AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Foundation), 2024: Question 2

8 marks · Standard Demand difficulty · Short Answer

Complete a dot-and-cross diagram for methane and answer questions about the structures, bonding, conductivity and uses of diamond, graphite and fullerenes.

Practise this question

Question

The question page is Chemistry Question 2 about carbon structures, split into parts 02.1 to 02.6 for a total of 8 marks. Part 02.1 states that carbon is in Group 4 and methane contains carbon and hydrogen atoms; it gives that carbon has 4 outer-shell electrons and hydrogen has 1, then shows an incomplete dot-and-cross diagram with a central carbon and four surrounding hydrogens and asks the student to complete it. Part 02.2 asks which of three diagrams represents diamond: the options shown are a football-like fullerene sphere, a polymer repeat unit with two carbons and hydrogens in brackets, and a 3D giant covalent carbon network; Part 02.3 shows a layered graphite structure labelled carbon atom and asks how many covalent bonds each carbon forms, with options 1, 2, 3 or 4. Part 02.4 asks which particles carry electrical charge through graphite; Part 02.5 shows Figure 4, a hollow cylindrical fullerene or nanotube, and asks where fullerenes are used, with options electronic components, self-heating cans, or sports injury packs; Part 02.6 asks the student to describe the structure of the fullerene shown in Figure 4 using written response lines.
Question text

02 Carbon is in Group 4 of the periodic table.

02.1 Methane contains carbon and hydrogen atoms.

A carbon atom has 4 electrons in the outer shell.

A hydrogen atom has 1 electron in the outer shell.

Complete the dot and cross diagram for a methane molecule.

[2 marks]

02.2 Which diagram represents the structure of diamond?

[1 mark]

Tick ( ) one box.

Figure 3 represents part of the structure of graphite.

Figure 3

02.3 In graphite each carbon atom forms covalent bonds.

How many covalent bonds does each carbon atom form in graphite?

[1 mark]

Tick ( ) one box.

*07* 1 2 3 4

02.4 Graphite conducts electricity.

Which particles carry electrical charge through graphite?

[1 mark]

Figure 4 represents the structure of a fullerene.

Figure 4

02.5 Where are fullerenes used?

[1 mark]

Tick ( ) one box.

In electronic components

In self-heating cans

In sports injury packs

02.6 Describe the structure of the fullerene shown in Figure 4.

[2 marks]

Mark scheme

Show the mark scheme The mark scheme is a table for Question 2 with columns for question number, answers, extra information, mark and AO/specification references. For 02.1, 2 marks are awarded for one pair of electrons in each of the three missing overlaps on the methane dot-and-cross diagram, allowing any combination of dots, crosses, circles or electron notation and ignoring inner-shell electrons; extra electrons are not accepted. For 02.2 the correct diagram is the 3D giant covalent diamond structure; for 02.3 the answer is 3; for 02.4 the accepted answer is delocalised or free electrons; for 02.5 the correct use is in electronic components. For 02.6, 2 marks are available for any two of: hollow or cylindrical shape, hexagonal rings, made of carbon atoms, and each carbon atom forms 3 covalent bonds; the total mark for Question 2 is 8.

Question 2

AO /

Question Answers Extra information Mark

Spec. Ref.

02.1 allow any combination of circles, AO1

dots, crosses, e(–) for electrons 5.2.1.1

5.2.1.4

one pair of electrons drawn in ignore inner shell electrons on 2

each of the three overlaps the carbon atom

do not accept extra electron(s)

on outer shell of carbon /

hydrogen

allow 1 mark for one shared pair

in one overlap without non-

bonding electron(s) on that

hydrogen

an answer of

scores 2 marks

AO /

Spec. Ref.

02.2 1 AO1

5.2.1.4

5.2.2.6

5.2.3.1

– – –

AO /

Spec. Ref.

02.3 3 1 AO1

5.2.3.2 9

AO /

Spec. Ref.

02.4 (delocalised) electrons allow (free) electrons 1 AO2

5.2.3.2

AO /

Spec. Ref.

02.5 in electronic components 1 AO1

5.2.3.3

AO /

Spec. Ref.

02.6 any two from: 2 AO1

5.2.3.3

• hollow (shape) allow cylindrical (shape)

allow (nano)tube

• hexagonal rings allow (made of) hexagons

• (of) carbon atoms

• each (carbon) atom forms 3

(covalent) bonds

Total Question 2 8

How to answer it

Carbon Structures: Methane, Diamond, Graphite and Fullerenes

What this question tests

This question checks your knowledge of covalent bonding and the structures and uses of diamond, graphite and fullerenes. You need to: describe electron sharing in methane, identify carbon structures from diagrams, know why graphite conducts, and recall a use and key structural features of a fullerene.

Question 2 Overview

💡 Key knowledge

  • Carbon atoms form 4 covalent bonds in many compounds.
  • In methane, each H atom forms 1 bond and carbon forms 4 single bonds.
  • Diamond = each carbon bonded to 4 others in a giant covalent lattice.
  • Graphite = each carbon bonded to 3 others, leaving delocalised electrons.
  • Fullerenes are hollow carbon structures with hexagonal rings.

🧠 Exam technique

  • For structure questions, use the diagram clues and the bonding pattern.
  • If asked to “describe”, give two clear points for two marks.
  • When naming charge carriers in graphite, say delocalised electrons or free electrons.
  • Tick questions: only one box should be selected.

❌ Common errors

  • Mixing up diamond and graphite.
  • Saying graphite conducts because of “ions” or “protons” — that is incorrect.
  • For methane, drawing too many or too few electrons in overlaps.
  • Not giving enough detail for a 2-mark “describe” question.

02.1 Complete the dot and cross diagram for methane

2 marks

✅ Correct answer

Draw one shared pair of electrons in each of the three overlaps between the carbon atom and the hydrogen atoms shown.

Accept dots, crosses, circles or any combination, as long as each overlap contains 2 electrons.

💡 Key knowledge

  • Carbon has 4 outer-shell electrons.
  • Hydrogen has 1 outer-shell electron.
  • Methane is CH₄, so carbon makes 4 single covalent bonds.
  • In this question, one H is already shown as overlapping in the diagram, and the mark scheme allows the same bonding pattern to be completed across the visible overlaps.

🧠 Exam technique

  • The mark scheme rewards the shared pairs, not artistic drawing.
  • Place electrons in the overlap to show bonding.
  • Ignore inner-shell electrons on carbon.

❌ Common errors

  • Putting extra electrons on the outside of carbon or hydrogen.
  • Drawing only one electron in an overlap instead of a shared pair.
  • Forgetting that each hydrogen can only form one bond.

📐 How to think about it

  1. Carbon needs 4 more electrons to fill its outer shell.
  2. Each hydrogen needs 1 more electron.
  3. Carbon shares one electron with each hydrogen.
  4. This gives 4 shared pairs in methane overall.
Mark breakdown: 1 mark for at least one correct shared pair, and 2 marks for completing all three overlaps correctly.

02.2 Which diagram represents the structure of diamond?

1 mark

✅ Correct answer

The third diagram is diamond.

💡 Key knowledge

  • Diamond is a giant covalent structure.
  • Each carbon atom forms 4 covalent bonds.
  • The structure is a 3D lattice, not layers and not a tube.

🧠 Exam technique

  • Look for the model where each carbon is bonded in a tetrahedral network.
  • In multiple-choice diagram questions, compare the number of bonds per carbon.

❌ Common errors

  • Choosing the fullerene sphere or tube.
  • Choosing the polymer-like chain structure.
  • Confusing diamond with graphite because both contain only carbon.

02.3 How many covalent bonds does each carbon atom form in graphite?

1 mark

✅ Correct answer

3

💡 Key knowledge

  • Each carbon atom in graphite forms three covalent bonds.
  • The fourth outer electron is delocalised.

🧠 Exam technique

  • This is a straight recall question: one mark, one word or number.
  • Give the exact number: 3.

❌ Common errors

  • Answering 4 because carbon has 4 outer electrons.
  • Writing “three and a half” or “mostly 3”.

02.4 Which particles carry electrical charge through graphite?

1 mark

✅ Correct answer

Delocalised electrons

💡 Key knowledge

  • Graphite conducts because it has free-moving electrons.
  • These electrons can move through the structure and carry charge.

🧠 Exam technique

  • “Delocalised electrons” is the safest full-mark answer.
  • “Free electrons” is also accepted.

❌ Common errors

  • Saying “ions” because graphite is a solid.
  • Saying “atoms” carry the charge.
  • Thinking the layers themselves carry charge.

02.5 Where are fullerenes used?

1 mark

✅ Correct answer

In electronic components

💡 Key knowledge

  • Fullerenes have uses in electronics.
  • They are carbon structures with useful properties for very small-scale applications.

🧠 Exam technique

  • Only one box should be ticked.
  • Use the exact wording if possible: electronic components.

❌ Common errors

  • Choosing self-heating cans or sports injury packs — those are not fullerene uses here.
  • Ticking more than one box.

02.6 Describe the structure of the fullerene shown in Figure 4

2 marks

✅ Correct answer

Any two of the following:

  • Hollow shape.
  • Cylindrical shape / nanotube.
  • Made of hexagonal rings.
  • Made of carbon atoms.
  • Each carbon atom forms 3 covalent bonds.

💡 Key knowledge

  • The figure shows a carbon nanotube type fullerene.
  • It is a hollow cylinder built from carbon atoms.
  • The atoms are joined in hexagonal patterns.

🧠 Exam technique

  • For 2 marks, give two separate structural features.
  • Good answers are short and precise: “hollow” and “hexagonal rings”.
  • If you write “nanotube”, that is accepted as cylindrical/hollow fullerene.

❌ Common errors

  • Saying it is a sphere when the image shows a tube.
  • Writing “many bonds” without saying 3 bonds per carbon.
  • Describing graphite layers instead of a fullerene.

📐 If you were describing the diagram like an examiner

  1. It is a hollow cylindrical structure.
  2. It is made from carbon atoms arranged in hexagonal rings.
  3. Each carbon atom forms 3 covalent bonds.

Why full marks were awarded: the best answers gave two clear, correct structure points rather than vague statements like “it is a carbon shape”.

Quick revision summary

Diamond

Each carbon forms 4 covalent bonds. It is a giant covalent lattice.

Graphite

Each carbon forms 3 covalent bonds and has delocalised electrons, so it conducts electricity.

Fullerenes

They are hollow, often cylindrical, and made of carbon atoms in hexagonal rings.

Topics

Chemistry · C2: Bonding, Structure and the Properties of Matter

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Foundation), 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.