AQA A-Level Chemistry AS Paper 1, November 2021

Every question from AQA A-Level Chemistry AS Paper 1, November 2021 (7404): 25 questions, 80 marks, each with its mark scheme and topic.

Original question paper

  1. Question 1 6 marks

    State features of the current atomic model missing from Rutherford's model, and calculate the relative atomic mass of tin from mass spectrometry data.

    Physical Chemistry · 3.1.1 Atomic Structure · 3.1.2 Amount of Substance

  2. Question 2 8 marks

    Describe the reaction of magnesium with steam, the metallic bonding in magnesium, the ionic bonding and melting point of magnesium chloride, and a medical use of magnesium hydroxide.

    Inorganic Chemistry · Physical Chemistry · 3.2.2 Group 2, The Alkaline Earth Metals · 3.1.3 Bonding

  3. Question 3 4 marks

    State the meaning of an oxidising agent and deduce half-equations and the overall redox equation for the oxidation of sulfite ions by dichromate ions in acidic conditions.

    Physical Chemistry · 3.1.7 Oxidation, Reduction and Redox Equations

  4. Question 4 7 marks

    Identify cations and anions in unknown solutions A, B, and C using test-tube reactions and observations from Table 2.

    Inorganic Chemistry · Required Practicals · Required Practical 4: Carry out simple test-tube reactions to identify Cations and Anions · 3.2.3 Group 7(17), The Halogens · 3.2.2 Group 2, The Alkaline Earth Metals

  5. Question 5 6 marks

    Explain the intermolecular forces in chlorine, write equations for its reactions with water and sodium hydroxide, and state the reason chlorine is added to drinking water.

    Physical Chemistry · Inorganic Chemistry · 3.1.3 Bonding · 3.2.3 Group 7(17), The Halogens

  6. Question 6 5 marks

    Calculate the mass of sulfur dioxide formed in the reaction between calcium sulfide and calcium sulfate, and show that calcium sulfate is the limiting reagent.

    Physical Chemistry · 3.1.2 Amount of Substance

  7. Question 7 6 marks

    State the meaning of standard enthalpy of combustion, calculate the enthalpy of combustion of propan-1-ol from calorimetry data, and give a reason why the experimental value is less exothermic than expected.

    Physical Chemistry · Required Practicals · 3.1.4 Energetics · Required Practical 2: Measurement of an enthalpy change

  8. Question 8 8 marks

    Calculate the percentage by mass of sodium ethanoate in a contaminated sample of ethanoic acid using titration data, and explain the effect of rinsing the burette with deionised water.

    Physical Chemistry · Required Practicals · Required Practical 1: Making up a volumetric solution · 3.1.2 Amount of Substance · 3.1.12 Acids and Bases

  9. Question 9 6 marks

    Explain, in terms of equilibrium yield and cost, why specific conditions of temperature, pressure, and a nickel catalyst are used in the industrial preparation of hydrogen from methane and steam.

    Physical Chemistry · 3.1.5 Kinetics · 3.1.6 Chemical Equilibria, Le Chatelier's Principle and Kc

  10. Question 10 9 marks

    Calculate the equilibrium constant expression, moles of oxygen at equilibrium, and temperature using the ideal gas equation for the oxidation of sulfur dioxide.

    Physical Chemistry · 3.1.2 Amount of Substance · 3.1.6 Chemical Equilibria, Le Chatelier's Principle and Kc

  11. Question 11 1 mark

    Identify the correct equation for the electrospray ionisation of molecule X in a time of flight mass spectrometer.

    Physical Chemistry · Organic Chemistry · 3.1.1 Atomic Structure · 3.3.6 Organic Analysis

  12. Question 12 1 mark

    Identify the electron configuration of V2+ in the ground state

    Physical Chemistry · 3.1.1 Atomic Structure

  13. Question 13 1 mark

    Identify which given molecule is not able to form a co-ordinate bond with another species

    Physical Chemistry · 3.1.3 Bonding

  14. Question 14 1 mark

    Identify which species has a square planar shape among the given options.

    Physical Chemistry · 3.1.3 Bonding

  15. Question 15 1 mark

    Identify which bond has the most unsymmetrical electron distribution among the given options.

    Physical Chemistry · 3.1.3 Bonding

  16. Question 16 1 mark

    Identify which compound contains a chlorine atom with an oxidation state of +4

    Physical Chemistry · 3.1.7 Oxidation, Reduction and Redox Equations

  17. Question 17 1 mark

    Identify which of the given elements is classified as a d-block element.

    Inorganic Chemistry · 3.2.1 Periodicity

  18. Question 18 1 mark

    Identify which element in Period 3 has the highest melting point from the given multiple-choice options.

    Inorganic Chemistry · 3.2.1 Periodicity

  19. Question 19 1 mark

    Identify which pair of solutions reacts when mixed to form a dark brown solution containing iodine.

    Inorganic Chemistry · 3.2.3 Group 7(17), The Halogens

  20. Question 20 1 mark

    Identify which solid sodium halide does not produce a sulfur-containing gas when reacted with concentrated sulfuric acid.

    Inorganic Chemistry · 3.2.3 Group 7(17), The Halogens

  21. Question 21 1 mark

    Identify which atom has one more proton and two more neutrons than 31P with subscript 15.

    Physical Chemistry · 3.1.1 Atomic Structure

  22. Question 22 1 mark

    Identify the correct use of barium sulfate from the given multiple-choice options.

    Inorganic Chemistry · 3.2.2 Group 2, The Alkaline Earth Metals

  23. Question 23 1 mark

    Identify which isoelectronic ion has the largest radius among F-, Mg2+, Na+, and O2-.

    Inorganic Chemistry · 3.2.1 Periodicity

  24. Question 24 1 mark

    Identify which of the given elements has a first ionisation energy lower than that of sulfur.

    Inorganic Chemistry · 3.2.1 Periodicity

  25. Question 25 1 mark

    Identify element Z from the graph of its first seven successive ionisation energies showing a large jump after the fourth ionisation energy.

    Physical Chemistry · 3.1.1 Atomic Structure

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