked products are useful, and using LCA data to make a balanced sustainability judgement. You need to select key facts, compare data, and write a clear evaluative conclusion.

Overall focus: hydrocarbons and uses of hydrocarbons

Question 04.1–04.5

This is a low-demand question overall because the early parts are recall-based, but the final part needs a supported judgement using data.

04.1 — Name the alkane in Figure 6

1 mark

✅ Correct answer

butane

This is worth 1 mark for the correct alkane name.

💡 Key knowledge

  • Alkanes are hydrocarbons with only single bonds.
  • Butane has 4 carbon atoms.
  • Its formula is C₄H₁₀ .

🧠 Exam technique

  • Count the carbon atoms in the model.
  • Match the chain length to the alkane name.
  • For a 1-mark naming question, spell the name clearly.

❌ Common errors

  • Giving the formula instead of the name.
  • Confusing butane with butene.
  • Misspelling the alkane name.

04.2 — What is a hydrocarbon?

1 mark

✅ Correct answer

A hydrocarbon is a molecule made of carbon and hydrogen only.

💡 Key knowledge

  • Hydrocarbons contain only carbon atoms and hydrogen atoms.
  • They can be alkanes or alkenes.

🧠 Exam technique

A 1-mark definition needs the exact idea: carbon and hydrogen only. Extra detail is not needed.

❌ Common errors

  • Saying “contains carbon and hydrogen and oxygen”.
  • Writing “made of molecules” without defining the elements.
  • Forgetting the word only.

04.3 — Complete the cracking equation

2 marks

✅ Correct answer

One full correct equation is:

C₁₁H₂₄ → C₅H₁₀ + 2C₂H₄ + C₂H₆

Other valid alternatives were allowed by the mark scheme, as long as atoms are balanced.

💡 Key knowledge

  • Cracking breaks long-chain hydrocarbons into smaller molecules.
  • Products can include alkenes and alkanes.
  • You must conserve the number of each type of atom.

🧠 Exam technique

  • Check carbon atoms first.
  • Then check hydrogen atoms.
  • Use coefficients to balance the equation.
  • Make sure the products total the same atoms as the reactant.

❌ Common errors

  • Forgetting to balance the atoms.
  • Writing only one product from the allowed list.
  • Changing the subscript in the formula instead of adding a coefficient.

📐 Calculations / balancing steps

  1. Start with the reactant: C₁₁H₂₄ means 11 carbon atoms and 24 hydrogen atoms.
  2. Count carbon on the products: C₅H₁₀ gives 5 C, 2C₂H₄ gives 4 C, and C₂H₆ gives 2 C. Total = 11 C.
  3. Count hydrogen on the products: 10 + 8 + 6 = 24 H.
  4. Check the final equation: atoms are balanced, so the equation is correct.

❌ Calculation traps

  • Do not alter the formula of the substances to make them fit.
  • Do not forget that the number in front of a formula multiplies every atom in that formula.
  • Check that the final answer uses correct chemical formulae, not names.

04.4 — Explain why one product of cracking is in high demand

2 marks

✅ Correct answer

Any one of these linked explanations scores full marks:

  • C₂H₆ is useful as a fuel because it is a smaller molecule and is more flammable.
  • C₂H₄ / C₃H₆ / C₅H₁₀ are used to make polymers because they are more reactive than alkanes.

💡 Key knowledge

  • Smaller hydrocarbons are often useful as fuels.
  • Alkenes are important because they can be used to make plastics/polymers.
  • Unsaturated molecules are more reactive than alkanes.

🧠 Exam technique

  • For 2 marks, give a use and a reason.
  • Use a cause-and-effect sentence: “X is useful because Y”.
  • If you name a specific product, make sure the use matches it.

❌ Common errors

  • Saying “it is high demand because it is important” — too vague.
  • Mixing up alkanes and alkenes.
  • Not linking the property to the use.

04.5 — Evaluate the sustainability of wooden and plastic window frames

6 marks

💡 Key data from the table

  • Hydrocarbons used: wood 5.37 kg, plastic 18.23 kg
  • Greenhouse gases: wood 457, plastic 487 kg CO₂ equivalent
  • Oxides of nitrogen and sulfur dioxide: wood 29.6, plastic 37.7 units
  • Waste materials: wood 16.5 kg, plastic 28.8 kg
  • Total energy use: wood 9150 MJ, plastic 9713 MJ
  • Lifetime cost: wood £147, plastic £102

✅ What a strong answer includes

  • Compares environmental factors for wood and plastic.
  • Compares economic factors for wood and plastic.
  • Uses the data to support a clear final judgement.
  • Recognises that plastic is cheaper, but wood is generally better environmentally.

🧠 Exam technique

  • Make direct comparisons: “plastic is higher than wood”.
  • Include numbers from the table to prove your points.
  • End with a judgement such as “overall, wood is more sustainable” or “overall, plastic is better economically”.
  • Top answers are logically linked and cover both sides.

❌ Common errors

  • Describing only one frame without comparing.
  • Ignoring the economic data.
  • Only listing facts with no conclusion.
  • Saying plastic is sustainable just because it is cheaper.

📐 Useful comparison points for evaluation

  1. Plastic uses more hydrocarbons than wood, so it relies more on non-renewable crude oil.
  2. Plastic produces more greenhouse gases, which contributes more to global warming.
  3. Plastic produces more oxides of nitrogen and sulfur dioxide, which can cause acid rain and respiratory problems.
  4. Plastic produces more waste, so it is less good for landfill.
  5. Plastic uses slightly more energy overall.
  6. Plastic is cheaper over its lifetime, so it has an economic advantage.

✅ Example level 3 response

Wood is more sustainable overall because it uses fewer hydrocarbons than plastic and produces less greenhouse gases, oxides of nitrogen and sulfur dioxide, and waste. For example, wood uses 5.37 kg of hydrocarbons compared with 18.23 kg for plastic, and wood produces 457 kg CO₂ equivalent compared with 487 kg for plastic. Wood also produces less waste, 16.5 kg compared with 28.8 kg. However, plastic is cheaper over its lifetime at £102 compared with £147 for wood. Even so, environmental factors are more important in sustainability, so wood is the better choice overall.

🧠 Why this scores highly

  • It makes a clear judgement.
  • It uses several pieces of correct data.
  • It includes both environmental and economic factors.
  • The reasons are linked, not just listed.

❌ Examiner-style pitfalls in 04.5

  • “Plastic is better because it is cheaper” — too one-sided for top marks.
  • “Wood is better because it is natural” — not enough scientific support.
  • “Plastic makes more pollution” — too vague unless you state which pollution and compare values.
  • Forgetting to finish with a clear overall judgement.
Mark scheme insight: Level 3 responses are strongly linked and logically supported by a sufficient range of correct reasons. Level 2 responses have some linked reasons but may be less developed. Level 1 answers usually just state a few separate points with little comparison.

Quick revision recap

💡 Remember

  • Butane = C₄H₁₀
  • Hydrocarbon = carbon and hydrogen only
  • Cracking makes smaller alkanes and alkenes
  • Alkenes are useful for polymers
  • Wood is environmentally better here; plastic is cheaper

🧠 Best way to gain marks

  • Use exact scientific words.
  • Compare data directly.
  • Give a reason, not just a statement.
  • Always end evaluation questions with a judgement.

Topics

Chemistry · C7: Organic Chemistry · C10: Using Resources

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 2 (Higher), 2022. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.