OCR A-Level Chemistry Periodic table, elements and physical chemistry (01), November 2021

Every question from OCR A-Level Chemistry Periodic table, elements and physical chemistry (01), November 2021 (H432): 22 questions, 100 marks, each with its mark scheme and topic.

Original question paper

  1. Question 1 1 mark

    Identify the correct definition of electronegativity from the given multiple-choice options.

    Module 2: Foundations in chemistry · 2.2 Electrons, bonding and structure

  2. Question 2 1 mark

    Identify the formula for sodium chlorate(VII) given that a chlorate(VII) ion has a 1- charge.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  3. Question 3 1 mark

    Deduce the correct stoichiometric balancing numbers for silver and water in the redox reaction between silver and concentrated nitric acid.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  4. Question 4 1 mark

    Determine which of the four given samples of organic compounds contains the greatest number of moles of molecules.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  5. Question 5 1 mark

    Calculate the minimum mass of magnesium required to reduce 11.4 g of chromium(III) oxide.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  6. Question 6 1 mark

    Calculate the volume of water needed to dilute a solution of magnesium iodide to a given iodide ion concentration.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  7. Question 7 1 mark

    Identify the row showing elements in order of increasing first ionisation energy among Ca, Si, P, and N.

    Module 3: Periodic table and energy · Module 2: Foundations in chemistry · 3.1 The periodic table · 2.2 Electrons, bonding and structure

  8. Question 8 1 mark

    Calculate the enthalpy change for the reaction of hydrogen sulfide with oxygen using given mean bond enthalpies

    Module 3: Periodic table and energy · 3.2 Physical chemistry

  9. Question 9 1 mark

    Identify which container will have the largest concentration of carbon monoxide at equilibrium given different initial amounts of reactants and products.

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

  10. Question 10 1 mark

    Calculate the pH of a 0.50 mol dm-3 aqueous solution of ethanoic acid given its pKa value at 25 °C.

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

  11. Question 11 1 mark

    Identify the correct signs for enthalpy change and entropy change for a reaction that is feasible at high temperatures but not feasible at low temperatures.

    Module 5: Physical chemistry and transition elements · 5.2 Energy

  12. Question 12 1 mark

    Identify the strongest oxidising agent given two redox systems with their standard electrode potentials.

    Module 5: Physical chemistry and transition elements · 5.2 Energy

  13. Question 13 1 mark

    Identify the correct statement(s) that explain the trend in boiling points down the halogens group.

    Module 3: Periodic table and energy · Module 2: Foundations in chemistry · 3.1 The periodic table · 2.2 Electrons, bonding and structure

  14. Question 14 1 mark

    Identify the correct statements about a molecule of Cl-N=O regarding polarity, lone pairs, and bond angle

    Module 2: Foundations in chemistry · 2.2 Electrons, bonding and structure

  15. Question 15 1 mark

    Identify the correct test results for the hydrated double salt ammonium iron(II) sulfate from a given table of three test reactions.

    Module 5: Physical chemistry and transition elements · Practical Activity Groups · 5.3 Transition elements · PAG 4: Qualitative analysis of ions

  16. Question 16 14 marks

    Describe metallic bonding in magnesium, analyze its successive ionisation energies, and calculate the enthalpy change of solution for magnesium fluoride using an energy cycle.

    Module 2: Foundations in chemistry · Module 3: Periodic table and energy · Module 5: Physical chemistry and transition elements · 2.2 Electrons, bonding and structure · 3.1 The periodic table · 3.2 Physical chemistry · 5.2 Energy

  17. Question 17 11 marks

    Explain the definitions of d-block and transition elements using electron configurations, define a bidentate ligand, determine the formulae of a hydrated chromium(III) salt and a complex ion formed by ligand substitution, write the ionic equation, and draw 3D structures for the three stereoisomers.

    Module 5: Physical chemistry and transition elements · Module 2: Foundations in chemistry · 5.3 Transition elements · 2.1 Atoms and reactions

  18. Question 18 12 marks

    Determine the percentage by mass of copper in an ore using a titration method involving copper(II) ions, potassium iodide, and sodium thiosulphate.

    Module 2: Foundations in chemistry · Module 5: Physical chemistry and transition elements · Practical Activity Groups · PAG 2: Acid-base titration · 5.3 Transition elements · 2.1 Atoms and reactions

  19. Question 19 11 marks

    Construct electrochemical cell diagrams, overall redox equations, explain disproportionation using oxidation numbers and electrode potentials, and calculate standard cell potentials for hydrogen-oxygen fuel cells.

    Module 5: Physical chemistry and transition elements · 5.2 Energy

  20. Question 20 11 marks

    Calculate Gibbs free energy change, maximum feasibility temperature, and equilibrium constant Kp for the reaction of nitrogen monoxide and oxygen to form nitrogen dioxide, and predict the effects of changes on equilibrium and rate.

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH · 5.2 Energy

  21. Question 21 10 marks

    Analyze rate of reaction data, propose reaction mechanisms, calculate activation energy from an Arrhenius plot, and determine temperature from rate constant data.

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

  22. Question 22 16 marks

    Calculate the pH of sodium hydroxide, enthalpy changes of neutralisation and enthalpy of reaction, and determine the pH and mass of N2O3 used to form a buffer solution with nitrous acid.

    Module 5: Physical chemistry and transition elements · Module 3: Periodic table and energy · Practical Activity Groups · 5.1 Rates, equilibrium and pH · 5.2 Energy · PAG 3: Enthalpy determination · PAG 11: pH measurement

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