OCR A-Level Chemistry AS Breadth in chemistry (01), June 2018

Every question from OCR A-Level Chemistry AS Breadth in chemistry (01), June 2018 (H032): 25 questions, 70 marks, each with its mark scheme and topic.

Original question paper

  1. Question 1 1 mark

    Determine the formula of the compound formed when sodium reacts with element X, given the electron configuration of element X.

    Module 2: Foundations in chemistry · 2.2 Electrons, bonding and structure · 2.1 Atoms and reactions

  2. Question 2 1 mark

    Calculate the number of oxygen atoms in 88.0 g of CO2

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  3. Question 3 1 mark

    Identify the compound with a given percentage composition by mass from four multiple-choice options.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  4. Question 4 1 mark

    Calculate the mass of sodium that reacts with water to produce 960 cm3 of hydrogen gas at RTP based on a given chemical equation.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  5. Question 5 1 mark

    Identify which chemical equation does not represent a neutralisation reaction among the four given options.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  6. Question 6 1 mark

    Determine the oxidation number of iron in K2FeO4.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  7. Question 7 1 mark

    Identify which given chemical reaction shows the oxidation of sulfur.

    Module 3: Periodic table and energy · 3.1 The periodic table

  8. Question 8 1 mark

    Identify the property that determines the order of elements in the Periodic Table.

    Module 2: Foundations in chemistry · Module 3: Periodic table and energy · 2.1 Atoms and reactions · 3.1 The periodic table

  9. Question 9 1 mark

    Deduce the formula of the chloride of element Y using its first five successive ionisation energies.

    Module 2: Foundations in chemistry · Module 3: Periodic table and energy · 2.1 Atoms and reactions · 2.2 Electrons, bonding and structure · 3.1 The periodic table

  10. Question 10 1 mark

    Identify which element has induced dipole-dipole interactions (London forces) in its solid lattice among boron, magnesium, silicon, and sulfur.

    Module 2: Foundations in chemistry · Module 3: Periodic table and energy · 2.2 Electrons, bonding and structure · 3.1 The periodic table

  11. Question 11 1 mark

    Calculate the standard enthalpy change of combustion of aluminium sulfide using standard enthalpy changes of formation.

    Module 3: Periodic table and energy · 3.2 Physical chemistry

  12. Question 12 1 mark

    Identify which experimental error caused the calculated enthalpy change of combustion of methanol to be more exothermic than the data book value.

    Module 3: Periodic table and energy · Practical Activity Groups · 3.2 Physical chemistry · PAG 3: Enthalpy determination

  13. Question 13 1 mark

    Deduce the changes in pressure and temperature required to shift the equilibrium position towards the products for the given reversible reaction.

    Module 3: Periodic table and energy · 3.2 Physical chemistry

  14. Question 14 1 mark

    Identify the correct expression for the equilibrium constant Kc for the reversible reaction between nitrogen and hydrogen to form ammonia.

    Module 5: Physical chemistry and transition elements · 5.1 Rates, equilibrium and pH

  15. Question 15 1 mark

    Identify the formula of a compound that reacts with 8 mol of O2 for complete combustion from multiple choice options.

    Module 2: Foundations in chemistry · 2.1 Atoms and reactions

  16. Question 16 1 mark

    Determine the number of tertiary alcohol structural isomers with the molecular formula C6H14O.

    Module 4: Core organic chemistry · 4.2 Alcohols, haloalkanes and analysis

  17. Question 17 1 mark

    Determine the molecular formula of naphthalene from its skeletal structure.

    Module 6: Organic chemistry and analysis · 6.1 Aromatic compounds, carbonyls and acids

  18. Question 18 1 mark

    Identify the product formed from the reaction of pent-2-ene with bromine

    Module 4: Core organic chemistry · 4.1 Basic concepts and hydrocarbons

  19. Question 19 1 mark

    Identify the correct E/Z isomerism for two double bonds in a given branched alkene molecule from multiple-choice options

    Module 4: Core organic chemistry · 4.1 Basic concepts and hydrocarbons

  20. Question 20 1 mark

    Identify which alcohol is likely to have a fragment ion at m/z = 31 in its mass spectrum from a given list of four structural formulas.

    Module 4: Core organic chemistry · Module 6: Organic chemistry and analysis · 4.2 Alcohols, haloalkanes and analysis · 6.3 Analysis

  21. Question 21 8 marks

    Calculate the relative atomic mass of silicon, determine atomic structure, draw a dot-and-cross diagram, predict the shape of phosgene, and explain why elements belong to the p-block.

    Module 2: Foundations in chemistry · Module 3: Periodic table and energy · 2.1 Atoms and reactions · 2.2 Electrons, bonding and structure · 3.1 The periodic table

  22. Question 22 13 marks

    Calculate the mass of magnesium needed to react with phosphoric acid, determine the volume of phosphine gas produced using the ideal gas equation, and write related chemical equations.

    Module 2: Foundations in chemistry · Module 3: Periodic table and energy · 2.1 Atoms and reactions · 3.2 Physical chemistry

  23. Question 23 10 marks

    Calculate the enthalpy change for the reaction between magnesium and silver nitrate, explain how to test if the reaction went to completion using sodium chloride, and use the Boltzmann distribution model to explain the effect of temperature on reaction rate.

    Module 3: Periodic table and energy · Module 5: Physical chemistry and transition elements · Practical Activity Groups · 3.2 Physical chemistry · 5.1 Rates, equilibrium and pH · PAG 3: Enthalpy determination

  24. Question 24 10 marks

    Explain structural isomerism and boiling point trends of saturated hydrocarbons A, B, and C, and analyse their reactions with chlorine.

    Module 4: Core organic chemistry · 4.1 Basic concepts and hydrocarbons

  25. Question 25 9 marks

    Deduce the products of alcohol reactions, name the alcohol, outline the haloalkane hydrolysis mechanism, and explain IR spectroscopy changes for the functional group conversion.

    Module 4: Core organic chemistry · Module 6: Organic chemistry and analysis · 4.2 Alcohols, haloalkanes and analysis · 6.3 Analysis

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