AQA GCSE Combined Science: Trilogy Chemistry Paper 1 (Foundation), 2024: Question 5

11 marks · Standard Demand difficulty · Short Answer

Answer a set of questions about magnesium chloride covering metal and acid reactions, electrolysis of molten ionic compounds, metal reactivity from displacement results, and simple mass and concentration calculations.

Practise this question

Question

The question sheet is labelled Question 05 and states that magnesium chloride is a soluble salt. Part 05.1 asks which gas is produced when magnesium reacts with hydrochloric acid, with tick-box options hydrogen, nitrogen and oxygen; part 05.2 asks which formula represents molten magnesium chloride, with options MgCl2(g), MgCl2(l) and MgCl2(s); part 05.3 says magnesium chloride contains Mg2+ and Cl- ions and asks for the product at the negative and positive electrodes during electrolysis of molten magnesium chloride. A table titled Table 6 shows results for mixing copper, magnesium and iron with copper chloride, magnesium chloride and iron chloride solutions, and part 05.4 asks for the order of reactivity with reasons; part 05.5 asks for the mass of iron oxide reacting with 0.72 g magnesium if 2.32 g of products form; part 05.6 states that 30 cm3 of magnesium chloride solution was used, that 1 dm3 contains 180 g magnesium chloride and 1 dm3 = 1000 cm3, and asks for the mass of magnesium chloride in 30 cm3.
Question text

05 Magnesium chloride is a soluble salt.

05.1 Magnesium reacts with hydrochloric acid to produce magnesium chloride and a gas.

Which gas is produced?

[1 mark]

Tick ( ) one box.

Hydrogen

Nitrogen

Oxygen 22

Magnesium chloride (MgCl2) can be electrolysed when molten.

05.2 Which represents molten magnesium chloride?

[1 mark]

Tick ( ) one box.

MgCl2(g)

MgCl2(l)

MgCl2(s)

05.3 Magnesium chloride contains Mg2+ ions and Cl– ions.

Name the product at each electrode when molten magnesium chloride is electrolysed.

[2 marks]

Negative electrode

Positive electrode

A student investigated the reactivity of three metals: copper, magnesium and iron.

The student mixed each metal with each metal chloride solution.

Table 6 shows the results.

*21* Table 6

Copper chloride Magnesium chloride Iron chloride

solution solution solution

Copper No reaction No reaction No reaction

Magnesium Reaction No reaction Reaction

Iron Reaction No reaction No reaction

05.4 What is the order of reactivity for copper, magnesium and iron?

Give two reasons for your answer.

Use Table 6.

[3 marks]

Most reactive

Least reactive

Reason 1

Reason 2

05.5 When heated 0.72 g of magnesium reacts with iron oxide to produce

2.32 g of products.

Calculate the mass of iron oxide that reacts with 0.72 g of magnesium.

[1 mark]

*23* Mass of iron oxide = g

05.6 The student used 30 cm3 of magnesium chloride solution.

1 dm3 of magnesium chloride solution contains 180 g of magnesium chloride.

1 dm3 = 1000 cm3

Calculate the mass of magnesium chloride in 30 cm3 of magnesium chloride solution.

[3 marks]

Mass of magnesium chloride = g

Mark scheme

Show the mark scheme The mark scheme for Question 5 is presented in a table with columns for question number, answers, extra information, mark and AO/specification reference. It gives the answers: 05.1 hydrogen; 05.2 MgCl2(l); 05.3 magnesium at the negative electrode and chlorine at the positive electrode, allowing symbols Mg and Cl2 and allowing one mark if the products are reversed; 05.4 magnesium most reactive, then iron, then copper, with credit for reasons based on the displacement table; 05.5 1.6 g; and 05.6 5.4 g using either conversion of 30.0 cm3 to 0.030 dm3 and multiplying by 180, or equivalent ratio methods. The bottom row shows Total Question 5 = 11 marks.

Question 5

AO /

Question Answers Extra information Mark

Spec. Ref.

05.1 hydrogen 1 AO1

5.4.1.2

5.4.2.1

AO /

Spec. Ref.

05.2 MgCl2(l) 1 AO2

5.1.1.1

5.2.2.2

AO /

Spec. Ref.

05.3 (negative electrode) magnesium allow Mg 1 AO2

5.4.3.1

5.4.3.2

(positive electrode) chlorine allow Cl2 1

allow 1 mark if both elements

– are reversed – –

AO /

Spec. Ref.

05.4 (most reactive metal) AO3

magnesium allow Mg 1 5.4.1.2

(iron) allow Fe

copper allow Cu

(least reactive metal)

any two from: 2

• magnesium reacts with both allow magnesium has two / most

copper chloride solution and reactions

iron chloride solution

• iron only reacts with copper allow iron has one reaction

chloride solution

• copper does not react with allow copper does not react

either magnesium chloride

solution or iron chloride

16 solution

AO /

Spec. Ref.

05.5 1.6 (g) 1 AO2

5.4.3.1

– – – 5.4.3.2

AO /

Spec. Ref.

05.6 (conversion 30.0 cm3 =) 1 AO2

0.030 dm3 5.3.2.5

(mass =) 0.030 × 180 allow correct use of incorrect / 1

no conversion of volume

= 5.4 (g) 1

OR

1000 cm3 contains 180 g MgCl

(1)

3 180

30 cm contains × 30 (g) (1)

1000

(30 cm3 contains) 5.4 (g) (1)

OR

1000

(ratio of volume =) 33.3

(1)

(so ratio of mass) = (1)

33.3

= 5.4 (g) (1)

Total Question 5 11

How to answer it

Magnesium chloride, electrolysis and reactivity

AQA GCSE Combined Science: Trilogy · Question 5
11 marks total

What this question tests

This question checks your ability to: identify products of metal + acid reactions, read state symbols, name electrolysis products of a molten ionic compound, use the reactivity series to compare metals, and do simple ratio-based mass calculations using concentration and volume.

Part (a): 05.1 — Magnesium + hydrochloric acid

Which gas is produced?

✅ Correct answer

Hydrogen

Mg + 2HCl → MgCl₂ + H₂

💡 Key knowledge

  • Most metals reacting with acids produce a salt + hydrogen.
  • Magnesium is above hydrogen in the reactivity series, so it reacts with hydrochloric acid.

🧠 Exam technique

  • For a 1-mark multiple choice question, you only need the correct tick.
  • If writing the equation, remember hydrogen is a diatomic molecule: H₂.

❌ Common errors

  • Choosing nitrogen or oxygen because they are common gases.
  • Forgetting that metal + acid gives hydrogen, not a metal oxide gas.

Part (b): 05.2 — State symbol for molten magnesium chloride

Which represents molten magnesium chloride?

✅ Correct answer

MgCl₂(l)

💡 Key knowledge

  • (l) means liquid / molten.
  • (g) means gas, and (s) means solid.
  • “Molten” means the substance has been melted, so it is a liquid.

🧠 Exam technique

State symbols are easy marks. Read the keyword carefully: molten = liquid.

❌ Common errors

  • Ticking MgCl₂(s) because salts are often solids at room temperature.
  • Ticking MgCl₂(g) because electrolysis uses electricity, but the compound itself is not a gas.

Part (c): 05.3 — Electrolysis of molten magnesium chloride

Name the product at each electrode.

✅ Correct answers

Negative electrode: magnesium

Positive electrode: chlorine

Allow Mg and Cl₂

💡 Key knowledge

  • Molten MgCl₂ contains Mg²⁺ and Cl⁻ ions only.
  • Positive ions go to the negative electrode and gain electrons.
  • Negative ions go to the positive electrode and lose electrons.
  • At the cathode: Mg²⁺ + 2e⁻ → Mg
  • At the anode: 2Cl⁻ → Cl₂ + 2e⁻

🧠 Exam technique

Mark schemes often award one mark per electrode. If you reverse the names, you may still get credit for identifying both substances, but the best answer is to match each ion to the correct electrode.

❌ Common errors

  • Writing magnesium chloride instead of the element formed.
  • Putting chlorine at the negative electrode.
  • Forgetting that in electrolysis of a molten ionic compound, the products are the elements.

Part (d): 05.4 — Reactivity order of copper, magnesium and iron

Use Table 6 to work out the order and justify it.

✅ Correct answer

Most reactive: magnesium

Then: iron

Least reactive: copper

💡 Key knowledge

  • A more reactive metal will displace a less reactive metal from its salt solution.
  • If there is no reaction, the solid metal is less reactive than the metal in the solution.
  • Magnesium reacts with both copper chloride and iron chloride, so it is the most reactive.
  • Iron reacts with copper chloride but not magnesium chloride, so iron is between magnesium and copper.
  • Copper does not react with either magnesium chloride or iron chloride, so copper is the least reactive.

🧠 Exam technique

  • Give two reasons for 3 marks: one for the order, two supporting statements.
  • Use evidence from the table in clear sentences, e.g. “Magnesium reacts with both solutions.”
  • Top responses compare all three metals, not just one reaction.

❌ Common errors

  • Thinking “no reaction” means the metal is more reactive.
  • Only stating the order without using the table as evidence.
  • Mixing up the meaning of displacement reactions.

📐 How the marks are awarded here

  • 1 mark for the correct order.
  • 2 marks for two correct reasons linked to Table 6.

Model reasons:

  • Magnesium reacts with both copper chloride solution and iron chloride solution.
  • Iron reacts with copper chloride solution but not magnesium chloride solution.
  • Copper does not react with either magnesium chloride solution or iron chloride solution.

Part (e): 05.5 — Mass from a reaction result

0.72 g of magnesium reacts with iron oxide to produce 2.32 g of products. Find the mass of iron oxide that reacted.

✅ Correct answer

1.6 g

💡 Key knowledge

Use conservation of mass:

mass of reactants = mass of products

📐 Step-by-step calculation

  1. Total mass of products = 2.32 g
  2. Mass of magnesium = 0.72 g
  3. Mass of iron oxide = 2.32 − 0.72
  4. = 1.60 g
  5. Rounded appropriately: 1.6 g

🧠 Exam technique

  • This is a quick subtraction question, but you still need to show the calculation clearly for full confidence.
  • Use the numbers given exactly as shown and include the unit g.
  • Watch out for whether the question asks for the mass of a reactant or a product.

❌ Common errors

  • Adding the two masses instead of subtracting.
  • Using 2.32 − 0.72 = 1.60 but forgetting the unit.
  • Writing 1.6 without understanding it comes from conservation of mass.

Part (f): 05.6 — Mass in a given volume of solution

30 cm³ of magnesium chloride solution is used. 1 dm³ contains 180 g of MgCl₂. Calculate the mass in 30 cm³.

✅ Correct answer

5.4 g

💡 Key knowledge

  • 1 dm³ = 1000 cm³
  • The mass in a smaller volume is found by using a proportion or ratio.
  • Mass is directly proportional to volume for the same solution.

📐 Step-by-step calculation

  1. Convert the volume: 30 cm³ = 0.030 dm³
  2. Use the concentration given: 1 dm³ contains 180 g
  3. Multiply: 0.030 × 180 = 5.4
  4. Answer: 5.4 g
Alternative ratio method: 1000 cm³ contains 180 g, so 30 cm³ contains (180 ÷ 1000) × 30 = 5.4 g

🧠 Exam technique

  • Always check whether you need to convert cm³ to dm³.
  • In GCSE chemistry, cm³ to dm³ conversion is a very common trap.
  • Use the correct number of significant figures if the question suggests it; here 5.4 g is suitable.

❌ Common errors

  • Using 30 × 180 without converting units.
  • Dividing the wrong way round.
  • Writing 5.40 g is not wrong, but the key is to show the method clearly.

Quick recap: full-mark answers

✅ Answers in order

  1. Hydrogen
  2. MgCl₂(l)
  3. Negative electrode: magnesium; Positive electrode: chlorine
  4. Magnesium, iron, copper
  5. 1.6 g
  6. 5.4 g

🧠 What top-level responses did well

  • Used precise science terms: hydrogen, molten, displacement, reactivity.
  • Matched answers directly to evidence in the table.
  • Showed calculations clearly and included units.

Topics

Chemistry · C4: Chemical Changes · C3: Quantitative Chemistry

Question and mark scheme from the AQA GCSE Combined Science: Trilogy examination, Chemistry Paper 1 (Foundation), 2024. QuestionVault is an independent revision resource; questions remain the copyright of the awarding body.