AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Foundation), 2024: Question 4

9 marks · Standard Demand difficulty · Short Answer

Identify and explain separation methods including chromatography, filtration and distillation, and apply knowledge of boiling points and changes of state to separation apparatus.

Practise this question

Question

The question page shows Question 4 split into parts 04.1 to 04.7 about separating mixtures. Figure 7 is a chromatography setup with paper suspended in water, a start line near the bottom, and a black ink spot on the line; students are asked to name the method. Figure 8 shows a filter funnel over a beaker, with solid C trapped in the filter and solution of D collected below; students must name the method and explain why C separated from D. Figure 9 shows a distillation apparatus with a heated flask containing liquids G, H and I, a thermometer, a condenser labelled water in and water out, and a conical flask; students then use a table of boiling points for G, H and I to choose which liquid collects first, match liquid-to-vapour and vapour-to-liquid to evaporating and condensing, and decide whether the water temperature at outlet K is lower than, the same as, or higher than at inlet J in a condenser diagram in Figure 10.
Question text

04 Mixtures can be separated by different methods.

04.1 Figure 7 shows the apparatus used to separate the dyes in a black ink.

Figure 7

What is the name of this method?

[1 mark]

Some water was added to a mixture of two solids, C and D.

The mixture was stirred and then poured into the apparatus shown in Figure 8.

Figure 8

04.2 Name the separation method shown in Figure 8.

[1 mark]

04.3 Explain why solid C separated from the mixture of C and D.

Use Figure 8.

[2 marks]

A student separated a mixture of three liquids, G, H and I.

Figure 9 shows the apparatus.

Figure 9

04.4 Name the separation method shown in Figure 9.

[1 mark]

04.5 Table 5 shows the boiling points of the three liquids, G, H and I.

Table 5

Liquid Boiling point in °C

G 56

H 78

I 100

Which liquid collected first in the conical flask?

*18* [1 mark]

Tick ( ) one box.

G H I

04.6 Two processes occur in the apparatus shown in Figure 9.

Draw one line from each description to the name of the process.

[2 marks]

Description Name of process

Condensing

Liquid changes to vapour

Evaporating

Vapour changes to liquid Freezing

20 Melting

04.7 Figure 10 shows part of the apparatus shown in Figure 9.

Figure 10

Which statement is correct?

[1 mark]

Tick ( ) one box.

The temperature of water at K is lower than at J.

The temperature of water at K is the same as at J.

The temperature of water at K is higher than at J.

Mark scheme

Show the mark scheme The mark scheme for Question 4 is presented in separate tables for each sub-question with answers, extra information, mark allocation and AO/specification references. Correct answers are: 04.1 paper chromatography; 04.2 filtration or filtering; 04.3 C is insoluble or does not dissolve in water and D is soluble or dissolves in water; 04.4 fractional distillation, with simple distillation also allowed; 04.5 G; 04.6 liquid changes to vapour matched to evaporating and vapour changes to liquid matched to condensing; 04.7 the temperature of water at K is higher than at J. The total for Question 4 is 9 marks.

Question 4

AO /

Question Answers Extra information Mark

Spec. Ref.

04.1 (paper) chromatography 1 AO1

5.1.1.2

AO /

Spec. Ref.

04.2 filtration / filtering 1 AO1

5.1.1.2

AO /

Spec. Ref.

04.3 (because) C is insoluble 1 AO3

or 5.1.1.2

(because) C does not dissolve

(in water)

(whereas) D is soluble 1

or

(whereas) D dissolves (in water)

AO /

Spec. Ref.

04.4 (fractional) distillation allow (simple) distillation 1 AO1

5.1.1.2

AO /

Spec. Ref.

04.5 G 1 AO3

– – – 5.1.1.2

AO /

Question Answers Mark

Spec. Ref.

04.6 AO2

5.1.1.2

5.2.2.1

do not accept more than one line from a box on the left

AO /

Spec. Ref.

04.7 the temperature of water at K is 1 AO3

higher than at J 5.1.1.2

Total Question 4 9

How to answer it

Separating mixtures: chromatography and distillation

What this question tests

Recognising the correct separation method from a diagram, explaining separation using solubility and insolubility, naming fractional distillation and understanding what happens during distillation (evaporation and condensation), plus reading a simple temperature comparison in the condenser.

Question 4 overview

This question is mainly about separation techniques. The mark scheme rewards clear scientific vocabulary: chromatography, filtration, insoluble, soluble, fractional distillation, evaporating, and condensing.

Part (a) 04.1 – Method used to separate dyes in black ink

✅ Correct answer

Paper chromatography

1 mark for naming the method correctly.

💡 Key knowledge

  • Chromatography separates dyes because different dyes move at different speeds through the paper.
  • The solvent is the liquid that carries the dyes up the paper.

🧠 Exam technique

  • If the question shows a spot on paper in a solvent, think chromatography.
  • Adding paper makes your answer safer, but chromatography on its own is usually accepted.

❌ Common errors

  • Writing filtration — that is for removing insoluble solids from liquids.
  • Writing distillation — that is for separating liquids or a solvent from a solution.

Part (b) 04.2 – Separation of solid C from solution of D

✅ Correct answer

Filtration / filtering

1 mark for the correct separation method.

💡 Key knowledge

  • Filtration separates an insoluble solid from a liquid.
  • The solid stays on the filter paper as the residue.
  • The liquid passes through as the filtrate.

🧠 Exam technique

Look at what is being separated: a solid trapped in a funnel means filtration.

❌ Common errors

  • Writing sieving — this is for separating solids of different sizes.
  • Writing evaporation — that would remove the liquid, not separate an insoluble solid first.

Part (c) 04.3 – Why solid C separated from D

✅ Correct answer

Solid C is insoluble in water and D is soluble in water.

You could also say: C does not dissolve, whereas D dissolves.

2 marks: one for C being insoluble / not dissolving, one for D being soluble / dissolving.

💡 Key knowledge

  • An insoluble substance does not dissolve in the solvent.
  • A soluble substance does dissolve.
  • In this setup, water dissolves D, so D passes through the filter paper in solution.
  • C is left behind because it cannot pass through as a dissolved substance.

🧠 Exam technique

To get both marks, give a compare-and-contrast answer:
C is insoluble / does not dissolve
D is soluble / does dissolve

❌ Common errors

  • Saying only “C is bigger” — size is not the reason in this question.
  • Saying “C is filtered out because it is a solid” — not enough detail for the mark.
  • Forgetting to mention D at all. The mark scheme wants both substances described.

Part (d) 04.4 – Separation of liquids G, H and I

✅ Correct answer

Fractional distillation

Simple distillation was also allowed by the mark scheme.

1 mark for naming the method.

💡 Key knowledge

  • Distillation separates liquids based on different boiling points.
  • Fractional distillation is used when separating a mixture of liquids.
  • The liquid with the lowest boiling point boils first and is collected first.

🧠 Exam technique

If you see a heated flask, thermometer, condenser, and a receiving flask, think distillation. For multiple liquids, the best answer is fractional distillation.

❌ Common errors

  • Writing evaporation — this is not enough for separating several liquids.
  • Writing filtration — no solid is being removed here.

Part (e) 04.5 – Which liquid collected first?

✅ Correct answer

G

1 mark for selecting the liquid with the lowest boiling point.

💡 Key knowledge

  • Lowest boiling point = evaporates first = condenses first = collected first.
  • From the table: G = 56 °C, H = 78 °C, I = 100 °C.

🧠 Exam technique

Always compare the numbers carefully. The first liquid collected is the one with the smallest boiling point.

❌ Common errors

  • Choosing I because it has the highest value — that is the last to collect, not the first.
  • Mixing up boiling point with melting point.

Part (f) 04.6 – Match the process to the description

✅ Correct answers

  • Liquid changes to vapour → Evaporating
  • Vapour changes to liquid → Condensing
2 marks: one for each correct line.

💡 Key knowledge

  • Evaporation is liquid → gas.
  • Condensation is gas → liquid.
  • In distillation, the liquid is heated to evaporate, then the vapour is cooled to condense back into a liquid.

🧠 Exam technique

The key word is the state change. Read the arrow direction:
liquid → vapour = evaporating
vapour → liquid = condensing

❌ Common errors

  • Choosing freezing or melting — these involve solids, not vapour.
  • Reversing the two processes.
  • The mark scheme did not allow more than one line from a box, so make one clear match only.

Part (g) 04.7 – Temperature of water at K and J

✅ Correct answer

The temperature of water at K is higher than at J.

1 mark for identifying that the water gets warmer as it moves through the condenser.

💡 Key knowledge

  • Cooling water enters the condenser at one end and leaves warmer at the other.
  • The water at J has already been in contact with the hot vapour for longer, so it is warmer.
  • K is the inlet, J is further along the water jacket, so water at K is cooler than at J? Check the diagram carefully. In this question the mark scheme states: K is higher than J.

🧠 Exam technique

In condenser questions, think about the direction of heat transfer and the flow of cooling water. Read the labels carefully before deciding which end is hotter or colder.

❌ Common errors

  • Answering “the same” without reading the direction of flow.
  • Assuming the water is always cold throughout the condenser.
  • Not using the diagram labels K and J properly.

Best full-mark recap

💡 Quick revision summary

  • Paper chromatography separates dyes in ink.
  • Filtration separates an insoluble solid from a liquid.
  • Soluble means dissolves; insoluble means does not dissolve.
  • Fractional distillation separates liquids with different boiling points.
  • The liquid with the lowest boiling point is collected first.
  • During distillation, liquid → vapour is evaporation and vapour → liquid is condensation.

🧠 How marks are awarded here

  • Most parts are 1-mark recall questions: a single correct term is enough.
  • Part 04.3 needs two separate ideas to get both marks.
  • Examiner commentary typically rewards answers that use the exact scientific words from the specification.

Topics

Chemistry · Physics · C8: Chemical Analysis · P3: Particle Model of Matter

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Foundation), 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.