AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Foundation), 2024: Question 3

11 marks · Standard Demand difficulty · Short Answer

Investigate the reaction of zinc with copper sulfate by identifying variables and products, making observations, reading a thermometer, and processing repeat temperature data including mean, range and anomalous results.

Practise this question

Question

The question page shows a practical investigation where different masses of zinc are added to 50 cm³ of copper sulfate solution in a polystyrene cup with a thermometer. A labelled diagram identifies zinc being added, the thermometer, the polystyrene cup, and the copper sulfate solution, followed by a numbered method: pour 50 cm³ solution into the cup, measure starting temperature, add 1.0 g zinc, stir, measure the highest temperature, repeat twice, then repeat with different zinc masses. Sub-questions ask the student to identify the type of variable for zinc mass, name the salt formed in the word equation zinc + copper sulfate → salt A + copper, state two observations other than temperature change, read the highest temperature from a thermometer scale and complete a table with starting temperature 21°C, highest temperature and temperature increase, calculate a mean value B from a results table, give the range for the 2.0 g zinc data, and identify an anomalous result for 3.0 g zinc with a reason. The results table lists temperature increases for masses 1.0 g, 2.0 g, and 3.0 g across three experiments plus a mean column: for 1.0 g the values are 7.8, 7.3, 7.7 and mean B; for 2.0 g they are 13.1, 13.8, 13.3 and mean 13.4; for 3.0 g they are 20.4, 12.9, 20.2 and mean 20.3.
Question text

03 A student investigated the temperature change when different masses of zinc were

added to copper sulfate solution.

Figure 5 shows the apparatus.

Figure 5

This is the method used.

1. Pour 50 cm3 of copper sulfate solution into a polystyrene cup.

2. Measure the starting temperature of the copper sulfate solution.

3. Add 1.0 g of zinc.

4. Stir the mixture.

5. Measure the highest temperature reached.

6. Repeat steps 1 to 5 two more times.

7. Repeat steps 1 to 6 with different masses of zinc.

03.1 The student varied the mass of zinc.

What type of variable is the mass of zinc?

[1 mark]

Tick ( ) one box.

Control

Dependent

Independent 12

Zinc reacts with copper sulfate solution to produce salt A and copper.

*10* The word equation for the reaction is:

zinc + copper sulfate → salt A + copper

03.2 What is the name of salt A?

[1 mark]

03.3 The temperature of the solution increases when zinc reacts with

copper sulfate solution.

Give two other observations that can be made when zinc reacts with

copper sulfate solution.

[2 marks]

03.4 Figure 6 shows the highest temperature reached in one experiment.

Figure 6

*12* Complete Table 3.

Use Figure 6.

[2 marks]

Table 3

Starting temperature in °C 21

Highest temperature reached in °C

Temperature increase in °C14

A teacher repeated the investigation using a digital thermometer.

Table 4 shows the results.

Table 4

Temperature increase in °C

Mass of zinc in grams

Experiment 1 Experiment 2 Experiment 3 Mean

1.0 7.8 7.3 7.7 B

2.0 13.1 13.8 13.3 13.4

3.0 20.4 12.9 20.2 20.3

03.5 Calculate value B in Table 4.

[2 marks]

B = °C

03.6 The range of the results is the minimum value of temperature increase to the

maximum value of temperature increase.

What is the range of temperature increase for the experiment with 2.0 g of zinc?

[1 mark]

Range = °C to 15 °C

03.7 One of the results for 3.0 g of zinc is anomalous.

Which result is anomalous?

Suggest one reason why this result is anomalous.

[2 marks]

Anomalous result

Reason

Mark scheme

Show the mark scheme The mark scheme is presented in tables for Question 3 parts 03.1 to 03.7 with columns for answers, extra information, marks, and AO/specification references. It gives: 03.1 independent; 03.2 zinc sulfate, allowing ZnSO4; 03.3 solution becomes colourless and a brown or orange solid is produced, while ignoring temperature or fizzing references; 03.4 highest temperature 36°C and temperature increase 15°C from 36 minus 21; 03.5 mean B = 7.6°C from 22.8 divided by 3, or 7.75 to 7.8°C if calculated using only two values with working shown; 03.6 range 13.1°C to 13.8°C in either order; 03.7 anomalous result 12.9°C or experiment 2, with reasons such as much lower than the other two results, less than 3 g zinc used, more than 50 cm³ copper sulfate used, or the mixture was not stirred. The bottom of the page states Total Question 3 = 11 marks.

Question 3

AO /

Question Answers Extra information Mark

Spec. Ref.

03.1 independent 1 AO1

5.4.1.2

5.5.1.1

RPA10

AO /

Spec. Ref.

03.2 zinc sulfate allow ZnSO4 1 AO2

5.4.1.2

5.5.1.1

RPA10

AO /

Spec. Ref.

ignore references to

03.3 temperature / fizzing AO2

5.4.1.2

solution becomes colourless allow solution changes colour 1 5.5.1.1

RPA10

(brown / orange) solid produced allow zinc changes colour 1

AO /

Spec. Ref.

03.4 (highest temperature =) 36 (°C) 1 AO2

5.4.1.2

(temperature increase = allow correct use of an 1 5.5.1.1

36 – 21 =) 15 (°C) incorrectly determined value for RPA10

highest temperature

– ignore minus sign – –

AO /

Spec. Ref.

03.5 7.8 + 7.3 + 7.7 22.8 1 AO2

(B =) or 5.4.1.2

5.5.1.1

= 7.6 (°C) 1 RPA10

OR

7.8 + 7.7 15.5 allow 7.8 (°C) if working shown

(B =) or (1) for calculation of the mean using

7.8 and 7.7 (°C)

= 7.75 (°C) (1)

AO /

Spec. Ref.

03.6 (range =) 13.1 (°C to) 13.8 (°C) allow (range =) 13.8 (°C to) 13.1 1 AO2

(°C) 5.3.1.4

5.4.1.2

– – – 5.5.1.1

RPA10

AO /

Spec. Ref.

03.7 MP2 is dependent on MP1 AO3

being awarded 5.4.1.2

5.5.1.1

(result) 12.9 (°C) allow (result / experiment) 2 1 RPA10

any one from: 1

• (the result is) much lower than

the other two results

• (used) less than 3 g zinc allow (used) incorrect mass of

zinc

• (used) more than 50 cm3 of allow (used) incorrect volume of

copper sulfate (solution) copper sulfate (solution)

• the mixture was not stirred

Total Question 3 11

How to answer it

Reacting Masses and Temperature Change

What this question tests

Identifying variables, naming the product in a displacement reaction, describing simple observations, reading a thermometer, calculating a temperature change, finding a mean, understanding range, and spotting an anomalous result.

Part (a)–(g) overview

💡 Key knowledge

  • The independent variable is the one you change.
  • Zinc reacts with copper sulfate to make zinc sulfate and copper.
  • When copper is displaced, the blue solution becomes colourless and copper metal appears.
  • Temperature increase = highest temperature − starting temperature.

🧠 Exam technique

  • Use the exact science term the mark scheme wants.
  • For means, add the values and divide by the number of results.
  • For thermometer readings, read the scale carefully and use the correct unit: °C.

❌ Common errors

  • Calling the changed variable dependent instead of independent.
  • Naming the product as “copper sulfate” instead of zinc sulfate.
  • Forgetting that a mean needs all relevant results divided by 3, or averaging the wrong numbers.
  • Giving the range as a single number instead of a lower-to-higher interval.

Part 03.1 — Variable type

What type of variable is the mass of zinc?

✅ Correct answer

Independent

Mark point: 1 mark for identifying the variable that the student changes.

💡 Key knowledge

  • Independent variable = the factor deliberately changed.
  • Dependent variable = what is measured, here the temperature increase.
  • Control variable = kept the same, such as volume of copper sulfate solution.

🧠 Exam technique

The question says the student varied the mass of zinc, so that is your clue. Always match the answer to the wording of the method.

❌ Common errors

Students often picked dependent because the temperature changes, but the mass of zinc is what is being changed, not measured.

Part 03.2 — Name the salt

Zinc + copper sulfate → salt A + copper. What is salt A?

✅ Correct answer

zinc sulfate (allow ZnSO₄)

Mark point: 1 mark for the correct salt name or formula.

💡 Key knowledge

This is a displacement reaction. Zinc is more reactive than copper, so zinc replaces copper in copper sulfate.

zinc + copper sulfate → zinc sulfate + copper

🧠 Exam technique

If you know the general pattern, you can predict the product by swapping the metal in the sulfate compound.

❌ Common errors

Do not write copper sulfate again. The word sulfate stays, but the metal changes to zinc.

Part 03.3 — Observations

Give two other observations when zinc reacts with copper sulfate solution.

✅ Correct answers

  • The solution becomes colourless.
  • A brown / orange solid is produced.
2 marks available: 1 mark for each valid observation.

💡 Key knowledge

  • Copper sulfate solution is blue at the start.
  • As copper ions are removed, the solution loses its blue colour.
  • Copper metal forms as a reddish-brown solid.

🧠 Exam technique

Describe what you can see. Examiner guidance says to ignore mentions of temperature or fizzing because they are not the required observation marks.

❌ Common errors

  • Writing “it gets hotter” — this was already stated in the question.
  • Writing “gas is made” — not a correct observation here.
  • Describing the copper as “black” instead of brown/orange.

Part 03.4 — Reading the thermometer

Complete Table 3 using Figure 6.

✅ Correct answers

  • Highest temperature reached = 36 °C
  • Temperature increase = 36 − 21 = 15 °C
2 marks: 1 for the correct highest temperature, 1 for the correct increase.

📐 Calculations

  1. Read the thermometer scale carefully: the top of the liquid is at 36 °C.
  2. Use the formula: temperature increase = highest temperature − starting temperature.
  3. Substitute the values: 36 − 21.
  4. Calculate: 15 °C.

Unit: degrees Celsius, °C

🧠 Exam technique

Marks are awarded for the method as well as the answer. If your highest temperature is slightly wrong, you can still gain the calculation mark if you subtract correctly from your own value.

❌ Common traps

  • Reading the scale one division out.
  • Using 35 °C or 37 °C by not checking the intervals.
  • Forgetting to subtract the starting temperature.
  • Writing a minus sign in the increase when the question wants the size of the change.

Part 03.5 — Calculate the mean

Calculate value B in Table 4.

✅ Correct answer

B = 7.6 °C

Accepted working:
(7.8 + 7.3 + 7.7) ÷ 3 = 22.8 ÷ 3 = 7.6

Alternative valid method using the two consistent results:
(7.8 + 7.7) ÷ 2 = 7.75 °C

📐 Calculations

  1. Add the three results: 7.8 + 7.3 + 7.7 = 22.8
  2. Divide by 3: 22.8 ÷ 3 = 7.6
  3. Give the answer to a sensible decimal place: 7.6 °C

Important: keep the unit °C .

🧠 Exam technique

If one value is suspicious, you may be allowed to use the two matching results to find a mean. The mark scheme accepts 7.75 °C if you clearly show the method using 7.8 and 7.7.

❌ Common errors

  • Adding only two values and dividing by three.
  • Rounding too early.
  • Forgetting the unit.
  • Writing 76 or 7.06 because of place-value mistakes.

Part 03.6 — Range

What is the range of the results for 2.0 g of zinc?

✅ Correct answer

Range = 13.1 °C to 13.8 °C

1 mark for giving the lowest and highest values in the set.

📐 Calculations

Results for 2.0 g zinc are:

  • 13.1 °C
  • 13.8 °C
  • 13.3 °C

The minimum is 13.1 °C and the maximum is 13.8 °C.

🧠 Exam technique

In this question, “range” means the smallest to largest value, not the difference between them.

❌ Common errors

  • Writing 0.7 °C instead of the interval.
  • Using the mean instead of the range.
  • Mixing up the minimum and maximum values.

Part 03.7 — Anomalous result

One result for 3.0 g of zinc is anomalous. Identify it and suggest one reason.

✅ Correct answer

Anomalous result: 12.9 °C

One reason: the mixture was not stirred / less than 3 g of zinc was used / more than 50 cm³ of copper sulfate solution was used.

2 marks: 1 for the anomalous result, 1 for a valid explanation.

💡 Key knowledge

An anomalous result is one that is very different from the others and does not fit the pattern. The other 3.0 g results are 20.4 °C and 20.2 °C, so 12.9 °C is much lower.

🧠 Exam technique

Top answers do two things:

  • identify the odd result,
  • explain why it is suspicious compared with the other repeats.

The examiner noted that the explanation must be linked to the experiment, not just “it is wrong”.

❌ Common errors

  • Picking 20.4 °C or 20.2 °C because they are larger numbers.
  • Giving a vague reason like “human error” without detail.
  • Forgetting that the reason must be something that could happen in the experiment.

Final mark-winning checklist

💡 What to remember

  • Independent variable = mass of zinc.
  • Product salt = zinc sulfate.
  • Observations = solution becomes colourless; brown/orange solid forms.
  • Temperature increase = highest − start.
  • Mean = add and divide by number of results.
  • Range = lowest to highest result.
  • Anomalous result = value that does not fit the pattern.

🧠 How to secure full marks

  • Use the exact scientific terms.
  • Show working in calculations.
  • Include units.
  • Link explanations to the data in the table.

❌ Last-minute traps

  • Using the wrong variable type.
  • Mixing up zinc sulfate and copper sulfate.
  • Not reading the thermometer carefully.
  • Confusing range with difference.

Topics

Chemistry · C4: Chemical Changes · C5: Energy Changes

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Foundation), 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.