AQA A-Level Chemistry Paper 3, June 2025

Every question from AQA A-Level Chemistry Paper 3, June 2025 (7405): 36 questions, 90 marks, each with its mark scheme and topic.

Original question paper

  1. Question 1 9 marks

    Determine the enthalpy of solution of potassium hydroxide experimentally and theoretically using calorimetry calculations and Born–Haber cycle data.

    Physical Chemistry · Required Practicals · 3.1.4 Energetics · 3.1.8 Thermodynamics · Required Practical 2: Measurement of an enthalpy change

  2. Question 2 15 marks

    Investigate the rate of reaction between hydrogen peroxide, iodide ions, and acid using an iodine clock method to determine orders of reaction, rate equation, initial rate, and evaluate experimental uncertainties.

    Physical Chemistry · Required Practicals · 3.1.9 Rate Equations · 3.1.2 Amount of Substance · Required Practical 7: Measuring the rate of reaction by an initial rate method

  3. Question 3 11 marks

    Identify apparatus errors in a standard electrode potential setup, state the voltmeter property required to measure cell EMF, deduce overall cell reactions, and use electrode potential data to explain redox observations and calculate cell EMF.

    Physical Chemistry · Required Practicals · 3.1.11 Electrode Potentials · Required Practical 8: Measuring the EMF of an electrochemical cell

  4. Question 4 9 marks

    Write the Kc expression, explain why a sample is quenched with ice-cold water before titration, and calculate the value and units of Kc for an equilibrium between iron(III) and iodide ions.

    Physical Chemistry · 3.1.6 Chemical Equilibria, Le Chatelier's Principle and Kc · 3.1.2 Amount of Substance · 3.1.5 Kinetics

  5. Question 5 10 marks

    Describe a method to distinguish propan-1-ol and propan-2-ol using oxidation, chemical tests, and infrared spectroscopy, state the purpose of anti-bumping granules, and draw labelled apparatus for heating under reflux.

    Organic Chemistry · Required Practicals · 3.3.5 Alcohols · 3.3.6 Organic Analysis · 3.3.8 Aldehydes and Ketones · Required Practical 5: Distillation of a product from a reaction · Required Practical 6: Tests for alcohol, aldehyde, alkene and carboxylic acid

  6. Question 6 6 marks

    Identify stereoisomerism in a triglyceride from rapeseed oil, determine double bond locants and stereoisomer counts for methyl esters, and state products and uses of saponification and transesterification.

    Organic Chemistry · 3.3.1 Introduction to Organic Chemistry · 3.3.9 Carboxylic Acids and Derivatives

  7. Question 7 1 mark

    Identify the formula for the quaternary ammonium cation produced in the reaction between methylamine and excess bromoethane.

    Organic Chemistry · 3.3.11 Amines · 3.3.3 Halogenoalkanes

  8. Question 8 1 mark

    Identify which reaction involving potassium hydroxide (KOH) does not involve it acting as a base.

    Organic Chemistry · 3.3.3 Halogenoalkanes · 3.3.9 Carboxylic Acids and Derivatives · 3.3.11 Amines

  9. Question 9 1 mark

    Identify which statement correctly describes the effect of using a catalyst in a reversible reaction.

    Physical Chemistry · 3.1.5 Kinetics · 3.1.6 Chemical Equilibria, Le Chatelier's Principle and Kc

  10. Question 10 1 mark

    Identify which diagram correctly shows the curly arrows in the mechanism for the elimination reaction of bromoethane.

    Organic Chemistry · 3.3.3 Halogenoalkanes · 3.3.1 Introduction to Organic Chemistry

  11. Question 11 1 mark

    Identify the correct classification of Period 3 oxides into giant ionic, giant covalent, and simple molecular structures.

    Inorganic Chemistry · Physical Chemistry · 3.2.4 Properties of Period 3 Elements and Their Oxides · 3.1.3 Bonding

  12. Question 12 1 mark

    Calculate the percentage abundance of 235UF6 in a sample given the relative molecular mass of the sample and the isotopes present.

    Physical Chemistry · 3.1.1 Atomic Structure · 3.1.2 Amount of Substance

  13. Question 13 1 mark

    Identify which compound reacts with concentrated sulfuric acid to form an intermediate that reacts with excess water to produce an alcohol.

    Organic Chemistry · 3.3.4 Alkenes · 3.3.5 Alcohols

  14. Question 14 1 mark

    Identify the correct and complete observation when a piece of strontium is added to an excess of water.

    Inorganic Chemistry · 3.2.2 Group 2, The Alkaline Earth Metals

  15. Question 15 1 mark

    Identify the correct statement regarding trends in physical properties across Period 3.

    Inorganic Chemistry · 3.2.1 Periodicity

  16. Question 16 1 mark

    Identify the incorrect statement regarding the first ionisation energies of Period 3 elements.

    Inorganic Chemistry · Physical Chemistry · 3.2.1 Periodicity · 3.1.1 Atomic Structure

  17. Question 17 1 mark

    Identify the type(s) of stereoisomerism shown by the complex ion [Cr(H2NCH2CH2NH2)3]3+.

    Inorganic Chemistry · 3.2.5 Transition Metals

  18. Question 18 1 mark

    Identify the correct structural formula for 4-chloro-2-methylpent-2-enoic acid from four multiple choice options.

    Organic Chemistry · 3.3.1 Introduction to Organic Chemistry · 3.3.9 Carboxylic Acids and Derivatives

  19. Question 19 1 mark

    Identify which Period 3 oxide produces a solution with the lowest pH when added to water.

    Inorganic Chemistry · 3.2.4 Properties of Period 3 Elements and Their Oxides

  20. Question 20 1 mark

    Identify which property of the Group 2 elements increases with increasing atomic number.

    Inorganic Chemistry · 3.2.2 Group 2, The Alkaline Earth Metals

  21. Question 21 1 mark

    Identify which electron configuration corresponds to an element with a maximum oxidation state of +5 in its compounds.

    Physical Chemistry · Inorganic Chemistry · 3.1.1 Atomic Structure · 3.2.5 Transition Metals · 3.1.7 Oxidation, Reduction and Redox Equations

  22. Question 22 1 mark

    Identify the correct statement regarding the composition and geometry of the complex ion present in Tollens' reagent.

    Inorganic Chemistry · Organic Chemistry · 3.2.5 Transition Metals · 3.3.8 Aldehydes and Ketones

  23. Question 23 1 mark

    Identify which reaction produces an octahedral complex ion from the given options.

    Inorganic Chemistry · 3.2.5 Transition Metals · 3.2.6 Reactions of Ions in Aqueous Solution

  24. Question 24 1 mark

    Identify the correct statement regarding the production of ethanol biofuel by fermentation.

    Organic Chemistry · 3.3.5 Alcohols

  25. Question 25 1 mark

    Identify which of the given elements is in the p block of the Periodic Table.

    Inorganic Chemistry · Physical Chemistry · 3.2.1 Periodicity · 3.1.1 Atomic Structure

  26. Question 26 1 mark

    Identify which statement about the stoichiometry of reactions involving Period 3 oxides is correct.

    Inorganic Chemistry · Physical Chemistry · 3.2.4 Properties of Period 3 Elements and Their Oxides · 3.1.2 Amount of Substance

  27. Question 27 1 mark

    Identify which species from a given list has a tetrahedral shape.

    Physical Chemistry · Inorganic Chemistry · 3.1.3 Bonding · 3.2.5 Transition Metals

  28. Question 28 1 mark

    Identify the correct statement about the fractional distillation and cracking of alkanes.

    Organic Chemistry · 3.3.2 Alkanes

  29. Question 29 1 mark

    Identify the structure of the dipeptide formed from serine and alanine.

    Organic Chemistry · 3.3.13 Amino Acids, Proteins and DNA

  30. Question 30 1 mark

    Identify the correct order of decreasing pH for solutions formed when equal amounts of sodium, magnesium, and chlorine are added separately to water.

    Inorganic Chemistry · 3.2.4 Properties of Period 3 Elements and Their Oxides · 3.2.3 Group 7(17), The Halogens

  31. Question 31 1 mark

    Identify the shapes around the central atom in the acid molecules formed when phosphorus(V) oxide and sulfur dioxide react with water.

    Physical Chemistry · Inorganic Chemistry · 3.1.3 Bonding · 3.2.4 Properties of Period 3 Elements and Their Oxides

  32. Question 32 1 mark

    Identify the correct structure of transplatin from given square planar and tetrahedral representations.

    Inorganic Chemistry · Organic Chemistry · 3.2.5 Transition Metals · 3.3.13 Amino Acids, Proteins and DNA

  33. Question 33 1 mark

    Identify which two labelled R group interactions in a protein's tertiary structure represent an intermolecular force and a covalent bond, respectively.

    Organic Chemistry · Physical Chemistry · 3.3.13 Amino Acids, Proteins and DNA · 3.1.3 Bonding

  34. Question 34 1 mark

    Identify the correct statement about enzymes from the given options.

    Organic Chemistry · 3.3.13 Amino Acids, Proteins and DNA

  35. Question 35 1 mark

    Identify which compound can be used as a cationic surfactant from four given organic formulas.

    Organic Chemistry · 3.3.11 Amines

  36. Question 36 1 mark

    Identify which ion is formed during the mechanism for the acid-catalysed hydration of 1-methylcyclopent-1-ene to produce the major product.

    Organic Chemistry · 3.3.1 Introduction to Organic Chemistry · 3.3.4 Alkenes · 3.3.5 Alcohols

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